K10-montmorillonite as support for a cationic manganese(III)-salen complex
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Journal of the Brazilian Chemical Society (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000700017 |
Resumo: | A commercial K10-montmorillonite was used as support for the immobilization of a cationic manganese(III)-salen complex. The catalytic behavior of the resulting material was tested in the enantioselective epoxidation of three different alkenes, viz.: styrene, α-methylstyrene and 6-cyano-2,2-dimethylchromene, at 0 ºC, using three different oxidant systems: m-chloroperoxybenzoic acid (m-CPBA) and N-methylmorpholine (NMO) as co-oxidant, iodosylbenzene (PhIO) and sodium hypochlorite. All samples, before and after the catalytic studies, were characterised by nitrogen adsorption at -196 ºC, DRX, FTIR and chemical analysis, in order to evaluate the influence of the substrate/oxidant system on catalyst integrity. The catalytic results demonstrated a strong influence of the substrate and oxidant system on the enantiomeric excess (%ee) values. In some cases, these values were comparable to those in the corresponding homogeneous phase reactions. The results also highlighted the importance of optimizing the oxidant systems, since they may lead to the disruption of the complex from the support, and the consequent catalyst deactivation. |
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K10-montmorillonite as support for a cationic manganese(III)-salen complexK10-montmorillonitealkene epoxidationcatalyst supportmanganese(III)-salenA commercial K10-montmorillonite was used as support for the immobilization of a cationic manganese(III)-salen complex. The catalytic behavior of the resulting material was tested in the enantioselective epoxidation of three different alkenes, viz.: styrene, α-methylstyrene and 6-cyano-2,2-dimethylchromene, at 0 ºC, using three different oxidant systems: m-chloroperoxybenzoic acid (m-CPBA) and N-methylmorpholine (NMO) as co-oxidant, iodosylbenzene (PhIO) and sodium hypochlorite. All samples, before and after the catalytic studies, were characterised by nitrogen adsorption at -196 ºC, DRX, FTIR and chemical analysis, in order to evaluate the influence of the substrate/oxidant system on catalyst integrity. The catalytic results demonstrated a strong influence of the substrate and oxidant system on the enantiomeric excess (%ee) values. In some cases, these values were comparable to those in the corresponding homogeneous phase reactions. The results also highlighted the importance of optimizing the oxidant systems, since they may lead to the disruption of the complex from the support, and the consequent catalyst deactivation.Sociedade Brasileira de Química2009-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000700017Journal of the Brazilian Chemical Society v.20 n.7 2009reponame:Journal of the Brazilian Chemical Society (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0103-50532009000700017info:eu-repo/semantics/openAccessKuźniarska-Biernacka,IwonaPereira,ClaraCarvalho,Ana P.Pires,JoãoFreire,Cristinaeng2009-08-27T00:00:00Zoai:scielo:S0103-50532009000700017Revistahttp://jbcs.sbq.org.brONGhttps://old.scielo.br/oai/scielo-oai.php||office@jbcs.sbq.org.br1678-47900103-5053opendoar:2009-08-27T00:00Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
title |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
spellingShingle |
K10-montmorillonite as support for a cationic manganese(III)-salen complex Kuźniarska-Biernacka,Iwona K10-montmorillonite alkene epoxidation catalyst support manganese(III)-salen |
title_short |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
title_full |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
title_fullStr |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
title_full_unstemmed |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
title_sort |
K10-montmorillonite as support for a cationic manganese(III)-salen complex |
author |
Kuźniarska-Biernacka,Iwona |
author_facet |
Kuźniarska-Biernacka,Iwona Pereira,Clara Carvalho,Ana P. Pires,João Freire,Cristina |
author_role |
author |
author2 |
Pereira,Clara Carvalho,Ana P. Pires,João Freire,Cristina |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Kuźniarska-Biernacka,Iwona Pereira,Clara Carvalho,Ana P. Pires,João Freire,Cristina |
dc.subject.por.fl_str_mv |
K10-montmorillonite alkene epoxidation catalyst support manganese(III)-salen |
topic |
K10-montmorillonite alkene epoxidation catalyst support manganese(III)-salen |
description |
A commercial K10-montmorillonite was used as support for the immobilization of a cationic manganese(III)-salen complex. The catalytic behavior of the resulting material was tested in the enantioselective epoxidation of three different alkenes, viz.: styrene, α-methylstyrene and 6-cyano-2,2-dimethylchromene, at 0 ºC, using three different oxidant systems: m-chloroperoxybenzoic acid (m-CPBA) and N-methylmorpholine (NMO) as co-oxidant, iodosylbenzene (PhIO) and sodium hypochlorite. All samples, before and after the catalytic studies, were characterised by nitrogen adsorption at -196 ºC, DRX, FTIR and chemical analysis, in order to evaluate the influence of the substrate/oxidant system on catalyst integrity. The catalytic results demonstrated a strong influence of the substrate and oxidant system on the enantiomeric excess (%ee) values. In some cases, these values were comparable to those in the corresponding homogeneous phase reactions. The results also highlighted the importance of optimizing the oxidant systems, since they may lead to the disruption of the complex from the support, and the consequent catalyst deactivation. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000700017 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532009000700017 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0103-50532009000700017 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Journal of the Brazilian Chemical Society v.20 n.7 2009 reponame:Journal of the Brazilian Chemical Society (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Journal of the Brazilian Chemical Society (Online) |
collection |
Journal of the Brazilian Chemical Society (Online) |
repository.name.fl_str_mv |
Journal of the Brazilian Chemical Society (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
||office@jbcs.sbq.org.br |
_version_ |
1750318170201128960 |