Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | https://doi.org/10.3390/polym10040396 |
Resumo: | This work was supported by the Associate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013; 30951/02/SAICT/2017-SAICT) and co-financed by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265). The National NMR Facility is supported by Fundacao para a Ciencia e Tecnologia (RECI/BBB-BQB/0230/2012). We acknowledge the Laboratorio de Analises REQUIMTE for the technical support for the mass spectrometry analyses. |
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Incorporation of coumarin-based fluorescent monomers into co-oligomeric moleculesFluorescent polymersOligomersVinylcoumarinsChemistry(all)Polymers and PlasticsThis work was supported by the Associate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013; 30951/02/SAICT/2017-SAICT) and co-financed by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265). The National NMR Facility is supported by Fundacao para a Ciencia e Tecnologia (RECI/BBB-BQB/0230/2012). We acknowledge the Laboratorio de Analises REQUIMTE for the technical support for the mass spectrometry analyses.With the purpose of modifying organic fluorescent dyes based on the coumarin scaffold, and developing and evaluating a route to its incorporation into a polymeric backbone, a study was conducted on the co-polymerization of 3-vinylcoumarins with styrene and methyl acrylate using 2,2-azobis(isobutyronitrile) (AIBN) as the radical initiator. The structural and photophysical characterization proved the incorporation of the coumarin monomers into the polymeric chain and further showed a decrease in the fluorescence quantum yields in the co-oligomers.DQ - Departamento de QuímicaLAQV@REQUIMTERUNTeixeira, EdgarLima, João C.Parola, A. JorgeBranco, Paula S.2019-04-03T00:30:29Z2018-04-032018-04-03T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttps://doi.org/10.3390/polym10040396eng1618-7229PURE: 4056889http://www.scopus.com/inward/record.url?scp=85045051411&partnerID=8YFLogxKhttps://doi.org/10.3390/polym10040396info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T04:28:01Zoai:run.unl.pt:10362/58204Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:33:10.630718Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
title |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
spellingShingle |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules Teixeira, Edgar Fluorescent polymers Oligomers Vinylcoumarins Chemistry(all) Polymers and Plastics |
title_short |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
title_full |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
title_fullStr |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
title_full_unstemmed |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
title_sort |
Incorporation of coumarin-based fluorescent monomers into co-oligomeric molecules |
author |
Teixeira, Edgar |
author_facet |
Teixeira, Edgar Lima, João C. Parola, A. Jorge Branco, Paula S. |
author_role |
author |
author2 |
Lima, João C. Parola, A. Jorge Branco, Paula S. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
DQ - Departamento de Química LAQV@REQUIMTE RUN |
dc.contributor.author.fl_str_mv |
Teixeira, Edgar Lima, João C. Parola, A. Jorge Branco, Paula S. |
dc.subject.por.fl_str_mv |
Fluorescent polymers Oligomers Vinylcoumarins Chemistry(all) Polymers and Plastics |
topic |
Fluorescent polymers Oligomers Vinylcoumarins Chemistry(all) Polymers and Plastics |
description |
This work was supported by the Associate Laboratory for Green Chemistry-LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2013; 30951/02/SAICT/2017-SAICT) and co-financed by the ERDF under the PT2020 Partnership Agreement (POCI-01-0145-FEDER-007265). The National NMR Facility is supported by Fundacao para a Ciencia e Tecnologia (RECI/BBB-BQB/0230/2012). We acknowledge the Laboratorio de Analises REQUIMTE for the technical support for the mass spectrometry analyses. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-04-03 2018-04-03T00:00:00Z 2019-04-03T00:30:29Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://doi.org/10.3390/polym10040396 |
url |
https://doi.org/10.3390/polym10040396 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
1618-7229 PURE: 4056889 http://www.scopus.com/inward/record.url?scp=85045051411&partnerID=8YFLogxK https://doi.org/10.3390/polym10040396 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
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openAccess |
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application/pdf |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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