Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives

Detalhes bibliográficos
Autor(a) principal: Cruz, Hugo
Data de Publicação: 2023
Outros Autores: Jordão, Noemi, Santiago, Sara, Gago, Sandra, Villabona, Marc, Hernando, Jordi, Guirado, Gonzalo, Branco, Luís C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/164076
Resumo: Funding Information: This work was supported by the Associate Laboratory for Green Chemistry‐LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). The authors thank the Portuguese Foundation for Science and Technology/MCTES. For funding of the project “SunStorage‐ Harvesting and storage of solar energy”, with reference POCI‐01‐0145‐FEDER‐016387, and the position of Hugo Cruz in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree‐Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Marc Villabona, Sara Santiago, Jordi Hernando and Gonzalo Guirado thank the Agencia Estatal de Investigación (PID2019‐106171RB‐100/AEI/10.13039/501100011033 project) of Spain for financial support. Marc Villabona thank the Spanish Ministry for Education, Culture, and Sports for his predoctoral FPU. Publisher Copyright: © 2022 The Authors. Electrochemical Science Advances published by Wiley-VCH GmbH.
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spelling Photo-electrochromic salt composed by viologen cation and diarylethene anion derivativesdiarylethene anionionic Liquidsmulti-stimuli responsive materialsphoto-electrochromismviologen cationChemistry (miscellaneous)ElectrochemistryFunding Information: This work was supported by the Associate Laboratory for Green Chemistry‐LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). The authors thank the Portuguese Foundation for Science and Technology/MCTES. For funding of the project “SunStorage‐ Harvesting and storage of solar energy”, with reference POCI‐01‐0145‐FEDER‐016387, and the position of Hugo Cruz in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree‐Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Marc Villabona, Sara Santiago, Jordi Hernando and Gonzalo Guirado thank the Agencia Estatal de Investigación (PID2019‐106171RB‐100/AEI/10.13039/501100011033 project) of Spain for financial support. Marc Villabona thank the Spanish Ministry for Education, Culture, and Sports for his predoctoral FPU. Publisher Copyright: © 2022 The Authors. Electrochemical Science Advances published by Wiley-VCH GmbH.A multi-responsive photo and electrochromic salt based on a viologen derivative ([(C10)2Bpy]2+) as organic cation combined with diarylethene anion ([DTE]2−) is synthesized and characterized for the first time. The coloration of this functional salt can be modulated by light and electricity according to further applications. Photochemical determination of the quantum yields in solution for the ring-opening and closure of [(C10)2Bpy][DTE-COO] ionic liquid have been determined. The electrochemical and electrochromism performance have been also studied in order to evaluate the reduction of bipyridinium cation as well as the oxidation of the DTE anion in its open and closed forms. The possibility of individually addressing the redox state of the anion and cation is seen as a very attractive approach to designing photo-electrochromic devices.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNCruz, HugoJordão, NoemiSantiago, SaraGago, SandraVillabona, MarcHernando, JordiGuirado, GonzaloBranco, Luís C.2024-02-23T23:55:31Z2023-102023-10-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article7application/pdfhttp://hdl.handle.net/10362/164076eng2698-5977PURE: 83887150https://doi.org/10.1002/elsa.202100022info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:50:41Zoai:run.unl.pt:10362/164076Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T04:00:02.090308Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
title Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
spellingShingle Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
Cruz, Hugo
diarylethene anion
ionic Liquids
multi-stimuli responsive materials
photo-electrochromism
viologen cation
Chemistry (miscellaneous)
Electrochemistry
title_short Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
title_full Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
title_fullStr Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
title_full_unstemmed Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
title_sort Photo-electrochromic salt composed by viologen cation and diarylethene anion derivatives
author Cruz, Hugo
author_facet Cruz, Hugo
Jordão, Noemi
Santiago, Sara
Gago, Sandra
Villabona, Marc
Hernando, Jordi
Guirado, Gonzalo
Branco, Luís C.
author_role author
author2 Jordão, Noemi
Santiago, Sara
Gago, Sandra
Villabona, Marc
Hernando, Jordi
Guirado, Gonzalo
Branco, Luís C.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Cruz, Hugo
Jordão, Noemi
Santiago, Sara
Gago, Sandra
Villabona, Marc
Hernando, Jordi
Guirado, Gonzalo
Branco, Luís C.
dc.subject.por.fl_str_mv diarylethene anion
ionic Liquids
multi-stimuli responsive materials
photo-electrochromism
viologen cation
Chemistry (miscellaneous)
Electrochemistry
topic diarylethene anion
ionic Liquids
multi-stimuli responsive materials
photo-electrochromism
viologen cation
Chemistry (miscellaneous)
Electrochemistry
description Funding Information: This work was supported by the Associate Laboratory for Green Chemistry‐LAQV which is financed by national funds from FCT/MCTES (UID/QUI/50006/2019). The authors thank the Portuguese Foundation for Science and Technology/MCTES. For funding of the project “SunStorage‐ Harvesting and storage of solar energy”, with reference POCI‐01‐0145‐FEDER‐016387, and the position of Hugo Cruz in the scope of the framework contract foreseen in the numbers 4, 5, and 6 of article 23 of the Decree‐Law 57/2016 of 29 August, changed by Law 57/2017 of 19 July. Marc Villabona, Sara Santiago, Jordi Hernando and Gonzalo Guirado thank the Agencia Estatal de Investigación (PID2019‐106171RB‐100/AEI/10.13039/501100011033 project) of Spain for financial support. Marc Villabona thank the Spanish Ministry for Education, Culture, and Sports for his predoctoral FPU. Publisher Copyright: © 2022 The Authors. Electrochemical Science Advances published by Wiley-VCH GmbH.
publishDate 2023
dc.date.none.fl_str_mv 2023-10
2023-10-01T00:00:00Z
2024-02-23T23:55:31Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/164076
url http://hdl.handle.net/10362/164076
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 2698-5977
PURE: 83887150
https://doi.org/10.1002/elsa.202100022
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
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repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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