Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Tipo de documento: | Dissertação |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.1/10731 |
Resumo: | An analytical procedure based on headspace – solid phase microextraction (HS-SPME) followed by gas chromatography-mass spectrometry (GC-MS) has been developed for the determination of free volatile fatty acids in municipal wastewater samples. Polydimethylsiloxane-Carboxen (PDMS-CAR) fibre was found to have greater affinity to extract lower chain fatty acids. Extraction and gas chromatographic parameters of importance such as desorption time, sample volume, amount of salt to be added and extraction time have been optimized. Detection limits were in the low to medium mg/L levels. To evaluate the applicability of the developed HS-SPME procedure on real samples, municipal wastewater treatment plant samples were analysed. |
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Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibreHeadspace-solid phase microextractionMunicipal wastewaterVFAsDomínio/Área Científica::Engenharia e Tecnologia::Outras Engenharias e TecnologiasAn analytical procedure based on headspace – solid phase microextraction (HS-SPME) followed by gas chromatography-mass spectrometry (GC-MS) has been developed for the determination of free volatile fatty acids in municipal wastewater samples. Polydimethylsiloxane-Carboxen (PDMS-CAR) fibre was found to have greater affinity to extract lower chain fatty acids. Extraction and gas chromatographic parameters of importance such as desorption time, sample volume, amount of salt to be added and extraction time have been optimized. Detection limits were in the low to medium mg/L levels. To evaluate the applicability of the developed HS-SPME procedure on real samples, municipal wastewater treatment plant samples were analysed.Zygmunt, BogdanBanel, AnnaSapientiaPokhrel, Teeka Ram2018-06-29T14:41:28Z2010-03-0220102010-03-02T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisapplication/pdfhttp://hdl.handle.net/10400.1/10731enginfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-24T10:22:23Zoai:sapientia.ualg.pt:10400.1/10731Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T20:02:20.820622Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
title |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
spellingShingle |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre Pokhrel, Teeka Ram Headspace-solid phase microextraction Municipal wastewater VFAs Domínio/Área Científica::Engenharia e Tecnologia::Outras Engenharias e Tecnologias |
title_short |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
title_full |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
title_fullStr |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
title_full_unstemmed |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
title_sort |
Determination of volatile fatty acids in municipal wastewater by gas chromatography-mass spectrometry preceded by headspace- solid phase microextraction with PDMS-CAR fibre |
author |
Pokhrel, Teeka Ram |
author_facet |
Pokhrel, Teeka Ram |
author_role |
author |
dc.contributor.none.fl_str_mv |
Zygmunt, Bogdan Banel, Anna Sapientia |
dc.contributor.author.fl_str_mv |
Pokhrel, Teeka Ram |
dc.subject.por.fl_str_mv |
Headspace-solid phase microextraction Municipal wastewater VFAs Domínio/Área Científica::Engenharia e Tecnologia::Outras Engenharias e Tecnologias |
topic |
Headspace-solid phase microextraction Municipal wastewater VFAs Domínio/Área Científica::Engenharia e Tecnologia::Outras Engenharias e Tecnologias |
description |
An analytical procedure based on headspace – solid phase microextraction (HS-SPME) followed by gas chromatography-mass spectrometry (GC-MS) has been developed for the determination of free volatile fatty acids in municipal wastewater samples. Polydimethylsiloxane-Carboxen (PDMS-CAR) fibre was found to have greater affinity to extract lower chain fatty acids. Extraction and gas chromatographic parameters of importance such as desorption time, sample volume, amount of salt to be added and extraction time have been optimized. Detection limits were in the low to medium mg/L levels. To evaluate the applicability of the developed HS-SPME procedure on real samples, municipal wastewater treatment plant samples were analysed. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-03-02 2010 2010-03-02T00:00:00Z 2018-06-29T14:41:28Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
format |
masterThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.1/10731 |
url |
http://hdl.handle.net/10400.1/10731 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
|
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1799133255833747456 |