Structure-property relations in ZrCN coatings for tribologic applications

Detalhes bibliográficos
Autor(a) principal: Silva, E.
Data de Publicação: 2010
Outros Autores: Figueiredo, M. Rebelo, Franz, R., Escobar Galindo, R., Palacio, C., Espinosa, A., Velasco, Sebastian Calderon, Mitterer, C., Carvalho, S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/1822/27573
Resumo: ZrCN coatings were deposited by dc reactive magnetron sputtering with N2 flows ranging from 2 to 10 sccm in order to investigate the influence of the nitrogen incorporation on structure and properties. Information about the chemical composition was obtained by glow discharge optical emission spectroscopy and Rutherford backscattering spectroscopy. The evolution of the crystal structure studied by X-ray diffraction revealed the formation of a face-centred cubic ZrCN phase for N2 flows greater than 4 sccm. Additionally, the presence of an amorphous phase in the coatings deposited with the highest N2 flows could be evidenced by Raman spectroscopy and X-ray photoelectron spectroscopy. This phase can act as a lubricant resulting in a low coefficient of friction as shown in the conducted ball-on-disc tests. Nanoindentation measurements showed that coatings deposited with a 6 sccm N2 flow had the maximum hardness which also revealed the best performance in the conducted dry cutting tests.
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spelling Structure-property relations in ZrCN coatings for tribologic applicationsZrCNPVDMagnetron sputteringMetal-containing coatingHardnessTribologyScience & TechnologyZrCN coatings were deposited by dc reactive magnetron sputtering with N2 flows ranging from 2 to 10 sccm in order to investigate the influence of the nitrogen incorporation on structure and properties. Information about the chemical composition was obtained by glow discharge optical emission spectroscopy and Rutherford backscattering spectroscopy. The evolution of the crystal structure studied by X-ray diffraction revealed the formation of a face-centred cubic ZrCN phase for N2 flows greater than 4 sccm. Additionally, the presence of an amorphous phase in the coatings deposited with the highest N2 flows could be evidenced by Raman spectroscopy and X-ray photoelectron spectroscopy. This phase can act as a lubricant resulting in a low coefficient of friction as shown in the conducted ball-on-disc tests. Nanoindentation measurements showed that coatings deposited with a 6 sccm N2 flow had the maximum hardness which also revealed the best performance in the conducted dry cutting tests.CRUP InstitutionSpanish Ministry of Science and InnovationChristian Doppler Research AssociationElsevierUniversidade do MinhoSilva, E.Figueiredo, M. RebeloFranz, R.Escobar Galindo, R.Palacio, C.Espinosa, A.Velasco, Sebastian CalderonMitterer, C.Carvalho, S.2010-09-072010-09-07T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/1822/27573eng0257-897210.1016/j.surfcoat.2010.08.126info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-07-21T12:46:34Zoai:repositorium.sdum.uminho.pt:1822/27573Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T19:44:34.773971Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Structure-property relations in ZrCN coatings for tribologic applications
title Structure-property relations in ZrCN coatings for tribologic applications
spellingShingle Structure-property relations in ZrCN coatings for tribologic applications
Silva, E.
ZrCN
PVD
Magnetron sputtering
Metal-containing coating
Hardness
Tribology
Science & Technology
title_short Structure-property relations in ZrCN coatings for tribologic applications
title_full Structure-property relations in ZrCN coatings for tribologic applications
title_fullStr Structure-property relations in ZrCN coatings for tribologic applications
title_full_unstemmed Structure-property relations in ZrCN coatings for tribologic applications
title_sort Structure-property relations in ZrCN coatings for tribologic applications
author Silva, E.
author_facet Silva, E.
Figueiredo, M. Rebelo
Franz, R.
Escobar Galindo, R.
Palacio, C.
Espinosa, A.
Velasco, Sebastian Calderon
Mitterer, C.
Carvalho, S.
author_role author
author2 Figueiredo, M. Rebelo
Franz, R.
Escobar Galindo, R.
Palacio, C.
Espinosa, A.
Velasco, Sebastian Calderon
Mitterer, C.
Carvalho, S.
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade do Minho
dc.contributor.author.fl_str_mv Silva, E.
Figueiredo, M. Rebelo
Franz, R.
Escobar Galindo, R.
Palacio, C.
Espinosa, A.
Velasco, Sebastian Calderon
Mitterer, C.
Carvalho, S.
dc.subject.por.fl_str_mv ZrCN
PVD
Magnetron sputtering
Metal-containing coating
Hardness
Tribology
Science & Technology
topic ZrCN
PVD
Magnetron sputtering
Metal-containing coating
Hardness
Tribology
Science & Technology
description ZrCN coatings were deposited by dc reactive magnetron sputtering with N2 flows ranging from 2 to 10 sccm in order to investigate the influence of the nitrogen incorporation on structure and properties. Information about the chemical composition was obtained by glow discharge optical emission spectroscopy and Rutherford backscattering spectroscopy. The evolution of the crystal structure studied by X-ray diffraction revealed the formation of a face-centred cubic ZrCN phase for N2 flows greater than 4 sccm. Additionally, the presence of an amorphous phase in the coatings deposited with the highest N2 flows could be evidenced by Raman spectroscopy and X-ray photoelectron spectroscopy. This phase can act as a lubricant resulting in a low coefficient of friction as shown in the conducted ball-on-disc tests. Nanoindentation measurements showed that coatings deposited with a 6 sccm N2 flow had the maximum hardness which also revealed the best performance in the conducted dry cutting tests.
publishDate 2010
dc.date.none.fl_str_mv 2010-09-07
2010-09-07T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1822/27573
url http://hdl.handle.net/1822/27573
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 0257-8972
10.1016/j.surfcoat.2010.08.126
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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