Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/11110/2230 |
Resumo: | The present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage. |
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Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological AdhesivesMicroencapsulationMicrofluidicEco-friendlyAdhesivesThe present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage.Polymer Bulletin2021-11-25T15:30:33Z2021-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://hdl.handle.net/11110/2230oai:ciencipca.ipca.pt:11110/2230engCosta, Mariana; e.a., Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives, Polymer Bulletin (2021) DOI 10.1007/s00289-021-03690-1https://doi.org/10.1007/s00289-021-03690-1http://hdl.handle.net/11110/2230metadata only accessinfo:eu-repo/semantics/openAccessCosta, MarianaPinho, IsabelLoureiro, MonicaMarques, AnaSimões, CarlaSimoes, Ricardoreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2022-09-05T12:53:31Zoai:ciencipca.ipca.pt:11110/2230Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T15:02:30.490009Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
title |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
spellingShingle |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives Costa, Mariana Microencapsulation Microfluidic Eco-friendly Adhesives |
title_short |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
title_full |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
title_fullStr |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
title_full_unstemmed |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
title_sort |
Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives |
author |
Costa, Mariana |
author_facet |
Costa, Mariana Pinho, Isabel Loureiro, Monica Marques, Ana Simões, Carla Simoes, Ricardo |
author_role |
author |
author2 |
Pinho, Isabel Loureiro, Monica Marques, Ana Simões, Carla Simoes, Ricardo |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Costa, Mariana Pinho, Isabel Loureiro, Monica Marques, Ana Simões, Carla Simoes, Ricardo |
dc.subject.por.fl_str_mv |
Microencapsulation Microfluidic Eco-friendly Adhesives |
topic |
Microencapsulation Microfluidic Eco-friendly Adhesives |
description |
The present paper reports a continuous microfluidic approach for the preparation of microcapsules (MCs), by interfacial polymerization, with a polyurea/polyurethane (PUa/PU) shell containing isophorone diisocyanate (IPDI). The microfluidic system enables the formation of a monodisperse oil-in-water (O/W) emulsion by a separate flow of the reagents along the tubing system, which posteriorly meet at a cross-junction, resulting in the precise formation of one emulsion droplet at a time. The developed MCs are intended to be part of a new monocomponent, autoreactive and ecological adhesive, as cross-linking agents. Critical operational parameters in the microfluidic process were investigated, namely the flow rate of the emulsion phases, the cross-junction’s configuration and its correlation with the MCs’ morphology, average diameter, size distribution and amount of encapsulated isocyanate. The advances achieved in the current study represent a contribution to the development of new sustainable and eco-friendly products, where the employment of monodisperse MCs is an advantage. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-11-25T15:30:33Z 2021-01-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/11110/2230 oai:ciencipca.ipca.pt:11110/2230 |
url |
http://hdl.handle.net/11110/2230 |
identifier_str_mv |
oai:ciencipca.ipca.pt:11110/2230 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Costa, Mariana; e.a., Optimization of a Microfluidic Process to Encapsulate Isocyanate for Autoreactive and Ecological Adhesives, Polymer Bulletin (2021) DOI 10.1007/s00289-021-03690-1 https://doi.org/10.1007/s00289-021-03690-1 http://hdl.handle.net/11110/2230 |
dc.rights.driver.fl_str_mv |
metadata only access info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
metadata only access |
eu_rights_str_mv |
openAccess |
dc.publisher.none.fl_str_mv |
Polymer Bulletin |
publisher.none.fl_str_mv |
Polymer Bulletin |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799129894995623936 |