A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption

Detalhes bibliográficos
Autor(a) principal: Bastin, Laurent
Data de Publicação: 2008
Outros Autores: Bárcia, Patrick da Silva, Hurtado, Eric, Silva, José A.C., Rodrigues, Alírio, Chen, Banglin
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10198/3271
Resumo: A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process.
id RCAP_d8936a78455f5e941f52dec25a06480e
oai_identifier_str oai:bibliotecadigital.ipb.pt:10198/3271
network_acronym_str RCAP
network_name_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository_id_str 7160
spelling A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorptionAdsorptionA microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process.American Chemical SocietyBiblioteca Digital do IPBBastin, LaurentBárcia, Patrick da SilvaHurtado, EricSilva, José A.C.Rodrigues, AlírioChen, Banglin2011-02-04T16:04:09Z20082008-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/3271engBastin, Laurent; Barcia, Patrick; Hurtado, Eric; Silva, Jose A. C.; Rodrigues, Alirio; Chen, Banglin (2008). A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. Journal od Physical Chemistry C. ISSN 1932-7447. 112:5, p. 1575-15811932-744710.1021/jp077618ginfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:08:32Zoai:bibliotecadigital.ipb.pt:10198/3271Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T22:56:12.503406Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
title A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
spellingShingle A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
Bastin, Laurent
Adsorption
title_short A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
title_full A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
title_fullStr A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
title_full_unstemmed A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
title_sort A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
author Bastin, Laurent
author_facet Bastin, Laurent
Bárcia, Patrick da Silva
Hurtado, Eric
Silva, José A.C.
Rodrigues, Alírio
Chen, Banglin
author_role author
author2 Bárcia, Patrick da Silva
Hurtado, Eric
Silva, José A.C.
Rodrigues, Alírio
Chen, Banglin
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Biblioteca Digital do IPB
dc.contributor.author.fl_str_mv Bastin, Laurent
Bárcia, Patrick da Silva
Hurtado, Eric
Silva, José A.C.
Rodrigues, Alírio
Chen, Banglin
dc.subject.por.fl_str_mv Adsorption
topic Adsorption
description A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process.
publishDate 2008
dc.date.none.fl_str_mv 2008
2008-01-01T00:00:00Z
2011-02-04T16:04:09Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10198/3271
url http://hdl.handle.net/10198/3271
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Bastin, Laurent; Barcia, Patrick; Hurtado, Eric; Silva, Jose A. C.; Rodrigues, Alirio; Chen, Banglin (2008). A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. Journal od Physical Chemistry C. ISSN 1932-7447. 112:5, p. 1575-1581
1932-7447
10.1021/jp077618g
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
_version_ 1799135169698856960

Registros relacionados