The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture

Detalhes bibliográficos
Autor(a) principal: Barrulas, Raquel V.
Data de Publicação: 2021
Outros Autores: López‐iglesias, Clara, Zanatta, Marcileia, Casimiro, Teresa, Mármol, Gonzalo, Carrott, Manuela Ribeiro, García‐gonzález, Carlos A., Corvo, Marta C.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/134339
Resumo: UIDB/50025/2020-2023 UID/QUI/50006/2019 UIDB/50006/2020|UIDP/50006/2020 PTDC/QUI-QFI/31508/2017 PTNMR-ROTEIRO/0031/2013 PINFRA/22161/2016 COMPETE 2020, PT2020 POCI-01-0145-FEDER-007688 POCI-01-0145-FEDER-007265 ED431C 2020/17 PID2020-120010RB-I00 SFRH/BD/150662/2020 ED481B-2021-008 CA18125
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spelling The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 captureAdsorptionAerogelChitosanCO capturePolymeric ionic liquidsPorosity inductionCatalysisMolecular BiologySpectroscopyComputer Science ApplicationsPhysical and Theoretical ChemistryOrganic ChemistryInorganic ChemistrySDG 13 - Climate ActionUIDB/50025/2020-2023 UID/QUI/50006/2019 UIDB/50006/2020|UIDP/50006/2020 PTDC/QUI-QFI/31508/2017 PTNMR-ROTEIRO/0031/2013 PINFRA/22161/2016 COMPETE 2020, PT2020 POCI-01-0145-FEDER-007688 POCI-01-0145-FEDER-007265 ED431C 2020/17 PID2020-120010RB-I00 SFRH/BD/150662/2020 ED481B-2021-008 CA18125CO2 levels in the atmosphere are increasing exponentially. The current climate change effects motivate an urgent need for new and sustainable materials to capture CO2. Porous materials are particularly interesting for processes that take place near atmospheric pressure. However, materials design should not only consider the morphology, but also the chemical identity of the CO2 sorbent to enhance the affinity towards CO2. Poly(ionic liquid)s (PILs) can enhance CO2 sorption capacity, but tailoring the porosity is still a challenge. Aerogel’s properties grant production strategies that ensure a porosity control. In this work, we joined both worlds, PILs and aerogels, to produce a sustainable CO2 sorbent. PIL‐chitosan aerogels (AEROPILs) in the form of beads were successfully obtained with high porosity (94.6–97.0 %) and surface areas (270–744 m2/g). AEROPILs were applied for the first time as CO2 sorbents. The combination of PILs with chitosan aerogels generally increased the CO2 sorption capability of these materials, being the maximum CO2 capture capacity obtained (0.70 mmol g−1, at 25 °C and 1 bar) for the CHT:P[DADMA]Cl30% AEROPIL.CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)DCM - Departamento de Ciência dos MateriaisLAQV@REQUIMTEDQ - Departamento de QuímicaRUNBarrulas, Raquel V.López‐iglesias, ClaraZanatta, MarcileiaCasimiro, TeresaMármol, GonzaloCarrott, Manuela RibeiroGarcía‐gonzález, Carlos A.Corvo, Marta C.2022-03-11T23:22:07Z2021-12-242021-12-24T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/134339eng1661-6596PURE: 35998840https://doi.org/10.3390/ijms23010200info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-22T18:00:07Zoai:run.unl.pt:10362/134339Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-22T18:00:07Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
title The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
spellingShingle The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
Barrulas, Raquel V.
Adsorption
Aerogel
Chitosan
CO capture
Polymeric ionic liquids
Porosity induction
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
SDG 13 - Climate Action
title_short The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
title_full The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
title_fullStr The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
title_full_unstemmed The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
title_sort The AEROPILs generation: Novel poly(ionic liquid)‐based aerogels for CO2 capture
author Barrulas, Raquel V.
author_facet Barrulas, Raquel V.
López‐iglesias, Clara
Zanatta, Marcileia
Casimiro, Teresa
Mármol, Gonzalo
Carrott, Manuela Ribeiro
García‐gonzález, Carlos A.
Corvo, Marta C.
author_role author
author2 López‐iglesias, Clara
Zanatta, Marcileia
Casimiro, Teresa
Mármol, Gonzalo
Carrott, Manuela Ribeiro
García‐gonzález, Carlos A.
Corvo, Marta C.
author2_role author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv CENIMAT-i3N - Centro de Investigação de Materiais (Lab. Associado I3N)
DCM - Departamento de Ciência dos Materiais
LAQV@REQUIMTE
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Barrulas, Raquel V.
López‐iglesias, Clara
Zanatta, Marcileia
Casimiro, Teresa
Mármol, Gonzalo
Carrott, Manuela Ribeiro
García‐gonzález, Carlos A.
Corvo, Marta C.
dc.subject.por.fl_str_mv Adsorption
Aerogel
Chitosan
CO capture
Polymeric ionic liquids
Porosity induction
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
SDG 13 - Climate Action
topic Adsorption
Aerogel
Chitosan
CO capture
Polymeric ionic liquids
Porosity induction
Catalysis
Molecular Biology
Spectroscopy
Computer Science Applications
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
SDG 13 - Climate Action
description UIDB/50025/2020-2023 UID/QUI/50006/2019 UIDB/50006/2020|UIDP/50006/2020 PTDC/QUI-QFI/31508/2017 PTNMR-ROTEIRO/0031/2013 PINFRA/22161/2016 COMPETE 2020, PT2020 POCI-01-0145-FEDER-007688 POCI-01-0145-FEDER-007265 ED431C 2020/17 PID2020-120010RB-I00 SFRH/BD/150662/2020 ED481B-2021-008 CA18125
publishDate 2021
dc.date.none.fl_str_mv 2021-12-24
2021-12-24T00:00:00Z
2022-03-11T23:22:07Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/134339
url http://hdl.handle.net/10362/134339
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 1661-6596
PURE: 35998840
https://doi.org/10.3390/ijms23010200
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv mluisa.alvim@gmail.com
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