Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions

Detalhes bibliográficos
Autor(a) principal: Nájera,Carmen
Data de Publicação: 2010
Outros Autores: Sansano,José M., Yus,Miguel
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000300002
Resumo: In this review, a comparison between the Lewis acid catalysed and organocatalysed 1,3-dipolar cycloaddition is presented with special focus on the enantioselective synthesis of five-membered hetero- or carbocyclic systems, is described. These reactions exhibit very interesting features, but the most important one is the generation of up to four stereogenic centres in only one reaction step.
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spelling Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditionsasymmetric catalysiscycloadditionsLewis acidsorganocatalystsIn this review, a comparison between the Lewis acid catalysed and organocatalysed 1,3-dipolar cycloaddition is presented with special focus on the enantioselective synthesis of five-membered hetero- or carbocyclic systems, is described. These reactions exhibit very interesting features, but the most important one is the generation of up to four stereogenic centres in only one reaction step.Sociedade Brasileira de Química2010-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000300002Journal of the Brazilian Chemical Society v.21 n.3 2010reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532010000300002info:eu-repo/semantics/openAccessNájera,CarmenSansano,José M.Yus,Migueleng2010-04-30T00:00:00Zoai:scielo:S0103-50532010000300002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2010-04-30T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
title Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
spellingShingle Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
Nájera,Carmen
asymmetric catalysis
cycloadditions
Lewis acids
organocatalysts
title_short Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
title_full Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
title_fullStr Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
title_full_unstemmed Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
title_sort Metal complexes versus organocatalysts in asymmetric 1,3-dipolar cycloadditions
author Nájera,Carmen
author_facet Nájera,Carmen
Sansano,José M.
Yus,Miguel
author_role author
author2 Sansano,José M.
Yus,Miguel
author2_role author
author
dc.contributor.author.fl_str_mv Nájera,Carmen
Sansano,José M.
Yus,Miguel
dc.subject.por.fl_str_mv asymmetric catalysis
cycloadditions
Lewis acids
organocatalysts
topic asymmetric catalysis
cycloadditions
Lewis acids
organocatalysts
description In this review, a comparison between the Lewis acid catalysed and organocatalysed 1,3-dipolar cycloaddition is presented with special focus on the enantioselective synthesis of five-membered hetero- or carbocyclic systems, is described. These reactions exhibit very interesting features, but the most important one is the generation of up to four stereogenic centres in only one reaction step.
publishDate 2010
dc.date.none.fl_str_mv 2010-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000300002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000300002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532010000300002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.21 n.3 2010
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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