Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices

Detalhes bibliográficos
Autor(a) principal: Rodrigues, L. C.
Data de Publicação: 2011
Outros Autores: Silva, Maria Manuela, Smith, Michael John, Gonçalves, A., Fortunato, E.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/13610
Resumo: In this exploratory study the results of characterisation of a poly(oxyethylene) (PEO)/siloxane hybrid network electrolyte doped with lithium hexafluoroarsenate (LiAsF6) are described. In accordance with convention, the lithium salt concentration is expressed in terms of the number of oxyethylene units in the organic component of the host network per Li+ ion guest species. Samples of solvent-free electrolytes were prepared with a range of guest salt concentration using the sol-gel process. Hybrid materials based on LiAsF6, were obtained as mechanically robust, flexible, transparent and completely amorphous films and characterized by conductivity measurements, thermal analysis and electrochemical stability. Preliminary characterisation of electrochromic devices (ECDs) incorporating optimised LiAsF6-doped di-ureasil compositions have confirmed that these electrolytes perform satisfactorily as multifunctional component layers in this application.
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spelling Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devicesSolid polymer electrolyteIonic conductivityThermal analysisElectrochemical stabilityElectrochromic devicesSolvent-free electrolytesLithium hexafluoroarsenateScience & TechnologyIn this exploratory study the results of characterisation of a poly(oxyethylene) (PEO)/siloxane hybrid network electrolyte doped with lithium hexafluoroarsenate (LiAsF6) are described. In accordance with convention, the lithium salt concentration is expressed in terms of the number of oxyethylene units in the organic component of the host network per Li+ ion guest species. Samples of solvent-free electrolytes were prepared with a range of guest salt concentration using the sol-gel process. Hybrid materials based on LiAsF6, were obtained as mechanically robust, flexible, transparent and completely amorphous films and characterized by conductivity measurements, thermal analysis and electrochemical stability. Preliminary characterisation of electrochromic devices (ECDs) incorporating optimised LiAsF6-doped di-ureasil compositions have confirmed that these electrolytes perform satisfactorily as multifunctional component layers in this application.Fundação para a Ciência e a TecnologiaElsevierUniversidade do MinhoRodrigues, L. C.Silva, Maria ManuelaSmith, Michael JohnGonçalves, A.Fortunato, E.20112011-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/13610eng0013-468810.1016/j.electacta.2011.07.040The original publication is available at www.elsevier.cominfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T11:59:09Zoai:repositorium.sdum.uminho.pt:1822/13610Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:48:54.394658Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
title Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
spellingShingle Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
Rodrigues, L. C.
Solid polymer electrolyte
Ionic conductivity
Thermal analysis
Electrochemical stability
Electrochromic devices
Solvent-free electrolytes
Lithium hexafluoroarsenate
Science & Technology
title_short Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
title_full Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
title_fullStr Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
title_full_unstemmed Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
title_sort Preliminary characterisation of LiAsF6 hybrid polymer electrolytes for electrochromic devices
author Rodrigues, L. C.
author_facet Rodrigues, L. C.
Silva, Maria Manuela
Smith, Michael John
Gonçalves, A.
Fortunato, E.
author_role author
author2 Silva, Maria Manuela
Smith, Michael John
Gonçalves, A.
Fortunato, E.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Rodrigues, L. C.
Silva, Maria Manuela
Smith, Michael John
Gonçalves, A.
Fortunato, E.
dc.subject.por.fl_str_mv Solid polymer electrolyte
Ionic conductivity
Thermal analysis
Electrochemical stability
Electrochromic devices
Solvent-free electrolytes
Lithium hexafluoroarsenate
Science & Technology
topic Solid polymer electrolyte
Ionic conductivity
Thermal analysis
Electrochemical stability
Electrochromic devices
Solvent-free electrolytes
Lithium hexafluoroarsenate
Science & Technology
description In this exploratory study the results of characterisation of a poly(oxyethylene) (PEO)/siloxane hybrid network electrolyte doped with lithium hexafluoroarsenate (LiAsF6) are described. In accordance with convention, the lithium salt concentration is expressed in terms of the number of oxyethylene units in the organic component of the host network per Li+ ion guest species. Samples of solvent-free electrolytes were prepared with a range of guest salt concentration using the sol-gel process. Hybrid materials based on LiAsF6, were obtained as mechanically robust, flexible, transparent and completely amorphous films and characterized by conductivity measurements, thermal analysis and electrochemical stability. Preliminary characterisation of electrochromic devices (ECDs) incorporating optimised LiAsF6-doped di-ureasil compositions have confirmed that these electrolytes perform satisfactorily as multifunctional component layers in this application.
publishDate 2011
dc.date.none.fl_str_mv 2011
2011-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/13610
url http://hdl.handle.net/1822/13610
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0013-4688
10.1016/j.electacta.2011.07.040
The original publication is available at www.elsevier.com
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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