Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y
Autor(a) principal: | |
---|---|
Data de Publicação: | 2012 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Química Nova (Online) |
Texto Completo: | http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003 |
Resumo: | Zeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage. |
id |
SBQ-3_1d1fae129566f430b593d9ab0b72658f |
---|---|
oai_identifier_str |
oai:scielo:S0100-40422012000500003 |
network_acronym_str |
SBQ-3 |
network_name_str |
Química Nova (Online) |
repository_id_str |
|
spelling |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Ypiperazineship-in-a-bottle encapsulationzeolite YZeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage.Sociedade Brasileira de Química2012-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003Química Nova v.35 n.5 2012reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.1590/S0100-40422012000500003info:eu-repo/semantics/openAccessBerezuk,Márcio E.Paesano Jr.,AndreaCarvalho,Nakédia M. F.Horn Jr.,AdolfoArroyo,Pedro A.Cardozo-Filho,Lúcioeng2012-07-02T00:00:00Zoai:scielo:S0100-40422012000500003Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2012-07-02T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false |
dc.title.none.fl_str_mv |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
title |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
spellingShingle |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y Berezuk,Márcio E. piperazine ship-in-a-bottle encapsulation zeolite Y |
title_short |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
title_full |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
title_fullStr |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
title_full_unstemmed |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
title_sort |
Synthesis and characterization of Fe(III)-piperazine-derived complexes encapsulated in zeolite Y |
author |
Berezuk,Márcio E. |
author_facet |
Berezuk,Márcio E. Paesano Jr.,Andrea Carvalho,Nakédia M. F. Horn Jr.,Adolfo Arroyo,Pedro A. Cardozo-Filho,Lúcio |
author_role |
author |
author2 |
Paesano Jr.,Andrea Carvalho,Nakédia M. F. Horn Jr.,Adolfo Arroyo,Pedro A. Cardozo-Filho,Lúcio |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Berezuk,Márcio E. Paesano Jr.,Andrea Carvalho,Nakédia M. F. Horn Jr.,Adolfo Arroyo,Pedro A. Cardozo-Filho,Lúcio |
dc.subject.por.fl_str_mv |
piperazine ship-in-a-bottle encapsulation zeolite Y |
topic |
piperazine ship-in-a-bottle encapsulation zeolite Y |
description |
Zeolite-encapsulated complexes have been widely applied in hydrocarbon oxidation catalysis. The "ship-in-a-bottle" encapsulation of iron(III) complexes containing piperazine and piperazine-derivative ligands in zeolite-Y is described. The flexible ligand methodology was employed and the efficiency and reproducibility of the procedure was investigated. The catalysts were characterized employing several techniques and the results indicate the presence of coordinated and uncoordinated iron(III) ions inside and outside the zeolitic cage. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01-01 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003 |
url |
http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422012000500003 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
10.1590/S0100-40422012000500003 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
text/html |
dc.publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
publisher.none.fl_str_mv |
Sociedade Brasileira de Química |
dc.source.none.fl_str_mv |
Química Nova v.35 n.5 2012 reponame:Química Nova (Online) instname:Sociedade Brasileira de Química (SBQ) instacron:SBQ |
instname_str |
Sociedade Brasileira de Química (SBQ) |
instacron_str |
SBQ |
institution |
SBQ |
reponame_str |
Química Nova (Online) |
collection |
Química Nova (Online) |
repository.name.fl_str_mv |
Química Nova (Online) - Sociedade Brasileira de Química (SBQ) |
repository.mail.fl_str_mv |
quimicanova@sbq.org.br |
_version_ |
1750318113484701696 |