Structure–elasticity relationships in hybrid-carrageenan hydrogels studied by image dynamic light scattering, ultra-small-angle light scattering and dynamic rheometry

• Autor(a) principal: Yahia, Amine Ben
• Data de Publicação: 2024
• Outros Autores: Aschi, Adel, Faria, Bruno Miguel Silva, Hilliou, L.
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: https://hdl.handle.net/1822/92960
• topic: Hybrid carrageenan; Image dynamic light scattering (IDLS); Ultra-small-angle light scattering (USALS); Pair-distance distribution function P(r); Rheology; Strain hardening; Engenharia e Tecnologia::Engenharia dos Materiais; Produção e consumo sustentáveis

Hybrid-carrageenan hydrogels are characterized using novel techniques based on high- resolution speckle imaging, namely image dynamic light scattering (IDLS) and ultra-small-angle light scattering (USALS). These techniques, used to probe the microscopic structure of the system in sol–gel phase separation and at different concentrations in the gel phase, give access to a better understanding of the network’s topology on the basis of fractals in the dense phase. Observations of the architecture and the spatial and the size distributions of gel phase and fractal dimension were performed by USALS. The pair-distance distribution function, P(r), extracted from USALS patterns, is a new methodology of calculus for determining the network’s internal size with precision. All structural features are systematically compared with a linear and non-linear rheological characterization of the gels and structure–elasticity relationships are identified in the framework of fractal colloid gels in the diffusion limit.