Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10400.22/21824 |
Resumo: | Recovery of bioactive compounds from biowaste is gaining more and more interest in circular economy models. The oilseed cakes are usually insufficiently exploited by most technologies since they represent valuable matrices abundant in proteins, minerals, and phytochemicals, but their use is mostly limited to feed ingredients, fertilizers or biofuel production. This study was thus focused on the exploration of new valorization pathways of oilseed cakes by subcritical water, representing a safe and economic alternative in the creation of value chains. Pumpkin, hemp, and flax seed cakes were treated with subcritical water in nitrogen and carbon-dioxide atmospheres, as well as in nitrogen atmosphere with the addition of acid catalyst. The degradation of carbohydrate fraction was studied by quantifying sugars and sugar degradation products in the obtained extracts. The extracts obtained under different conditions were further compared chemically with respect to total phenols and flavonoids, as well as to the content of individual phenolic compounds. Furthermore, the effects of subcritical water treatment conditions on antioxidant, antiradical and cytotoxic properties of thus obtained extracts were defined and discussed. |
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Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical waterOilseed cakesSubcritical waterValorizationPhenolicsSugarsBioactivityRecovery of bioactive compounds from biowaste is gaining more and more interest in circular economy models. The oilseed cakes are usually insufficiently exploited by most technologies since they represent valuable matrices abundant in proteins, minerals, and phytochemicals, but their use is mostly limited to feed ingredients, fertilizers or biofuel production. This study was thus focused on the exploration of new valorization pathways of oilseed cakes by subcritical water, representing a safe and economic alternative in the creation of value chains. Pumpkin, hemp, and flax seed cakes were treated with subcritical water in nitrogen and carbon-dioxide atmospheres, as well as in nitrogen atmosphere with the addition of acid catalyst. The degradation of carbohydrate fraction was studied by quantifying sugars and sugar degradation products in the obtained extracts. The extracts obtained under different conditions were further compared chemically with respect to total phenols and flavonoids, as well as to the content of individual phenolic compounds. Furthermore, the effects of subcritical water treatment conditions on antioxidant, antiradical and cytotoxic properties of thus obtained extracts were defined and discussed.This research was funded by the Italian Ministry of University (MIUR) call PRIN2017, project 2017LEPH3M “PANACEA: A technology PlAtform for the sustainable recovery and advanced use of NAnostructured CEllulose from Agro-food residues” and the Ministry of Science and Higher Education of the Russian Federation within the project MEGAgrant. This work was also funded by the Science Fund of the Republic of Serbia (Grant No. 7747845, In situ pollutants removal from waters by sustainable green nanotechnologies—CleanNanoCatalyze), the Portuguese Foundation for Science and Technology (project 5537 DRI, Sérvia 2020/21), are also acknowledged. The work was also supported by the FCT/MCTES through national funds, FEDER (through COMPETE funds) and Fundação para a Ciência e Tecnologia (project UIDB/50006/2020) and the Ministry of education, science and technological development of the Republic of Serbia (Grant No 451-03-68/2020–14/200134).SpringerRepositório Científico do Instituto Politécnico do PortoŠvarc-Gajić, JaroslavaRodrigues, FranciscaMoreira, Manuela M.Delerue-Matos, CristinaMorais, SimoneDorosh, OlenaSilva, Ana MargaridaBassani, AndreaDzedik, ValentinSpigno, Giorgia2023-01-24T14:58:02Z20222022-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.22/21824eng10.1186/s40643-022-00603-6info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-03-13T13:18:09Zoai:recipp.ipp.pt:10400.22/21824Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T17:41:54.774890Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
title |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
spellingShingle |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water Švarc-Gajić, Jaroslava Oilseed cakes Subcritical water Valorization Phenolics Sugars Bioactivity |
title_short |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
title_full |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
title_fullStr |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
title_full_unstemmed |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
title_sort |
Chemical composition and bioactivity of oilseed cake extracts obtained by subcritical and modified subcritical water |
author |
Švarc-Gajić, Jaroslava |
author_facet |
Švarc-Gajić, Jaroslava Rodrigues, Francisca Moreira, Manuela M. Delerue-Matos, Cristina Morais, Simone Dorosh, Olena Silva, Ana Margarida Bassani, Andrea Dzedik, Valentin Spigno, Giorgia |
author_role |
author |
author2 |
Rodrigues, Francisca Moreira, Manuela M. Delerue-Matos, Cristina Morais, Simone Dorosh, Olena Silva, Ana Margarida Bassani, Andrea Dzedik, Valentin Spigno, Giorgia |
author2_role |
author author author author author author author author author |
dc.contributor.none.fl_str_mv |
Repositório Científico do Instituto Politécnico do Porto |
dc.contributor.author.fl_str_mv |
Švarc-Gajić, Jaroslava Rodrigues, Francisca Moreira, Manuela M. Delerue-Matos, Cristina Morais, Simone Dorosh, Olena Silva, Ana Margarida Bassani, Andrea Dzedik, Valentin Spigno, Giorgia |
dc.subject.por.fl_str_mv |
Oilseed cakes Subcritical water Valorization Phenolics Sugars Bioactivity |
topic |
Oilseed cakes Subcritical water Valorization Phenolics Sugars Bioactivity |
description |
Recovery of bioactive compounds from biowaste is gaining more and more interest in circular economy models. The oilseed cakes are usually insufficiently exploited by most technologies since they represent valuable matrices abundant in proteins, minerals, and phytochemicals, but their use is mostly limited to feed ingredients, fertilizers or biofuel production. This study was thus focused on the exploration of new valorization pathways of oilseed cakes by subcritical water, representing a safe and economic alternative in the creation of value chains. Pumpkin, hemp, and flax seed cakes were treated with subcritical water in nitrogen and carbon-dioxide atmospheres, as well as in nitrogen atmosphere with the addition of acid catalyst. The degradation of carbohydrate fraction was studied by quantifying sugars and sugar degradation products in the obtained extracts. The extracts obtained under different conditions were further compared chemically with respect to total phenols and flavonoids, as well as to the content of individual phenolic compounds. Furthermore, the effects of subcritical water treatment conditions on antioxidant, antiradical and cytotoxic properties of thus obtained extracts were defined and discussed. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022 2022-01-01T00:00:00Z 2023-01-24T14:58:02Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10400.22/21824 |
url |
http://hdl.handle.net/10400.22/21824 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1186/s40643-022-00603-6 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799131505531813888 |