A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima

Detalhes bibliográficos
Autor(a) principal: Nogueira,Raquel T.
Data de Publicação: 2002
Outros Autores: Giacomini,Rosana A., Shepherd,George J., Imamura,Paulo M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300015
Resumo: A new ent-clerodane and two known ent-labdanes were isolated from the barks of Hymenaea courbaril var. altissima (Ducke). The new diterpene was identified, after esterification with diazomethane, as methyl (-)-(5R,8S,9S,10R)-clerod-3-en-15-oate and known diterpenes were identified as methyl (-)-copalate and methyl (-)-eperuate. From the EtOAc extract of seed pods a known methyl (-)-zanzibarate was isolated. The structures of isolated compounds were elucidated based on spectroscopic studies.
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spelling A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissimaHymenaea courbaril var. altissimaent-clerodaneent-labdaneA new ent-clerodane and two known ent-labdanes were isolated from the barks of Hymenaea courbaril var. altissima (Ducke). The new diterpene was identified, after esterification with diazomethane, as methyl (-)-(5R,8S,9S,10R)-clerod-3-en-15-oate and known diterpenes were identified as methyl (-)-copalate and methyl (-)-eperuate. From the EtOAc extract of seed pods a known methyl (-)-zanzibarate was isolated. The structures of isolated compounds were elucidated based on spectroscopic studies.Sociedade Brasileira de Química2002-06-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300015Journal of the Brazilian Chemical Society v.13 n.3 2002reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532002000300015info:eu-repo/semantics/openAccessNogueira,Raquel T.Giacomini,Rosana A.Shepherd,George J.Imamura,Paulo M.eng2002-07-01T00:00:00Zoai:scielo:S0103-50532002000300015Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2002-07-01T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
title A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
spellingShingle A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
Nogueira,Raquel T.
Hymenaea courbaril var. altissima
ent-clerodane
ent-labdane
title_short A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
title_full A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
title_fullStr A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
title_full_unstemmed A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
title_sort A New ent-Clerodane Diterpene from Hymenaea courbaril var. altissima
author Nogueira,Raquel T.
author_facet Nogueira,Raquel T.
Giacomini,Rosana A.
Shepherd,George J.
Imamura,Paulo M.
author_role author
author2 Giacomini,Rosana A.
Shepherd,George J.
Imamura,Paulo M.
author2_role author
author
author
dc.contributor.author.fl_str_mv Nogueira,Raquel T.
Giacomini,Rosana A.
Shepherd,George J.
Imamura,Paulo M.
dc.subject.por.fl_str_mv Hymenaea courbaril var. altissima
ent-clerodane
ent-labdane
topic Hymenaea courbaril var. altissima
ent-clerodane
ent-labdane
description A new ent-clerodane and two known ent-labdanes were isolated from the barks of Hymenaea courbaril var. altissima (Ducke). The new diterpene was identified, after esterification with diazomethane, as methyl (-)-(5R,8S,9S,10R)-clerod-3-en-15-oate and known diterpenes were identified as methyl (-)-copalate and methyl (-)-eperuate. From the EtOAc extract of seed pods a known methyl (-)-zanzibarate was isolated. The structures of isolated compounds were elucidated based on spectroscopic studies.
publishDate 2002
dc.date.none.fl_str_mv 2002-06-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300015
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532002000300015
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532002000300015
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.13 n.3 2002
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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