Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies

Detalhes bibliográficos
Autor(a) principal: Forte, Andreia
Data de Publicação: 2021
Outros Autores: Gago, Sandra, Carrott, Manuela Ribeiro, Carrott, Peter, Alves, Celso, Teodoro, Fernando, Pedrosa, Rui, Marrucho, Isabel M., Branco, Luis C
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10400.8/5998
Resumo: This work was supported by National Funds through FCT/ MCTES – Portuguese Foundation for Science and Technology within the scope of the projects UID/QUI/0619/2019, UIDB/ 50006/2020 (LAQV-REQUIMTE) and UIDB/00100/2020, UID/ MAR/04292/2020 (MARE—Marine and Environmental Sciences Centre). Also, a doctoral fellowship to Andreia Forte (PD/BD/ 109625/2015) and Solchemar company are acknowledged. The NMR spectrometers are part of The National NMR Facility, supported by FCT/MCTES (RECI/BBB-BQB/0230/2012).
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spelling Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studiesThis work was supported by National Funds through FCT/ MCTES – Portuguese Foundation for Science and Technology within the scope of the projects UID/QUI/0619/2019, UIDB/ 50006/2020 (LAQV-REQUIMTE) and UIDB/00100/2020, UID/ MAR/04292/2020 (MARE—Marine and Environmental Sciences Centre). Also, a doctoral fellowship to Andreia Forte (PD/BD/ 109625/2015) and Solchemar company are acknowledged. The NMR spectrometers are part of The National NMR Facility, supported by FCT/MCTES (RECI/BBB-BQB/0230/2012).Several organic salts based on the combination of two different choline derivative cations and MnCl3−, GdCl4− and TbCl4− as anions were immobilized in mesoporous silica nanoparticles (MSNs) by a two-step synthetic method. Firstly, MSNs were functionalized with choline derivative cations with chloride anions and then the metals were incorporated by the reaction of the chloride with the respective metal chloride salts. These nanomaterials were fully characterized by different characterization techniques such as 1H-NMR, FT-IR, elemental analysis, TEM, TGA, N2 adsorption, XRD and DLS. These characterization data were important to confirm the successful functionalization of the nanomaterials and to access their textural properties and colloidal stability. The final materials were also characterized by ICP-MS that indicated the metal contents. The cytotoxicity profile was evaluated in four different cell lines (3T3, 293T, HepG2 and Caco-2), which shows some relevant differences between the metal organic salts and their immobilized analogues.Royal Society of ChemistryIC-OnlineForte, AndreiaGago, SandraCarrott, Manuela RibeiroCarrott, PeterAlves, CelsoTeodoro, FernandoPedrosa, RuiMarrucho, Isabel M.Branco, Luis C2021-08-03T15:17:23Z20212021-01-01T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10400.8/5998engAndreia Forte; Sandra Gago; Manuela Ribeiro Carrott; Peter Carrott; Celso Alves; Fernando Teodoro; Rui Pedrosa; Isabel M. Marrucho; Luis C. Branco. "Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies". Dalton Transactions (2021): https://doi.org/10.1039/D1DT00605C.1477-922610.1039/D1DT00605Cmetadata only accessinfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-01-17T15:52:10Zoai:iconline.ipleiria.pt:10400.8/5998Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T01:49:21.080745Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
title Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
spellingShingle Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
Forte, Andreia
title_short Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
title_full Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
title_fullStr Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
title_full_unstemmed Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
title_sort Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies
author Forte, Andreia
author_facet Forte, Andreia
Gago, Sandra
Carrott, Manuela Ribeiro
Carrott, Peter
Alves, Celso
Teodoro, Fernando
Pedrosa, Rui
Marrucho, Isabel M.
Branco, Luis C
author_role author
author2 Gago, Sandra
Carrott, Manuela Ribeiro
Carrott, Peter
Alves, Celso
Teodoro, Fernando
Pedrosa, Rui
Marrucho, Isabel M.
Branco, Luis C
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv IC-Online
dc.contributor.author.fl_str_mv Forte, Andreia
Gago, Sandra
Carrott, Manuela Ribeiro
Carrott, Peter
Alves, Celso
Teodoro, Fernando
Pedrosa, Rui
Marrucho, Isabel M.
Branco, Luis C
description This work was supported by National Funds through FCT/ MCTES – Portuguese Foundation for Science and Technology within the scope of the projects UID/QUI/0619/2019, UIDB/ 50006/2020 (LAQV-REQUIMTE) and UIDB/00100/2020, UID/ MAR/04292/2020 (MARE—Marine and Environmental Sciences Centre). Also, a doctoral fellowship to Andreia Forte (PD/BD/ 109625/2015) and Solchemar company are acknowledged. The NMR spectrometers are part of The National NMR Facility, supported by FCT/MCTES (RECI/BBB-BQB/0230/2012).
publishDate 2021
dc.date.none.fl_str_mv 2021-08-03T15:17:23Z
2021
2021-01-01T00:00:00Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10400.8/5998
url http://hdl.handle.net/10400.8/5998
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Andreia Forte; Sandra Gago; Manuela Ribeiro Carrott; Peter Carrott; Celso Alves; Fernando Teodoro; Rui Pedrosa; Isabel M. Marrucho; Luis C. Branco. "Mesoporous silica nanoparticles with manganese and lanthanide salts: synthesis, characterization and cytotoxicity studies". Dalton Transactions (2021): https://doi.org/10.1039/D1DT00605C.
1477-9226
10.1039/D1DT00605C
dc.rights.driver.fl_str_mv metadata only access
info:eu-repo/semantics/openAccess
rights_invalid_str_mv metadata only access
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
repository.mail.fl_str_mv
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