New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry

Detalhes bibliográficos
Autor(a) principal: Guerra, Mauro
Data de Publicação: 2016
Outros Autores: Carvalho, Maria Luisa, Le Gac, Agnès, Manso, Marta, Mortari, Camila, Longelin, Stephane, Pessanha, Sofia
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: https://doi.org/10.1063/1.4943617
Resumo: SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013
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spelling New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometryPhysics and Astronomy(all)SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013The richly decorated foral charter attributed by D. Manuel I of Portugal, in 1515, to the village of Setubal, was studied using Energy Dispersive X-ray Fluorescence spectrometry and Raman micro-spectroscopy. An in situ characterization of the pigments used in the production of this masterpiece showed a very different pigment palette choice when compared to other similar Manueline charters. The red and green pigments are particularly puzzling, as the widely used mercury- and copper-based pigments, vermillion and malachite, respectively, were not found in the illuminated frontispiece. Instead, the cheaper lead-based pigment minium was used in the King's flag, while a mixture of copper sulfates was found for the green color, identified by means of micro-Raman spectroscopy. This result led to a new look at the conception that only one Royal workshop existed for the elaboration of Manueline foral charters.LIBPhys-UNLDF – Departamento de FísicaDCR - Departamento de Conservação e RestauroRUNGuerra, MauroCarvalho, Maria LuisaLe Gac, AgnèsManso, MartaMortari, CamilaLongelin, StephanePessanha, Sofia2019-04-09T22:20:31Z2016-03-142016-03-14T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.1063/1.4943617eng0021-8979PURE: 11799373http://www.scopus.com/inward/record.url?scp=84962487221&partnerID=8YFLogxKhttps://doi.org/10.1063/1.4943617info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:31:30Zoai:run.unl.pt:10362/66146Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:34:28.448724Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
title New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
spellingShingle New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
Guerra, Mauro
Physics and Astronomy(all)
title_short New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
title_full New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
title_fullStr New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
title_full_unstemmed New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
title_sort New insights into the red and green pigments in the illuminated foral charter of Setubal (1515) by combined use of μ-Raman and X-ray fluorescence spectrometry
author Guerra, Mauro
author_facet Guerra, Mauro
Carvalho, Maria Luisa
Le Gac, Agnès
Manso, Marta
Mortari, Camila
Longelin, Stephane
Pessanha, Sofia
author_role author
author2 Carvalho, Maria Luisa
Le Gac, Agnès
Manso, Marta
Mortari, Camila
Longelin, Stephane
Pessanha, Sofia
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv LIBPhys-UNL
DF – Departamento de Física
DCR - Departamento de Conservação e Restauro
RUN
dc.contributor.author.fl_str_mv Guerra, Mauro
Carvalho, Maria Luisa
Le Gac, Agnès
Manso, Marta
Mortari, Camila
Longelin, Stephane
Pessanha, Sofia
dc.subject.por.fl_str_mv Physics and Astronomy(all)
topic Physics and Astronomy(all)
description SPTDC/EAT-EAT/112662/2009 SFRH/BPD/94234/2013
publishDate 2016
dc.date.none.fl_str_mv 2016-03-14
2016-03-14T00:00:00Z
2019-04-09T22:20:31Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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dc.identifier.uri.fl_str_mv https://doi.org/10.1063/1.4943617
url https://doi.org/10.1063/1.4943617
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0021-8979
PURE: 11799373
http://www.scopus.com/inward/record.url?scp=84962487221&partnerID=8YFLogxK
https://doi.org/10.1063/1.4943617
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