Alilação e crotilação catalítica e enantiosseletiva de aldeídos

Detalhes bibliográficos
Autor(a) principal: Fátima,Ângelo de
Data de Publicação: 2006
Outros Autores: Robello,Luís Gustavo, Pilli,Ronaldo Aloise
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000500023
Resumo: The field of chiral catalysis has experienced explosive growth over the last two decades. By now, many of the classical reactions in organic synthesis can be carried out efficiently in asymmetric manner. As one of the fundamental and powerful C-C bond-forming reactions, enantioselective catalytic allylation (ECA) and crotylation (ECC) of aldehydes has attracted considerable attention. In this article, we present an overview about the importance of chiral Lewis acids and bases in catalytic enantioselective addition of allyl- and crotyl metals to aldehydes and the application of this methodology in the total synthesis of natural and non-natural products.
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spelling Alilação e crotilação catalítica e enantiosseletiva de aldeídosasymmetric catalysisallylation and crotylationLewis acids and basesThe field of chiral catalysis has experienced explosive growth over the last two decades. By now, many of the classical reactions in organic synthesis can be carried out efficiently in asymmetric manner. As one of the fundamental and powerful C-C bond-forming reactions, enantioselective catalytic allylation (ECA) and crotylation (ECC) of aldehydes has attracted considerable attention. In this article, we present an overview about the importance of chiral Lewis acids and bases in catalytic enantioselective addition of allyl- and crotyl metals to aldehydes and the application of this methodology in the total synthesis of natural and non-natural products.Sociedade Brasileira de Química2006-10-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000500023Química Nova v.29 n.5 2006reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422006000500023info:eu-repo/semantics/openAccessFátima,Ângelo deRobello,Luís GustavoPilli,Ronaldo Aloisepor2011-09-06T00:00:00Zoai:scielo:S0100-40422006000500023Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2011-09-06T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Alilação e crotilação catalítica e enantiosseletiva de aldeídos
title Alilação e crotilação catalítica e enantiosseletiva de aldeídos
spellingShingle Alilação e crotilação catalítica e enantiosseletiva de aldeídos
Fátima,Ângelo de
asymmetric catalysis
allylation and crotylation
Lewis acids and bases
title_short Alilação e crotilação catalítica e enantiosseletiva de aldeídos
title_full Alilação e crotilação catalítica e enantiosseletiva de aldeídos
title_fullStr Alilação e crotilação catalítica e enantiosseletiva de aldeídos
title_full_unstemmed Alilação e crotilação catalítica e enantiosseletiva de aldeídos
title_sort Alilação e crotilação catalítica e enantiosseletiva de aldeídos
author Fátima,Ângelo de
author_facet Fátima,Ângelo de
Robello,Luís Gustavo
Pilli,Ronaldo Aloise
author_role author
author2 Robello,Luís Gustavo
Pilli,Ronaldo Aloise
author2_role author
author
dc.contributor.author.fl_str_mv Fátima,Ângelo de
Robello,Luís Gustavo
Pilli,Ronaldo Aloise
dc.subject.por.fl_str_mv asymmetric catalysis
allylation and crotylation
Lewis acids and bases
topic asymmetric catalysis
allylation and crotylation
Lewis acids and bases
description The field of chiral catalysis has experienced explosive growth over the last two decades. By now, many of the classical reactions in organic synthesis can be carried out efficiently in asymmetric manner. As one of the fundamental and powerful C-C bond-forming reactions, enantioselective catalytic allylation (ECA) and crotylation (ECC) of aldehydes has attracted considerable attention. In this article, we present an overview about the importance of chiral Lewis acids and bases in catalytic enantioselective addition of allyl- and crotyl metals to aldehydes and the application of this methodology in the total synthesis of natural and non-natural products.
publishDate 2006
dc.date.none.fl_str_mv 2006-10-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000500023
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422006000500023
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.1590/S0100-40422006000500023
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.29 n.5 2006
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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