Characterization of Annona cherimola mill. Seed oil from Madeira Island: a possible biodiesel feedstock

• Autor(a) principal: Branco, Pedro Costa
• Data de Publicação: 2009
• Outros Autores: Castilho, Paula C., Rosa, Maria Fernanda, Ferreira, Juan
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
• Texto Completo: http://hdl.handle.net/10400.13/3258
• topic: Annona seed oil; Residue valorization; Triacylglycerols; Fatty acid; Methyl ester; Biodiesel production; Madeira Island (Portugal); .; Faculdade de Ciências Exatas e da Engenharia

The possibility of using Annona seed oil as an added value product, namely as a source of biodiesel, is explored. Milled Annona seeds were extracted with hexane at room temperature (72 h) and at solvent boiling point (6 h). Oil content was found to be 25 and 22.4% respec tively. The oil was characterized in terms of lipid compo sition (HPLC–APCI–MS and 13C NMR), resistance to oxidation and acidity index. FAME composition was determined by GC–MS and five major peaks were identi fied. Production of biodiesel from Annona’s seed oil was achieved by base-catalyzed transesterification. Density, viscosity, refraction coefficient, acid value, cold filter plugging point, cloud point and oxidation stability were measured. The iodine value and the ‘‘apparent cetane number’’ were calculated. Density, viscosity, acid value, iodine value, cold filter plugging point and cloud point were within EN14214 specifications and the calculated ‘‘apparent cetane number’’ was also indicative of a suitable product.