Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae)
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010001200007 |
Resumo: | The phytochemical investigation of Solanum crinitum Lam led to the isolation from the fruit trichomes of four flavonoids, tiliroside (1), astragalin (2), kaempferol (3), biochanin A-7-O-β-D-apiofuranosyl-(1→5)-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside (7), along with 4-hydroxybenzoic acid (12), and four cinnamic acid derivatives, cis- and trans- coumaric acids (10 and 11) and cis- and trans- ethyl coumarate (8 and 9). Three tri-glycosyl-steroidal alkaloids, solamargine (13), 20-epi-solamargine (14) and solasonine (16) were isolated from the methanolic extract of the green fruits. The derivatives 3,5,7,4'-tretra-O-methyl-kaempferol (4), 3,7,4'-tri-O-methyl-kaempferol (5), 3,7,4'-tri-O-methyl-5-O-acetyl-kaempferol (6), the peracetyl-epi-solamargine (15) and peracetyl-solasonine (17) were prepared. The structures were established through the analysis of their spectral data. The complete ¹H and 13C NMR data assignments of the new peracetyl derivatives of the alkaloids were made. |
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Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae)Solanum crinitumSolanaceaesteroidal glycoalkaloidsflavonoidscinnamic acidsThe phytochemical investigation of Solanum crinitum Lam led to the isolation from the fruit trichomes of four flavonoids, tiliroside (1), astragalin (2), kaempferol (3), biochanin A-7-O-β-D-apiofuranosyl-(1→5)-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside (7), along with 4-hydroxybenzoic acid (12), and four cinnamic acid derivatives, cis- and trans- coumaric acids (10 and 11) and cis- and trans- ethyl coumarate (8 and 9). Three tri-glycosyl-steroidal alkaloids, solamargine (13), 20-epi-solamargine (14) and solasonine (16) were isolated from the methanolic extract of the green fruits. The derivatives 3,5,7,4'-tretra-O-methyl-kaempferol (4), 3,7,4'-tri-O-methyl-kaempferol (5), 3,7,4'-tri-O-methyl-5-O-acetyl-kaempferol (6), the peracetyl-epi-solamargine (15) and peracetyl-solasonine (17) were prepared. The structures were established through the analysis of their spectral data. The complete ¹H and 13C NMR data assignments of the new peracetyl derivatives of the alkaloids were made.Sociedade Brasileira de Química2010-12-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010001200007Journal of the Brazilian Chemical Society v.21 n.12 2010reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532010001200007info:eu-repo/semantics/openAccessCornelius,Marli T. F.Carvalho,Mário G. deSilva,Tania M. S. daAlves,Cassia C. F.Siston,Ana P. N.Alves,Kelly Z.Sant'Anna,Carlos M. R.Neto,Mario B.Eberlin,Marcos N.Braz-Filho,Raimundoeng2010-12-16T00:00:00Zoai:scielo:S0103-50532010001200007Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2010-12-16T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
title |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
spellingShingle |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) Cornelius,Marli T. F. Solanum crinitum Solanaceae steroidal glycoalkaloids flavonoids cinnamic acids |
title_short |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
title_full |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
title_fullStr |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
title_full_unstemmed |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
title_sort |
Other chemical constituents isolated from Solanum crinitum Lam. (Solanaceae) |
author |
Cornelius,Marli T. F. |
author_facet |
Cornelius,Marli T. F. Carvalho,Mário G. de Silva,Tania M. S. da Alves,Cassia C. F. Siston,Ana P. N. Alves,Kelly Z. Sant'Anna,Carlos M. R. Neto,Mario B. Eberlin,Marcos N. Braz-Filho,Raimundo |
author_role |
author |
author2 |
Carvalho,Mário G. de Silva,Tania M. S. da Alves,Cassia C. F. Siston,Ana P. N. Alves,Kelly Z. Sant'Anna,Carlos M. R. Neto,Mario B. Eberlin,Marcos N. Braz-Filho,Raimundo |
author2_role |
author author author author author author author author author |
dc.contributor.author.fl_str_mv |
Cornelius,Marli T. F. Carvalho,Mário G. de Silva,Tania M. S. da Alves,Cassia C. F. Siston,Ana P. N. Alves,Kelly Z. Sant'Anna,Carlos M. R. Neto,Mario B. Eberlin,Marcos N. Braz-Filho,Raimundo |
dc.subject.por.fl_str_mv |
Solanum crinitum Solanaceae steroidal glycoalkaloids flavonoids cinnamic acids |
topic |
Solanum crinitum Solanaceae steroidal glycoalkaloids flavonoids cinnamic acids |
description |
The phytochemical investigation of Solanum crinitum Lam led to the isolation from the fruit trichomes of four flavonoids, tiliroside (1), astragalin (2), kaempferol (3), biochanin A-7-O-β-D-apiofuranosyl-(1→5)-β-D-apiofuranosyl-(1→6)-β-D-glucopyranoside (7), along with 4-hydroxybenzoic acid (12), and four cinnamic acid derivatives, cis- and trans- coumaric acids (10 and 11) and cis- and trans- ethyl coumarate (8 and 9). Three tri-glycosyl-steroidal alkaloids, solamargine (13), 20-epi-solamargine (14) and solasonine (16) were isolated from the methanolic extract of the green fruits. The derivatives 3,5,7,4'-tretra-O-methyl-kaempferol (4), 3,7,4'-tri-O-methyl-kaempferol (5), 3,7,4'-tri-O-methyl-5-O-acetyl-kaempferol (6), the peracetyl-epi-solamargine (15) and peracetyl-solasonine (17) were prepared. The structures were established through the analysis of their spectral data. The complete ¹H and 13C NMR data assignments of the new peracetyl derivatives of the alkaloids were made. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-12-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010001200007 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532010001200007 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532010001200007 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.21 n.12 2010 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318171549597696 |