Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4
Autor(a) principal: | |
---|---|
Data de Publicação: | 2021 |
Outros Autores: | , , , , , , , |
Idioma: | eng |
Título da fonte: | Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
Texto Completo: | http://hdl.handle.net/10773/32598 |
Resumo: | The variations of Raman and optic absorption spectra of Co-Al layered double hydroxides (LDH) intercalated with nitrate and carbonate anions have been studied as a function of the Co2+/Al3+ ratio. It was revealed from the comparative analysis of the hydrogen bond frequencies in Raman spectra and the phonon repetition lines in optic absorption spectra that the increasing Co2+/Al3+ ratio results in an enhancement of the anion exchange ability in nitrate LDH and in a suppression of the ability in carbonate LDH. |
id |
RCAP_f7c6be6ea320c918c9a384e64265cf40 |
---|---|
oai_identifier_str |
oai:ria.ua.pt:10773/32598 |
network_acronym_str |
RCAP |
network_name_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository_id_str |
7160 |
spelling |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4Layered double hydroxideAnion exchangeHydrogen bond energyHydrogen bond frequencyThe variations of Raman and optic absorption spectra of Co-Al layered double hydroxides (LDH) intercalated with nitrate and carbonate anions have been studied as a function of the Co2+/Al3+ ratio. It was revealed from the comparative analysis of the hydrogen bond frequencies in Raman spectra and the phonon repetition lines in optic absorption spectra that the increasing Co2+/Al3+ ratio results in an enhancement of the anion exchange ability in nitrate LDH and in a suppression of the ability in carbonate LDH.IEEE2023-10-21T00:00:00Z2021-10-20T00:00:00Z2021-10-20book partinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttp://hdl.handle.net/10773/32598eng978-1-6654-2988-710.1109/NAP51885.2021.9568631Pashkevich, YuriiGnezdiov, VladimirVieira, Daniel E. L.Babkin, RomanLukienko, IrinaVieira, Joaquim M.Wulferding, DirkLemmens, PeterSalak, Andrei N.info:eu-repo/semantics/embargoedAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-05-06T04:34:20Zoai:ria.ua.pt:10773/32598Portal AgregadorONGhttps://www.rcaap.pt/oai/openairemluisa.alvim@gmail.comopendoar:71602024-05-06T04:34:20Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse |
dc.title.none.fl_str_mv |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
title |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
spellingShingle |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 Pashkevich, Yurii Layered double hydroxide Anion exchange Hydrogen bond energy Hydrogen bond frequency |
title_short |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
title_full |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
title_fullStr |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
title_full_unstemmed |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
title_sort |
Comparative optic studies of cobalt-based layered double hydroxides with nitrate and carbonate anions and Co II/A1 III ratio n = 2, 3, 4 |
author |
Pashkevich, Yurii |
author_facet |
Pashkevich, Yurii Gnezdiov, Vladimir Vieira, Daniel E. L. Babkin, Roman Lukienko, Irina Vieira, Joaquim M. Wulferding, Dirk Lemmens, Peter Salak, Andrei N. |
author_role |
author |
author2 |
Gnezdiov, Vladimir Vieira, Daniel E. L. Babkin, Roman Lukienko, Irina Vieira, Joaquim M. Wulferding, Dirk Lemmens, Peter Salak, Andrei N. |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Pashkevich, Yurii Gnezdiov, Vladimir Vieira, Daniel E. L. Babkin, Roman Lukienko, Irina Vieira, Joaquim M. Wulferding, Dirk Lemmens, Peter Salak, Andrei N. |
dc.subject.por.fl_str_mv |
Layered double hydroxide Anion exchange Hydrogen bond energy Hydrogen bond frequency |
topic |
Layered double hydroxide Anion exchange Hydrogen bond energy Hydrogen bond frequency |
description |
The variations of Raman and optic absorption spectra of Co-Al layered double hydroxides (LDH) intercalated with nitrate and carbonate anions have been studied as a function of the Co2+/Al3+ ratio. It was revealed from the comparative analysis of the hydrogen bond frequencies in Raman spectra and the phonon repetition lines in optic absorption spectra that the increasing Co2+/Al3+ ratio results in an enhancement of the anion exchange ability in nitrate LDH and in a suppression of the ability in carbonate LDH. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-10-20T00:00:00Z 2021-10-20 2023-10-21T00:00:00Z |
dc.type.driver.fl_str_mv |
book part |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10773/32598 |
url |
http://hdl.handle.net/10773/32598 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
978-1-6654-2988-7 10.1109/NAP51885.2021.9568631 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/embargoedAccess |
eu_rights_str_mv |
embargoedAccess |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
IEEE |
publisher.none.fl_str_mv |
IEEE |
dc.source.none.fl_str_mv |
reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação instacron:RCAAP |
instname_str |
Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
instacron_str |
RCAAP |
institution |
RCAAP |
reponame_str |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
collection |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) |
repository.name.fl_str_mv |
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação |
repository.mail.fl_str_mv |
mluisa.alvim@gmail.com |
_version_ |
1817543794725224448 |