Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10362/133133 |
Resumo: | UIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020 |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic AcidAcetic acidCarbonEthane oxidationGoldHeterogeneous catalysisCatalysisPhysical and Theoretical ChemistryUIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020The single-pot efficient oxidation of ethane to acetic acid catalysed by Au(I) or Au(III) compounds, chlorotriphenylphosphinegold(I) (1), chlorotrimethylphosphinegold(I) (2), 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidenegold(I) chloride (3), dichloro(2-pyridinecarboxylato)gold(III) (4), homogenous and supported on different carbon materials: activated carbon (AC), multi-walled carbon nanotubes (CNT) and carbon xerogel (CX), oxidised with nitric acid followed by treatment with NaOH (-ox-Na), is reported. The reactions were performed in water/acetonitrile. The materials were selective for the production of acetic acid, with no trace of by-products being detected. The best homogenous catalysts were complexes 2 and 3 which showed the highest ethane conversion and an acetic acid yield of ca. 21%, followed by 4 and 1. The heterogenised materials showed much better activity than the homogenous counterparts, with acetic acid yields up to 41.4% for 4@CNT-ox-Na, and remarkable selectivity (with acetic acid being the only product detected). The heterogenised catalysts with the best results were reused up to five cycles, with no significant loss of activity, and maintaining high selectivity for acetic acid. 4@CNT-ox-Na showed not only the best catalytic activity but also the best stability during the recycling runs.LAQV@REQUIMTEDQ - Departamento de QuímicaRUNRibeiro, Ana P. C.Matias, Inês A. S.Carabineiro, Sónia A. C.Martins, Luísa M. D. R. S.2022-02-17T23:19:48Z2022-022022-02-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/133133eng2073-4344PURE: 36734554https://doi.org/10.3390/catal12020165info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:11:49Zoai:run.unl.pt:10362/133133Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:47:42.935379Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
title |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
spellingShingle |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid Ribeiro, Ana P. C. Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
title_short |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
title_full |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
title_fullStr |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
title_full_unstemmed |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
title_sort |
Commercial Gold Complexes Supported on Functionalised Carbon Materials as Efficient Catalysts for the Direct Oxidation of Ethane to Acetic Acid |
author |
Ribeiro, Ana P. C. |
author_facet |
Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
author_role |
author |
author2 |
Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
LAQV@REQUIMTE DQ - Departamento de Química RUN |
dc.contributor.author.fl_str_mv |
Ribeiro, Ana P. C. Matias, Inês A. S. Carabineiro, Sónia A. C. Martins, Luísa M. D. R. S. |
dc.subject.por.fl_str_mv |
Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
topic |
Acetic acid Carbon Ethane oxidation Gold Heterogeneous catalysis Catalysis Physical and Theoretical Chemistry |
description |
UIDB/00100/2020 UIDP/00100/2020 LA/P/0056/2020 IST-ID/119/2018 SFRH/BD/146426/2019 CEEC-INST/00102/2018 UIDB/50006/2020 UIDP/50006/2020 Base-UIDB/50020/2020 Programmatic-UIDP/50020/2020 |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-02-17T23:19:48Z 2022-02 2022-02-01T00:00:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10362/133133 |
url |
http://hdl.handle.net/10362/133133 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
2073-4344 PURE: 36734554 https://doi.org/10.3390/catal12020165 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
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reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
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1799138080067682304 |