The electrochemistry of simple inorganic molecules in room temperature ionic liquids

Detalhes bibliográficos
Autor(a) principal: Silvester,Debbie S.
Data de Publicação: 2008
Outros Autores: Rogers,Emma I., Barrosse-Antle,Laura E., Broder,Tessa L., Compton,Richard G.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000400002
Resumo: The electrochemistry of simple inorganic compounds in room temperature ionic liquids (RTILs) is reviewed and some new work in this area is presented. This paper focuses on the comparison between electrochemical behaviour in RTILs and in conventional aprotic solvents. Some compounds (iodides, O2, NO2, SO2, NH3) display similar reactions and mechanisms in RTILs as in aprotic solvents (as is observed for organic compounds). However other species (nitrates, PCl3, POCl3) show remarkably different behaviour to traditional solvents. This makes RTILs very promising media for the study of inorganic compounds, and highlights the need for more investigations in this exciting area.
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spelling The electrochemistry of simple inorganic molecules in room temperature ionic liquidsRoom Temperature Ionic Liquidsinorganic compoundselectrochemistryvoltammetrygas sensingmechanistic studiesThe electrochemistry of simple inorganic compounds in room temperature ionic liquids (RTILs) is reviewed and some new work in this area is presented. This paper focuses on the comparison between electrochemical behaviour in RTILs and in conventional aprotic solvents. Some compounds (iodides, O2, NO2, SO2, NH3) display similar reactions and mechanisms in RTILs as in aprotic solvents (as is observed for organic compounds). However other species (nitrates, PCl3, POCl3) show remarkably different behaviour to traditional solvents. This makes RTILs very promising media for the study of inorganic compounds, and highlights the need for more investigations in this exciting area.Sociedade Brasileira de Química2008-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000400002Journal of the Brazilian Chemical Society v.19 n.4 2008reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532008000400002info:eu-repo/semantics/openAccessSilvester,Debbie S.Rogers,Emma I.Barrosse-Antle,Laura E.Broder,Tessa L.Compton,Richard G.eng2008-06-11T00:00:00Zoai:scielo:S0103-50532008000400002Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-06-11T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv The electrochemistry of simple inorganic molecules in room temperature ionic liquids
title The electrochemistry of simple inorganic molecules in room temperature ionic liquids
spellingShingle The electrochemistry of simple inorganic molecules in room temperature ionic liquids
Silvester,Debbie S.
Room Temperature Ionic Liquids
inorganic compounds
electrochemistry
voltammetry
gas sensing
mechanistic studies
title_short The electrochemistry of simple inorganic molecules in room temperature ionic liquids
title_full The electrochemistry of simple inorganic molecules in room temperature ionic liquids
title_fullStr The electrochemistry of simple inorganic molecules in room temperature ionic liquids
title_full_unstemmed The electrochemistry of simple inorganic molecules in room temperature ionic liquids
title_sort The electrochemistry of simple inorganic molecules in room temperature ionic liquids
author Silvester,Debbie S.
author_facet Silvester,Debbie S.
Rogers,Emma I.
Barrosse-Antle,Laura E.
Broder,Tessa L.
Compton,Richard G.
author_role author
author2 Rogers,Emma I.
Barrosse-Antle,Laura E.
Broder,Tessa L.
Compton,Richard G.
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Silvester,Debbie S.
Rogers,Emma I.
Barrosse-Antle,Laura E.
Broder,Tessa L.
Compton,Richard G.
dc.subject.por.fl_str_mv Room Temperature Ionic Liquids
inorganic compounds
electrochemistry
voltammetry
gas sensing
mechanistic studies
topic Room Temperature Ionic Liquids
inorganic compounds
electrochemistry
voltammetry
gas sensing
mechanistic studies
description The electrochemistry of simple inorganic compounds in room temperature ionic liquids (RTILs) is reviewed and some new work in this area is presented. This paper focuses on the comparison between electrochemical behaviour in RTILs and in conventional aprotic solvents. Some compounds (iodides, O2, NO2, SO2, NH3) display similar reactions and mechanisms in RTILs as in aprotic solvents (as is observed for organic compounds). However other species (nitrates, PCl3, POCl3) show remarkably different behaviour to traditional solvents. This makes RTILs very promising media for the study of inorganic compounds, and highlights the need for more investigations in this exciting area.
publishDate 2008
dc.date.none.fl_str_mv 2008-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000400002
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532008000400002
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532008000400002
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.19 n.4 2008
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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