Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium

Detalhes bibliográficos
Autor(a) principal: Ghoneim,M. M.
Data de Publicação: 2010
Outros Autores: El-Hallag,I. S.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000100003
Resumo: Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex [(C6Me6)-isocloso-1-RuB9 H9] was investigated at a glassy carbon electrode in 0.1 mol L-1 tetrabutyl ammonium perchlorate dissolved in methylene chloride, at - 20 ºC < T < 21 ºC using convolutive cyclic voltammetry, chronoamperometry and chronopotentiometry techniques. The chemical and electrochemical parameters of the investigated complex have been determined and confirmed via digital simulation method. Low-temperature diffusion coefficient and heterogeneous electron transfer kinetics of the complex [(C6Me6)-isocloso-1-RuB9 H9] were reported. On the basis of the obtained data, the electrode reaction of the complex [(C6Me6)-isocloso-1-RuB9 H9] was suggested and discussed.
id SBQ-2_5a30af1310a97e52085d308fb3c62ae4
oai_identifier_str oai:scielo:S0103-50532010000100003
network_acronym_str SBQ-2
network_name_str Journal of the Brazilian Chemical Society (Online)
repository_id_str
spelling Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous mediumruthenium-borane complexeconvolutive voltammetrychronoamperometrychronopotentiometrydigital simulationElectrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex [(C6Me6)-isocloso-1-RuB9 H9] was investigated at a glassy carbon electrode in 0.1 mol L-1 tetrabutyl ammonium perchlorate dissolved in methylene chloride, at - 20 ºC < T < 21 ºC using convolutive cyclic voltammetry, chronoamperometry and chronopotentiometry techniques. The chemical and electrochemical parameters of the investigated complex have been determined and confirmed via digital simulation method. Low-temperature diffusion coefficient and heterogeneous electron transfer kinetics of the complex [(C6Me6)-isocloso-1-RuB9 H9] were reported. On the basis of the obtained data, the electrode reaction of the complex [(C6Me6)-isocloso-1-RuB9 H9] was suggested and discussed.Sociedade Brasileira de Química2010-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000100003Journal of the Brazilian Chemical Society v.21 n.1 2010reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532010000100003info:eu-repo/semantics/openAccessGhoneim,M. M.El-Hallag,I. S.eng2010-02-18T00:00:00Zoai:scielo:S0103-50532010000100003Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2010-02-18T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
title Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
spellingShingle Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
Ghoneim,M. M.
ruthenium-borane complexe
convolutive voltammetry
chronoamperometry
chronopotentiometry
digital simulation
title_short Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
title_full Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
title_fullStr Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
title_full_unstemmed Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
title_sort Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex at a glassy carbon electrode in non-aqueous medium
author Ghoneim,M. M.
author_facet Ghoneim,M. M.
El-Hallag,I. S.
author_role author
author2 El-Hallag,I. S.
author2_role author
dc.contributor.author.fl_str_mv Ghoneim,M. M.
El-Hallag,I. S.
dc.subject.por.fl_str_mv ruthenium-borane complexe
convolutive voltammetry
chronoamperometry
chronopotentiometry
digital simulation
topic ruthenium-borane complexe
convolutive voltammetry
chronoamperometry
chronopotentiometry
digital simulation
description Electrochemical behavior of hexamethylbenzene isocloso ruthenium-borane complex [(C6Me6)-isocloso-1-RuB9 H9] was investigated at a glassy carbon electrode in 0.1 mol L-1 tetrabutyl ammonium perchlorate dissolved in methylene chloride, at - 20 ºC < T < 21 ºC using convolutive cyclic voltammetry, chronoamperometry and chronopotentiometry techniques. The chemical and electrochemical parameters of the investigated complex have been determined and confirmed via digital simulation method. Low-temperature diffusion coefficient and heterogeneous electron transfer kinetics of the complex [(C6Me6)-isocloso-1-RuB9 H9] were reported. On the basis of the obtained data, the electrode reaction of the complex [(C6Me6)-isocloso-1-RuB9 H9] was suggested and discussed.
publishDate 2010
dc.date.none.fl_str_mv 2010-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000100003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010000100003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532010000100003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.21 n.1 2010
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
_version_ 1750318170582810625

Registros relacionados