A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10198/3271 |
Resumo: | A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process. |
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A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorptionAdsorptionA microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process.American Chemical SocietyBiblioteca Digital do IPBBastin, LaurentBárcia, Patrick da SilvaHurtado, EricSilva, José A.C.Rodrigues, AlírioChen, Banglin2011-02-04T16:04:09Z20082008-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10198/3271engBastin, Laurent; Barcia, Patrick; Hurtado, Eric; Silva, Jose A. C.; Rodrigues, Alirio; Chen, Banglin (2008). A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. Journal od Physical Chemistry C. ISSN 1932-7447. 112:5, p. 1575-15811932-744710.1021/jp077618ginfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2023-11-21T10:08:32Zoai:bibliotecadigital.ipb.pt:10198/3271Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T22:56:12.503406Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
title |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
spellingShingle |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption Bastin, Laurent Adsorption |
title_short |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
title_full |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
title_fullStr |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
title_full_unstemmed |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
title_sort |
A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption |
author |
Bastin, Laurent |
author_facet |
Bastin, Laurent Bárcia, Patrick da Silva Hurtado, Eric Silva, José A.C. Rodrigues, Alírio Chen, Banglin |
author_role |
author |
author2 |
Bárcia, Patrick da Silva Hurtado, Eric Silva, José A.C. Rodrigues, Alírio Chen, Banglin |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Biblioteca Digital do IPB |
dc.contributor.author.fl_str_mv |
Bastin, Laurent Bárcia, Patrick da Silva Hurtado, Eric Silva, José A.C. Rodrigues, Alírio Chen, Banglin |
dc.subject.por.fl_str_mv |
Adsorption |
topic |
Adsorption |
description |
A microporous MOF Zn(BDC)(4,4'-Bipy)0.5 (MOF-508b, BDC = 1,4-benzenedicarboxylate, 4,4'-Bipy = 4,4'-bipyridine) was examined for the separation and removal of CO2 from its binary CO2/N-2 and CO2/CH4 and ternary CO2/CH4/N-2 mixtures by fixed-bed adsorption. With one-dimensional pores of about 4.0 x 4.0 angstrom to induce their differential interactions with the three components, MOF-508b exhibits highly selective adsorption to CO2 with the,adsorption capacity of 26.0 wt % at 303 K and 4.5 bar. This is the first example of microporous MOFs for the separation and removal of CO2 from its binary and ternary mixtures by fixed-bed adsorption, establishing the feasibility of the emerging microporous MOFs for their potential. applications in this very important industrial and environmental process. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008 2008-01-01T00:00:00Z 2011-02-04T16:04:09Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10198/3271 |
url |
http://hdl.handle.net/10198/3271 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Bastin, Laurent; Barcia, Patrick; Hurtado, Eric; Silva, Jose A. C.; Rodrigues, Alirio; Chen, Banglin (2008). A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. Journal od Physical Chemistry C. ISSN 1932-7447. 112:5, p. 1575-1581 1932-7447 10.1021/jp077618g |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
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Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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RCAAP |
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RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
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Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799135169698856960 |