Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y

Detalhes bibliográficos
Autor(a) principal: Berezuk,Márcio E.
Data de Publicação: 2012
Outros Autores: Paesano Jr.,Andrea, Carvalho,Nakédia M. F., Horn Jr.,Adolfo, Arroyo,Pedro A., Cardozo-Filho,Lúcio
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003
Resumo: Zeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage.
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spelling Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Ypiperazineship-in-a-bottle encapsulationzeolite YZeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage.Sociedade Brasileira de Química2012-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003Química Nova v.35 n.5 2012reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422012000500003info:eu-repo/semantics/openAccessBerezuk,Márcio E.Paesano Jr.,AndreaCarvalho,Nakédia M. F.Horn Jr.,AdolfoArroyo,Pedro A.Cardozo-Filho,Lúcioeng2012-07-02T00:00:00Zoai:scielo:S0100-40422012000500003Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2012-07-02T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
title Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
spellingShingle Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
Berezuk,Márcio E.
piperazine
ship-in-a-bottle encapsulation
zeolite Y
title_short Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
title_full Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
title_fullStr Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
title_full_unstemmed Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
title_sort Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
author Berezuk,Márcio E.
author_facet Berezuk,Márcio E.
Paesano Jr.,Andrea
Carvalho,Nakédia M. F.
Horn Jr.,Adolfo
Arroyo,Pedro A.
Cardozo-Filho,Lúcio
author_role author
author2 Paesano Jr.,Andrea
Carvalho,Nakédia M. F.
Horn Jr.,Adolfo
Arroyo,Pedro A.
Cardozo-Filho,Lúcio
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Berezuk,Márcio E.
Paesano Jr.,Andrea
Carvalho,Nakédia M. F.
Horn Jr.,Adolfo
Arroyo,Pedro A.
Cardozo-Filho,Lúcio
dc.subject.por.fl_str_mv piperazine
ship-in-a-bottle encapsulation
zeolite Y
topic piperazine
ship-in-a-bottle encapsulation
zeolite Y
description Zeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage.
publishDate 2012
dc.date.none.fl_str_mv 2012-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-40422012000500003
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.35 n.5 2012
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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