Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH

Detalhes bibliográficos
Autor(a) principal: Dias,Luiz C.
Data de Publicação: 1998
Outros Autores: Campano,Priscila L.
Tipo de documento: Relatório
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100017
Resumo: A series of <FONT FACE=Symbol>a,b</FONT>-unsaturated alkyl and aryl ketones, esters and N-methoxy-N-methyl-amides (Weinreb amides) containing an O-benzyl protecting group undergo conjugate reduction by H2/Pd/C in the presence of 2N NH4OH/MeOH at room temperature and ordinary pressure leaving the benzyl group intact
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spelling Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOHconjugate reductioninhibition of benzyl ether hydrogenolysischemoselective reduction of alphabeta-unsaturated compoundsselective catalytic hydrogenationA series of <FONT FACE=Symbol>a,b</FONT>-unsaturated alkyl and aryl ketones, esters and N-methoxy-N-methyl-amides (Weinreb amides) containing an O-benzyl protecting group undergo conjugate reduction by H2/Pd/C in the presence of 2N NH4OH/MeOH at room temperature and ordinary pressure leaving the benzyl group intactSociedade Brasileira de Química1998-02-01info:eu-repo/semantics/reportinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100017Journal of the Brazilian Chemical Society v.9 n.1 1998reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50531998000100017info:eu-repo/semantics/openAccessDias,Luiz C.Campano,Priscila L.eng2008-03-17T00:00:00Zoai:scielo:S0103-50531998000100017Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2008-03-17T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
title Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
spellingShingle Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
Dias,Luiz C.
conjugate reduction
inhibition of benzyl ether hydrogenolysis
chemoselective reduction of alpha
beta-unsaturated compounds
selective catalytic hydrogenation
title_short Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
title_full Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
title_fullStr Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
title_full_unstemmed Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
title_sort Conjugate Reduction of a,b-Unsaturated Carbonyl Compounds. Selective Inhibition of Benzyl Ether Hydrogenolysis by NH4OH/MeOH
author Dias,Luiz C.
author_facet Dias,Luiz C.
Campano,Priscila L.
author_role author
author2 Campano,Priscila L.
author2_role author
dc.contributor.author.fl_str_mv Dias,Luiz C.
Campano,Priscila L.
dc.subject.por.fl_str_mv conjugate reduction
inhibition of benzyl ether hydrogenolysis
chemoselective reduction of alpha
beta-unsaturated compounds
selective catalytic hydrogenation
topic conjugate reduction
inhibition of benzyl ether hydrogenolysis
chemoselective reduction of alpha
beta-unsaturated compounds
selective catalytic hydrogenation
description A series of <FONT FACE=Symbol>a,b</FONT>-unsaturated alkyl and aryl ketones, esters and N-methoxy-N-methyl-amides (Weinreb amides) containing an O-benzyl protecting group undergo conjugate reduction by H2/Pd/C in the presence of 2N NH4OH/MeOH at room temperature and ordinary pressure leaving the benzyl group intact
publishDate 1998
dc.date.none.fl_str_mv 1998-02-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/report
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format report
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100017
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50531998000100017
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50531998000100017
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.9 n.1 1998
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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