An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS
Autor(a) principal: | |
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Data de Publicação: | 2016 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000701229 |
Resumo: | Formic acid extractions of Brazil nut and babassu coconut samples were undertaken prior to determination of Al, As, Ba, Co, Cr, Cu, Mn, Mo, Ni, Pb, Se, Sr, V and Zn in their meat and oil portions by inductively coupled plasma mass spectrometry (ICP-MS) in an effort to accomplish a first order fractionation of the trace elements between these two components. An optimized full factorial design was applied to establish the best conditions for extraction. Microwave-assisted nitric acid digestions of samples and fractions along with analysis of certified reference material TORT-2 established the efficiency of recovery of the trace elements as well as provided a verification of accuracy. The multiple responses were analyzed using a desirability function wherein the recovery of the trace elements by extraction was compared with the determination of the total content as determined by nitric acid digestion. Although most trace elements presented a recovery higher than 85% using a formic acid extraction, Al suffered consistently low results for all samples (40-50%). Except for Al and Cr, the majority of the trace elements were present in the defatted fraction of both samples, i.e., Al (50 and 10%), Cr (86 and 60%), Ni (30 and 10%) and Sr (8 and 20%) in Brazil nut and babassu coconut oil fractions, respectively. |
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An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MSformic acid extractiontrace elementsnutsfractionationICP-MSFormic acid extractions of Brazil nut and babassu coconut samples were undertaken prior to determination of Al, As, Ba, Co, Cr, Cu, Mn, Mo, Ni, Pb, Se, Sr, V and Zn in their meat and oil portions by inductively coupled plasma mass spectrometry (ICP-MS) in an effort to accomplish a first order fractionation of the trace elements between these two components. An optimized full factorial design was applied to establish the best conditions for extraction. Microwave-assisted nitric acid digestions of samples and fractions along with analysis of certified reference material TORT-2 established the efficiency of recovery of the trace elements as well as provided a verification of accuracy. The multiple responses were analyzed using a desirability function wherein the recovery of the trace elements by extraction was compared with the determination of the total content as determined by nitric acid digestion. Although most trace elements presented a recovery higher than 85% using a formic acid extraction, Al suffered consistently low results for all samples (40-50%). Except for Al and Cr, the majority of the trace elements were present in the defatted fraction of both samples, i.e., Al (50 and 10%), Cr (86 and 60%), Ni (30 and 10%) and Sr (8 and 20%) in Brazil nut and babassu coconut oil fractions, respectively.Sociedade Brasileira de Química2016-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000701229Journal of the Brazilian Chemical Society v.27 n.7 2016reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20160018info:eu-repo/semantics/openAccessLopes,Gisele S.Silva,Francisco L. F.Grinberg,PatriciaSturgeon,Ralph E.eng2016-07-26T00:00:00Zoai:scielo:S0103-50532016000701229Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2016-07-26T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
title |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
spellingShingle |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS Lopes,Gisele S. formic acid extraction trace elements nuts fractionation ICP-MS |
title_short |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
title_full |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
title_fullStr |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
title_full_unstemmed |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
title_sort |
An Evaluation of the Use of Formic Acid for Extraction of Trace Elements from Brazil Nut and Babassu Coconut and Its Suitability for Multi-Element Determination by ICP-MS |
author |
Lopes,Gisele S. |
author_facet |
Lopes,Gisele S. Silva,Francisco L. F. Grinberg,Patricia Sturgeon,Ralph E. |
author_role |
author |
author2 |
Silva,Francisco L. F. Grinberg,Patricia Sturgeon,Ralph E. |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Lopes,Gisele S. Silva,Francisco L. F. Grinberg,Patricia Sturgeon,Ralph E. |
dc.subject.por.fl_str_mv |
formic acid extraction trace elements nuts fractionation ICP-MS |
topic |
formic acid extraction trace elements nuts fractionation ICP-MS |
description |
Formic acid extractions of Brazil nut and babassu coconut samples were undertaken prior to determination of Al, As, Ba, Co, Cr, Cu, Mn, Mo, Ni, Pb, Se, Sr, V and Zn in their meat and oil portions by inductively coupled plasma mass spectrometry (ICP-MS) in an effort to accomplish a first order fractionation of the trace elements between these two components. An optimized full factorial design was applied to establish the best conditions for extraction. Microwave-assisted nitric acid digestions of samples and fractions along with analysis of certified reference material TORT-2 established the efficiency of recovery of the trace elements as well as provided a verification of accuracy. The multiple responses were analyzed using a desirability function wherein the recovery of the trace elements by extraction was compared with the determination of the total content as determined by nitric acid digestion. Although most trace elements presented a recovery higher than 85% using a formic acid extraction, Al suffered consistently low results for all samples (40-50%). Except for Al and Cr, the majority of the trace elements were present in the defatted fraction of both samples, i.e., Al (50 and 10%), Cr (86 and 60%), Ni (30 and 10%) and Sr (8 and 20%) in Brazil nut and babassu coconut oil fractions, respectively. |
publishDate |
2016 |
dc.date.none.fl_str_mv |
2016-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000701229 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532016000701229 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20160018 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.27 n.7 2016 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
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1750318178656845824 |