Mapping Ethanol Production Sources in Brazil Through Stable Isotopes
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000601283 |
Resumo: | Ethanol is a biofuel produced in Brazil through fermentation of sugarcane, requiring vast plantation areas and water availability. The present work aimed at testing isotopic markers as tools for ethanol source appointment or certification of origin. For this, oxygen and hydrogen isotopic patterns were determined in plant-water, soil-water, rainwater, and water from reservoirs and some rivers in four sugarcane crop areas. The isotopic fingerprint of carbon and hydrogen in ethanol produced in the respective mills was also determined. Samples were collected in 2011 and 2012 in crop areas of the state of Amazonas (North), Mato Grosso (Center-West), São Paulo (Southeast) and Rio Grande do Sul (South). The substantial and complex influence of the hydrological cycle on the ethanol δD and the small δ13C variations constrain the use of isotopes for the intended objectives. |
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Mapping Ethanol Production Sources in Brazil Through Stable Isotopescontinuous flow isotope ratio mass spectrometry (CF-IRMS)isotope ratio infrared spectroscopy (IRIS)ethanolwaterisotopic ratiosEthanol is a biofuel produced in Brazil through fermentation of sugarcane, requiring vast plantation areas and water availability. The present work aimed at testing isotopic markers as tools for ethanol source appointment or certification of origin. For this, oxygen and hydrogen isotopic patterns were determined in plant-water, soil-water, rainwater, and water from reservoirs and some rivers in four sugarcane crop areas. The isotopic fingerprint of carbon and hydrogen in ethanol produced in the respective mills was also determined. Samples were collected in 2011 and 2012 in crop areas of the state of Amazonas (North), Mato Grosso (Center-West), São Paulo (Southeast) and Rio Grande do Sul (South). The substantial and complex influence of the hydrological cycle on the ethanol δD and the small δ13C variations constrain the use of isotopes for the intended objectives.Sociedade Brasileira de Química2015-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000601283Journal of the Brazilian Chemical Society v.26 n.6 2015reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.5935/0103-5053.20150095info:eu-repo/semantics/openAccessSilva,Gilson C.Moreira,Marcelo Z.Scofield,Arthur L.Godoy,José M. O.Almeida,Lilian F.Wagener,Angela L. R.eng2020-06-05T00:00:00Zoai:scielo:S0103-50532015000601283Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2020-06-05T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
title |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
spellingShingle |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes Silva,Gilson C. continuous flow isotope ratio mass spectrometry (CF-IRMS) isotope ratio infrared spectroscopy (IRIS) ethanol water isotopic ratios |
title_short |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
title_full |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
title_fullStr |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
title_full_unstemmed |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
title_sort |
Mapping Ethanol Production Sources in Brazil Through Stable Isotopes |
author |
Silva,Gilson C. |
author_facet |
Silva,Gilson C. Moreira,Marcelo Z. Scofield,Arthur L. Godoy,José M. O. Almeida,Lilian F. Wagener,Angela L. R. |
author_role |
author |
author2 |
Moreira,Marcelo Z. Scofield,Arthur L. Godoy,José M. O. Almeida,Lilian F. Wagener,Angela L. R. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Silva,Gilson C. Moreira,Marcelo Z. Scofield,Arthur L. Godoy,José M. O. Almeida,Lilian F. Wagener,Angela L. R. |
dc.subject.por.fl_str_mv |
continuous flow isotope ratio mass spectrometry (CF-IRMS) isotope ratio infrared spectroscopy (IRIS) ethanol water isotopic ratios |
topic |
continuous flow isotope ratio mass spectrometry (CF-IRMS) isotope ratio infrared spectroscopy (IRIS) ethanol water isotopic ratios |
description |
Ethanol is a biofuel produced in Brazil through fermentation of sugarcane, requiring vast plantation areas and water availability. The present work aimed at testing isotopic markers as tools for ethanol source appointment or certification of origin. For this, oxygen and hydrogen isotopic patterns were determined in plant-water, soil-water, rainwater, and water from reservoirs and some rivers in four sugarcane crop areas. The isotopic fingerprint of carbon and hydrogen in ethanol produced in the respective mills was also determined. Samples were collected in 2011 and 2012 in crop areas of the state of Amazonas (North), Mato Grosso (Center-West), São Paulo (Southeast) and Rio Grande do Sul (South). The substantial and complex influence of the hydrological cycle on the ethanol δD and the small δ13C variations constrain the use of isotopes for the intended objectives. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000601283 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532015000601283 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.5935/0103-5053.20150095 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.26 n.6 2015 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318177391214592 |