Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene

Detalhes bibliográficos
Autor(a) principal: Gusevskaya,Elena V.
Data de Publicação: 2003
Outros Autores: Silva,Marcio J. da
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Journal of the Brazilian Chemical Society (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100014
Resumo: The structures of diterpene derivatives resulting from the palladium catalyzed tandem oxidative coupling-oxidation of camphene, i.e., bis(2,2-dimethyl-bicyclo[2.2.1]hept-3-ylidene)ethane and (4,4-dimethylbicyclo[3.2.1]oct-2-on-3-yl)(2,2-dimethylbicyclo[2.2.1]hept-3-ylidene)methane, were elucidated using one- and two-dimensional ¹H and13C NMR techniques. Their stereochemistry was determined unambiguously by NOESY experiments.
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spelling Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphenecamphene oxidationpalladium catalystditerpene derivativesNMR spectroscopyNOESYThe structures of diterpene derivatives resulting from the palladium catalyzed tandem oxidative coupling-oxidation of camphene, i.e., bis(2,2-dimethyl-bicyclo[2.2.1]hept-3-ylidene)ethane and (4,4-dimethylbicyclo[3.2.1]oct-2-on-3-yl)(2,2-dimethylbicyclo[2.2.1]hept-3-ylidene)methane, were elucidated using one- and two-dimensional ¹H and13C NMR techniques. Their stereochemistry was determined unambiguously by NOESY experiments.Sociedade Brasileira de Química2003-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100014Journal of the Brazilian Chemical Society v.14 n.1 2003reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532003000100014info:eu-repo/semantics/openAccessGusevskaya,Elena V.Silva,Marcio J. daeng2003-04-14T00:00:00Zoai:scielo:S0103-50532003000100014Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2003-04-14T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
title Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
spellingShingle Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
Gusevskaya,Elena V.
camphene oxidation
palladium catalyst
diterpene derivatives
NMR spectroscopy
NOESY
title_short Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
title_full Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
title_fullStr Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
title_full_unstemmed Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
title_sort Elucidation of the stereochemistry of diterpene derivatives obtained by palladium catalyzed oxidative coupling-oxidation of camphene
author Gusevskaya,Elena V.
author_facet Gusevskaya,Elena V.
Silva,Marcio J. da
author_role author
author2 Silva,Marcio J. da
author2_role author
dc.contributor.author.fl_str_mv Gusevskaya,Elena V.
Silva,Marcio J. da
dc.subject.por.fl_str_mv camphene oxidation
palladium catalyst
diterpene derivatives
NMR spectroscopy
NOESY
topic camphene oxidation
palladium catalyst
diterpene derivatives
NMR spectroscopy
NOESY
description The structures of diterpene derivatives resulting from the palladium catalyzed tandem oxidative coupling-oxidation of camphene, i.e., bis(2,2-dimethyl-bicyclo[2.2.1]hept-3-ylidene)ethane and (4,4-dimethylbicyclo[3.2.1]oct-2-on-3-yl)(2,2-dimethylbicyclo[2.2.1]hept-3-ylidene)methane, were elucidated using one- and two-dimensional ¹H and13C NMR techniques. Their stereochemistry was determined unambiguously by NOESY experiments.
publishDate 2003
dc.date.none.fl_str_mv 2003-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100014
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532003000100014
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0103-50532003000100014
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Journal of the Brazilian Chemical Society v.14 n.1 2003
reponame:Journal of the Brazilian Chemical Society (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Journal of the Brazilian Chemical Society (Online)
collection Journal of the Brazilian Chemical Society (Online)
repository.name.fl_str_mv Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv ||office@jbcs.sbq.org.br
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