Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives
Autor(a) principal: | |
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Data de Publicação: | 2005 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000300004 |
Resumo: | Thin films have been created on the surface of highly oriented pyrolytic graphite electrodes from chemically synthesized pi-donor species by using the cyclic voltammetry technique and in situ electrochemistry-atomic force microscopy. Results indicate that it is possible to form new compounds called molecular materials from the coupling of electro-oxidized N-trifluoromethanesulfonyl-1-azahexa-1,3,5-triene species and a [Cr(C2O4)3]3- anion. Different techniques such as AFM, SEM and EDS were employed to characterize the films morphology and composition. Results indicate that the new materials exhibited a particular electrochemical response and a different film texture depending on the chemical composition of the starting compounds. |
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Journal of the Brazilian Chemical Society (Online) |
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Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivativesthin filmselectrodepositionin situ AFMThin films have been created on the surface of highly oriented pyrolytic graphite electrodes from chemically synthesized pi-donor species by using the cyclic voltammetry technique and in situ electrochemistry-atomic force microscopy. Results indicate that it is possible to form new compounds called molecular materials from the coupling of electro-oxidized N-trifluoromethanesulfonyl-1-azahexa-1,3,5-triene species and a [Cr(C2O4)3]3- anion. Different techniques such as AFM, SEM and EDS were employed to characterize the films morphology and composition. Results indicate that the new materials exhibited a particular electrochemical response and a different film texture depending on the chemical composition of the starting compounds.Sociedade Brasileira de Química2005-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000300004Journal of the Brazilian Chemical Society v.16 n.3a 2005reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532005000300004info:eu-repo/semantics/openAccessRivera,MargaritaAlvarez-Toledano,CecilioMoreno,AbelSepúlveda-Sánchez,José D.Hernández-Pérez,TomásSánchez-Vergara,María E.eng2005-07-18T00:00:00Zoai:scielo:S0103-50532005000300004Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2005-07-18T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
title |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
spellingShingle |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives Rivera,Margarita thin films electrodeposition in situ AFM |
title_short |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
title_full |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
title_fullStr |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
title_full_unstemmed |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
title_sort |
Electrochemical and atomic force microscopy investigations of new materials from N-trifluoromethanesulfonyl-1-azahexa-1,3,5-trienes derivatives |
author |
Rivera,Margarita |
author_facet |
Rivera,Margarita Alvarez-Toledano,Cecilio Moreno,Abel Sepúlveda-Sánchez,José D. Hernández-Pérez,Tomás Sánchez-Vergara,María E. |
author_role |
author |
author2 |
Alvarez-Toledano,Cecilio Moreno,Abel Sepúlveda-Sánchez,José D. Hernández-Pérez,Tomás Sánchez-Vergara,María E. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Rivera,Margarita Alvarez-Toledano,Cecilio Moreno,Abel Sepúlveda-Sánchez,José D. Hernández-Pérez,Tomás Sánchez-Vergara,María E. |
dc.subject.por.fl_str_mv |
thin films electrodeposition in situ AFM |
topic |
thin films electrodeposition in situ AFM |
description |
Thin films have been created on the surface of highly oriented pyrolytic graphite electrodes from chemically synthesized pi-donor species by using the cyclic voltammetry technique and in situ electrochemistry-atomic force microscopy. Results indicate that it is possible to form new compounds called molecular materials from the coupling of electro-oxidized N-trifluoromethanesulfonyl-1-azahexa-1,3,5-triene species and a [Cr(C2O4)3]3- anion. Different techniques such as AFM, SEM and EDS were employed to characterize the films morphology and composition. Results indicate that the new materials exhibited a particular electrochemical response and a different film texture depending on the chemical composition of the starting compounds. |
publishDate |
2005 |
dc.date.none.fl_str_mv |
2005-06-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000300004 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532005000300004 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532005000300004 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.16 n.3a 2005 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318166176694272 |