Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging

Detalhes bibliográficos
Autor(a) principal: Meléndez-Rodríguez, Beatriz
Data de Publicação: 2021
Outros Autores: Torres-Giner, Sergio, Reis, Maria A. M., Silva, Fernando, Matos, Mariana, Cabedo, Luis, Lagarón, José María
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Texto Completo: http://hdl.handle.net/10362/132906
Resumo: BES-2016-077972 IJCI-2016-29675 RTI2018-097249-B-C21
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spelling Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packagingCircular bioeconomyFood packagingOrganic recyclingPolyhydroxyalkanoatesWaste valorizationChemistry(all)Polymers and PlasticsBES-2016-077972 IJCI-2016-29675 RTI2018-097249-B-C21In the present study, a new poly(3-hydroxybutyrate-co-3-hydroxyvalerate-co-3-hydroxyhexanoate) [P(3HB-co-3HV-co-3HHx)] terpolyester with approximately 68 mol% of 3-hydroxybutyrate (3HB), 17 mol% of 3-hydroxyvalerate (3HV), and 15 mol% of 3-hydroxyhexanoate (3HHx) was obtained via the mixed microbial culture (MMC) technology using fruit pulps as feedstock, a processing by-product of the juice industry. After extraction and purification performed in a single step, the P(3HB-co-3HV-co-3HHx) powder was melt-mixed, for the first time, in contents of 10, 25, and 50 wt% with commercial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV). Thereafter, the resultant doughs were thermo-compressed to obtain highly miscible films with good optical properties, which can be of interest in rigid and semirigid organic recyclable food packaging applications. The results showed that the developed blends exhibited a progressively lower melting enthalpy with increasing the incorporation of P(3HB-co-3HV-co-3HHx), but retained the PHB crystalline morphology, albeit with an inferred lower crystalline density. Moreover, all the melt-mixed blends were thermally stable up to nearly 240 °C. As the content of terpolymer increased in the blends, the mechanical response of their films showed a brittle-to-ductile transition. On the other hand, the permeabilities to water vapor, oxygen, and, more notably, limonene were seen to increase. On the overall, this study demonstrates the value of using industrial biowaste derived P(3HB-co-3HV-co-3HHx) terpolyesters as potentially cost-effective and sustainable plasticizing additives to balance the physical properties of organic recyclable polyhydroxyalkanoate (PHA)-based food packaging materials.UCIBIO - Applied Molecular Biosciences UnitDQ - Departamento de QuímicaRUNMeléndez-Rodríguez, BeatrizTorres-Giner, SergioReis, Maria A. M.Silva, FernandoMatos, MarianaCabedo, LuisLagarón, José María2022-02-14T23:29:43Z2021-04-042021-04-04T00:00:00Zinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10362/132906engPURE: 36692435https://doi.org/10.3390/polym13071155info:eu-repo/semantics/openAccessreponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãoinstacron:RCAAP2024-03-11T05:11:34Zoai:run.unl.pt:10362/132906Portal AgregadorONGhttps://www.rcaap.pt/oai/openaireopendoar:71602024-03-20T03:47:37.642009Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informaçãofalse
dc.title.none.fl_str_mv Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
title Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
spellingShingle Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
Meléndez-Rodríguez, Beatriz
Circular bioeconomy
Food packaging
Organic recycling
Polyhydroxyalkanoates
Waste valorization
Chemistry(all)
Polymers and Plastics
title_short Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
title_full Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
title_fullStr Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
title_full_unstemmed Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
title_sort Blends of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with fruit pulp biowaste derived poly(3-hydroxybutyrate-co-3- hydroxyvalerate-co-3-hydroxyhexanoate) for organic recycling food packaging
author Meléndez-Rodríguez, Beatriz
author_facet Meléndez-Rodríguez, Beatriz
Torres-Giner, Sergio
Reis, Maria A. M.
Silva, Fernando
Matos, Mariana
Cabedo, Luis
Lagarón, José María
author_role author
author2 Torres-Giner, Sergio
Reis, Maria A. M.
Silva, Fernando
Matos, Mariana
Cabedo, Luis
Lagarón, José María
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv UCIBIO - Applied Molecular Biosciences Unit
DQ - Departamento de Química
RUN
dc.contributor.author.fl_str_mv Meléndez-Rodríguez, Beatriz
Torres-Giner, Sergio
Reis, Maria A. M.
Silva, Fernando
Matos, Mariana
Cabedo, Luis
Lagarón, José María
dc.subject.por.fl_str_mv Circular bioeconomy
Food packaging
Organic recycling
Polyhydroxyalkanoates
Waste valorization
Chemistry(all)
Polymers and Plastics
topic Circular bioeconomy
Food packaging
Organic recycling
Polyhydroxyalkanoates
Waste valorization
Chemistry(all)
Polymers and Plastics
description BES-2016-077972 IJCI-2016-29675 RTI2018-097249-B-C21
publishDate 2021
dc.date.none.fl_str_mv 2021-04-04
2021-04-04T00:00:00Z
2022-02-14T23:29:43Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/10362/132906
url http://hdl.handle.net/10362/132906
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv PURE: 36692435
https://doi.org/10.3390/polym13071155
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
instname:Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron:RCAAP
instname_str Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
instacron_str RCAAP
institution RCAAP
reponame_str Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
collection Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
repository.name.fl_str_mv Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos) - Agência para a Sociedade do Conhecimento (UMIC) - FCT - Sociedade da Informação
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