Studies Toward the Synthesis of Caramboxin Analogues

Detalhes bibliográficos
Autor(a) principal: Oliveira Filho,Ronaldo E.
Data de Publicação: 2019
Outros Autores: Higa,Vanessa M., Omori,Álvaro T.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000300528
Resumo: Intrigued by the recent discovery of caramboxin by Brazilian researchers, we present the results from our studies toward the racemic synthesis of caramboxin analogs through the ortho-carboxylation of 3,5-dimethoxy benzyl derivatives. Three different approaches were tested, and the route involving a Vilsmeier-Haack formylation followed by a Lindgren oxidation provide a potential intermediate for the synthesis of several caramboxin analogs.
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spelling Studies Toward the Synthesis of Caramboxin Analoguescaramboxinstar fruitVilsmeier-Haack reactionLindgren oxidationCurtius rearrangementBischler-Napieralski reactionIntrigued by the recent discovery of caramboxin by Brazilian researchers, we present the results from our studies toward the racemic synthesis of caramboxin analogs through the ortho-carboxylation of 3,5-dimethoxy benzyl derivatives. Three different approaches were tested, and the route involving a Vilsmeier-Haack formylation followed by a Lindgren oxidation provide a potential intermediate for the synthesis of several caramboxin analogs.Sociedade Brasileira de Química2019-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000300528Journal of the Brazilian Chemical Society v.30 n.3 2019reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0103-5053.20180202info:eu-repo/semantics/openAccessOliveira Filho,Ronaldo E.Higa,Vanessa M.Omori,Álvaro T.eng2019-02-14T00:00:00Zoai:scielo:S0103-50532019000300528Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2019-02-14T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Studies Toward the Synthesis of Caramboxin Analogues
title Studies Toward the Synthesis of Caramboxin Analogues
spellingShingle Studies Toward the Synthesis of Caramboxin Analogues
Oliveira Filho,Ronaldo E.
caramboxin
star fruit
Vilsmeier-Haack reaction
Lindgren oxidation
Curtius rearrangement
Bischler-Napieralski reaction
title_short Studies Toward the Synthesis of Caramboxin Analogues
title_full Studies Toward the Synthesis of Caramboxin Analogues
title_fullStr Studies Toward the Synthesis of Caramboxin Analogues
title_full_unstemmed Studies Toward the Synthesis of Caramboxin Analogues
title_sort Studies Toward the Synthesis of Caramboxin Analogues
author Oliveira Filho,Ronaldo E.
author_facet Oliveira Filho,Ronaldo E.
Higa,Vanessa M.
Omori,Álvaro T.
author_role author
author2 Higa,Vanessa M.
Omori,Álvaro T.
author2_role author
author
dc.contributor.author.fl_str_mv Oliveira Filho,Ronaldo E.
Higa,Vanessa M.
Omori,Álvaro T.
dc.subject.por.fl_str_mv caramboxin
star fruit
Vilsmeier-Haack reaction
Lindgren oxidation
Curtius rearrangement
Bischler-Napieralski reaction
topic caramboxin
star fruit
Vilsmeier-Haack reaction
Lindgren oxidation
Curtius rearrangement
Bischler-Napieralski reaction
description Intrigued by the recent discovery of caramboxin by Brazilian researchers, we present the results from our studies toward the racemic synthesis of caramboxin analogs through the ortho-carboxylation of 3,5-dimethoxy benzyl derivatives. Three different approaches were tested, and the route involving a Vilsmeier-Haack formylation followed by a Lindgren oxidation provide a potential intermediate for the synthesis of several caramboxin analogs.
publishDate 2019
dc.date.none.fl_str_mv 2019-03-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000300528
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532019000300528
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0103-5053.20180202
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.30 n.3 2019
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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