Lipase-ultrasound assisted synthesis of polyesters

Detalhes bibliográficos
Autor(a) principal: Tomke, Prerana D.
Data de Publicação: 2017
Outros Autores: Zhao, Xiaoman, Chiplunkar, Pranali P., Xu, B., Wang, Hongbo, Silva, Carla, Rathod, Virendra K., Cavaco-Paulo, Artur
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/46746
Resumo: Poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), were enzymatically synthesized by immobilized Candida antarctica lipase B in solvent free conditions. The synthesis of these polyesters was based on the ester-ester exchange reaction between ethylene glycol diacetate and di-ethyl glutarate, di-benzyl malonate, di-n-octyl phthalate to produce poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), respectively. The effect of ultrasound and PET polymeric beads on the polyester synthesis was evaluated and showed to improve the synthesis of all polyesters. Ultrasound, as a green solvent-free technology, showed high potentiality for the polyester synthesis intensification.
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spelling Lipase-ultrasound assisted synthesis of polyestersUltrasoundLipasePolyesterPET polymeric beadsScience & TechnologyPoly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), were enzymatically synthesized by immobilized Candida antarctica lipase B in solvent free conditions. The synthesis of these polyesters was based on the ester-ester exchange reaction between ethylene glycol diacetate and di-ethyl glutarate, di-benzyl malonate, di-n-octyl phthalate to produce poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), respectively. The effect of ultrasound and PET polymeric beads on the polyester synthesis was evaluated and showed to improve the synthesis of all polyesters. Ultrasound, as a green solvent-free technology, showed high potentiality for the polyester synthesis intensification.All authors gratefully acknowledge the financial support provided by International Joint Research Laboratory for Textile and Fibre Bioprocesses at Jiangnan University. The authors are also thankful to the Department of Chemical Engineering, Institute of Chemical Technology, Matunga (E), Mumbai-400019, India and to the Bioprocess and Bio nanotechnology Research Group (BBRG) of University of Minho. Authors would like also to acknowledge the Portuguese Foundation for Science and Technology (FCT) under the scope of the strategic funding of UID/BIO/04469/2013 unit and COMPETE 2020 (POCI-01-0145-FEDER-006684) and BioTecNorte operation (NORTE-01-0145-FEDER-000004) funded by European Regional Development Fund under the scope of Norte2020 Programa Operacional Regional do Norte and to the Fundamental Research Funds for the Central Universities (No. JUSRP51622A) 2016, Jiangsu Province Scientific Research Innovation Project for Academic Graduate Students (No. KYLX16_0788).info:eu-repo/semantics/publishedVersionElsevierUniversidade do MinhoTomke, Prerana D.Zhao, XiaomanChiplunkar, Pranali P.Xu, B.Wang, HongboSilva, CarlaRathod, Virendra K.Cavaco-Paulo, Artur2017-092017-09-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/46746engTomke, Prerana D.; Zhao, Xiaoman; Chiplunkar, Pranali P.; Xu, B.; Wang, Hongbo; Silva, Carla; Rathod, Virendra K.; Cavaco-Paulo, Artur, Lipase-ultrasound assisted synthesis of polyesters. Ultrasonics Sonochemistry, 38, 496-502, 20171350-417710.1016/j.ultsonch.2017.03.05128633852http://www.journals.elsevier.com/ultrasonics-sonochemistry/info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T11:56:59Zoai:repositorium.sdum.uminho.pt:1822/46746Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T18:46:40.391609Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Lipase-ultrasound assisted synthesis of polyesters
title Lipase-ultrasound assisted synthesis of polyesters
spellingShingle Lipase-ultrasound assisted synthesis of polyesters
Tomke, Prerana D.
Ultrasound
Lipase
Polyester
PET polymeric beads
Science & Technology
title_short Lipase-ultrasound assisted synthesis of polyesters
title_full Lipase-ultrasound assisted synthesis of polyesters
title_fullStr Lipase-ultrasound assisted synthesis of polyesters
title_full_unstemmed Lipase-ultrasound assisted synthesis of polyesters
title_sort Lipase-ultrasound assisted synthesis of polyesters
author Tomke, Prerana D.
author_facet Tomke, Prerana D.
Zhao, Xiaoman
Chiplunkar, Pranali P.
Xu, B.
Wang, Hongbo
Silva, Carla
Rathod, Virendra K.
Cavaco-Paulo, Artur
author_role author
author2 Zhao, Xiaoman
Chiplunkar, Pranali P.
Xu, B.
Wang, Hongbo
Silva, Carla
Rathod, Virendra K.
Cavaco-Paulo, Artur
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Tomke, Prerana D.
Zhao, Xiaoman
Chiplunkar, Pranali P.
Xu, B.
Wang, Hongbo
Silva, Carla
Rathod, Virendra K.
Cavaco-Paulo, Artur
dc.subject.por.fl_str_mv Ultrasound
Lipase
Polyester
PET polymeric beads
Science & Technology
topic Ultrasound
Lipase
Polyester
PET polymeric beads
Science & Technology
description Poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), were enzymatically synthesized by immobilized Candida antarctica lipase B in solvent free conditions. The synthesis of these polyesters was based on the ester-ester exchange reaction between ethylene glycol diacetate and di-ethyl glutarate, di-benzyl malonate, di-n-octyl phthalate to produce poly (ethylene glutarate), poly (ethylene malonate) and poly (ethylene phthalate), respectively. The effect of ultrasound and PET polymeric beads on the polyester synthesis was evaluated and showed to improve the synthesis of all polyesters. Ultrasound, as a green solvent-free technology, showed high potentiality for the polyester synthesis intensification.
publishDate 2017
dc.date.none.fl_str_mv 2017-09
2017-09-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/46746
url http://hdl.handle.net/1822/46746
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Tomke, Prerana D.; Zhao, Xiaoman; Chiplunkar, Pranali P.; Xu, B.; Wang, Hongbo; Silva, Carla; Rathod, Virendra K.; Cavaco-Paulo, Artur, Lipase-ultrasound assisted synthesis of polyesters. Ultrasonics Sonochemistry, 38, 496-502, 2017
1350-4177
10.1016/j.ultsonch.2017.03.051
28633852
http://www.journals.elsevier.com/ultrasonics-sonochemistry/
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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