Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles
Autor(a) principal: | |
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Data de Publicação: | 2000 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10316/5241 https://doi.org/10.1002/chin.200048131 |
Resumo: | Nucleophilic substitution reactions of 2-halo-2H-azirine with potassium phthalimide and aniline allowed the preparation of new substituted 2H-azirines. The reactions of 2-bromo-3-phenyl-2H-azirine-2-carboxylate with methylamine led to the synthesis of [alpha]-diimines and from the reaction with water, a 3-oxazoline was obtained. |
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Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles2H-azirines[alpha]-diimines3-oxazolineNucleophilic substitution reactions of 2-halo-2H-azirine with potassium phthalimide and aniline allowed the preparation of new substituted 2H-azirines. The reactions of 2-bromo-3-phenyl-2H-azirine-2-carboxylate with methylamine led to the synthesis of [alpha]-diimines and from the reaction with water, a 3-oxazoline was obtained.http://www.sciencedirect.com/science/article/B6THS-4152YMR-K/1/e94005b66b66b6820ad27458f2562edd2000info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleaplication/PDFhttp://hdl.handle.net/10316/5241http://hdl.handle.net/10316/5241https://doi.org/10.1002/chin.200048131engTetrahedron Letters. 41:37 (2000) 7217-7220Pinho e Melo, Teresa M. V. D.Lopes, Cláudia S. J.Gonsalves, António M. d'A. Rochainfo:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2020-11-06T16:48:35Zoai:estudogeral.uc.pt:10316/5241Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-19T21:01:22.870611Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
title |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
spellingShingle |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles Pinho e Melo, Teresa M. V. D. 2H-azirines [alpha]-diimines 3-oxazoline |
title_short |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
title_full |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
title_fullStr |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
title_full_unstemmed |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
title_sort |
Synthesis and reactivity of 2-halo-2H-azirines towards nucleophiles |
author |
Pinho e Melo, Teresa M. V. D. |
author_facet |
Pinho e Melo, Teresa M. V. D. Lopes, Cláudia S. J. Gonsalves, António M. d'A. Rocha |
author_role |
author |
author2 |
Lopes, Cláudia S. J. Gonsalves, António M. d'A. Rocha |
author2_role |
author author |
dc.contributor.author.fl_str_mv |
Pinho e Melo, Teresa M. V. D. Lopes, Cláudia S. J. Gonsalves, António M. d'A. Rocha |
dc.subject.por.fl_str_mv |
2H-azirines [alpha]-diimines 3-oxazoline |
topic |
2H-azirines [alpha]-diimines 3-oxazoline |
description |
Nucleophilic substitution reactions of 2-halo-2H-azirine with potassium phthalimide and aniline allowed the preparation of new substituted 2H-azirines. The reactions of 2-bromo-3-phenyl-2H-azirine-2-carboxylate with methylamine led to the synthesis of [alpha]-diimines and from the reaction with water, a 3-oxazoline was obtained. |
publishDate |
2000 |
dc.date.none.fl_str_mv |
2000 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10316/5241 http://hdl.handle.net/10316/5241 https://doi.org/10.1002/chin.200048131 |
url |
http://hdl.handle.net/10316/5241 https://doi.org/10.1002/chin.200048131 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Tetrahedron Letters. 41:37 (2000) 7217-7220 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
aplication/PDF |
dc.source.none.fl_str_mv |
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instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
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1799133905333256192 |