A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route
Autor(a) principal: | |
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Data de Publicação: | 2019 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/36659 |
Resumo: | Fe-doped TiO2 thin films are deposited both on the (1 0 0) oriented Si and glass substrates by pulsed laser deposition technique using Fe powder doped TiO2 ceramic target. The structural and optical properties of the film have been studied in detail. The degree of film crystallinity is investigated by X-ray diffraction and confirmed by Raman scattering measurements. The stoichiometry and chemical states of Fe, Ti and O are probed by X-ray photoelectron spectroscopy. The surface morphologies are observed by Scanning electron microscopy. The optical properties are studied by measuring the transmittance and the optical constants, the refractive index and the extinction coefficient. It is found that the substrate temperature is a key factor in determining the thin film structure which further influences the refractive index and the optical band gap of the film. An anatase structure emerges above 300 °C while the rutile structure appears when the substrate temperature is higher than 500 °C. Another result is that Fe exists in the deposited films as Fe3+ and the atomic concentration of Fe in the films is much lower than that in the source target. |
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A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition routeFe-doped TiO2Structural propertiesOptical propertiesPLDThin FilmFe-doped TiO2 thin films are deposited both on the (1 0 0) oriented Si and glass substrates by pulsed laser deposition technique using Fe powder doped TiO2 ceramic target. The structural and optical properties of the film have been studied in detail. The degree of film crystallinity is investigated by X-ray diffraction and confirmed by Raman scattering measurements. The stoichiometry and chemical states of Fe, Ti and O are probed by X-ray photoelectron spectroscopy. The surface morphologies are observed by Scanning electron microscopy. The optical properties are studied by measuring the transmittance and the optical constants, the refractive index and the extinction coefficient. It is found that the substrate temperature is a key factor in determining the thin film structure which further influences the refractive index and the optical band gap of the film. An anatase structure emerges above 300 °C while the rutile structure appears when the substrate temperature is higher than 500 °C. Another result is that Fe exists in the deposited films as Fe3+ and the atomic concentration of Fe in the films is much lower than that in the source target.Elsevier2023-03-27T14:06:53Z2019-04-30T00:00:00Z2019-04-30info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10773/36659eng0169-433210.1016/j.apsusc.2018.03.043Meng, LijianWang, ZhenhuaYang, LiangRen, WeijunLiu, WeiZhang, ZhidongTao, Yangdos Santos, M.P.info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-02-22T12:10:43Zoai:ria.ua.pt:10773/36659Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:07:24.413968Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
title |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
spellingShingle |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route Meng, Lijian Fe-doped TiO2 Structural properties Optical properties PLD Thin Film |
title_short |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
title_full |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
title_fullStr |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
title_full_unstemmed |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
title_sort |
A detailed study on the Fe-doped TiO2 thin films induced by pulsed laser deposition route |
author |
Meng, Lijian |
author_facet |
Meng, Lijian Wang, Zhenhua Yang, Liang Ren, Weijun Liu, Wei Zhang, Zhidong Tao, Yang dos Santos, M.P. |
author_role |
author |
author2 |
Wang, Zhenhua Yang, Liang Ren, Weijun Liu, Wei Zhang, Zhidong Tao, Yang dos Santos, M.P. |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Meng, Lijian Wang, Zhenhua Yang, Liang Ren, Weijun Liu, Wei Zhang, Zhidong Tao, Yang dos Santos, M.P. |
dc.subject.por.fl_str_mv |
Fe-doped TiO2 Structural properties Optical properties PLD Thin Film |
topic |
Fe-doped TiO2 Structural properties Optical properties PLD Thin Film |
description |
Fe-doped TiO2 thin films are deposited both on the (1 0 0) oriented Si and glass substrates by pulsed laser deposition technique using Fe powder doped TiO2 ceramic target. The structural and optical properties of the film have been studied in detail. The degree of film crystallinity is investigated by X-ray diffraction and confirmed by Raman scattering measurements. The stoichiometry and chemical states of Fe, Ti and O are probed by X-ray photoelectron spectroscopy. The surface morphologies are observed by Scanning electron microscopy. The optical properties are studied by measuring the transmittance and the optical constants, the refractive index and the extinction coefficient. It is found that the substrate temperature is a key factor in determining the thin film structure which further influences the refractive index and the optical band gap of the film. An anatase structure emerges above 300 °C while the rutile structure appears when the substrate temperature is higher than 500 °C. Another result is that Fe exists in the deposited films as Fe3+ and the atomic concentration of Fe in the films is much lower than that in the source target. |
publishDate |
2019 |
dc.date.none.fl_str_mv |
2019-04-30T00:00:00Z 2019-04-30 2023-03-27T14:06:53Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/36659 |
url |
http://hdl.handle.net/10773/36659 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
0169-4332 10.1016/j.apsusc.2018.03.043 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799137729278115840 |