HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS

Detalhes bibliográficos
Autor(a) principal: Lamoureux,Guy
Data de Publicação: 2019
Outros Autores: Ogilvie,John F.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019004700812
Resumo: The importance of hybrid atomic orbitals, both historically and mathematically, is reviewed. Our new analysis of the original derivation of the sp3, sp2, sp model reveals serious errors. Based on a critical survey of the literature, we submit six formal criteria that deprecate the use of hybrid orbitals in a pedagogical context. A sound mathematical basis of sp3 and sp2 formulae does not exist; hybrid atomic orbitals have hence no legitimate role in the teaching of organic chemistry.
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spelling HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTSchemical educationundergraduate Organic Chemistrymisconceptionshybrid orbitalsThe importance of hybrid atomic orbitals, both historically and mathematically, is reviewed. Our new analysis of the original derivation of the sp3, sp2, sp model reveals serious errors. Based on a critical survey of the literature, we submit six formal criteria that deprecate the use of hybrid orbitals in a pedagogical context. A sound mathematical basis of sp3 and sp2 formulae does not exist; hybrid atomic orbitals have hence no legitimate role in the teaching of organic chemistry.Sociedade Brasileira de Química2019-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019004700812Química Nova v.42 n.7 2019reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170376info:eu-repo/semantics/openAccessLamoureux,GuyOgilvie,John F.eng2019-08-23T00:00:00Zoai:scielo:S0100-40422019004700812Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2019-08-23T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
title HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
spellingShingle HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
Lamoureux,Guy
chemical education
undergraduate Organic Chemistry
misconceptions
hybrid orbitals
title_short HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
title_full HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
title_fullStr HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
title_full_unstemmed HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
title_sort HYBRID ATOMIC ORBITALS IN ORGANIC CHEMISTRY. PART 1: CRITIQUE OF FORMAL ASPECTS
author Lamoureux,Guy
author_facet Lamoureux,Guy
Ogilvie,John F.
author_role author
author2 Ogilvie,John F.
author2_role author
dc.contributor.author.fl_str_mv Lamoureux,Guy
Ogilvie,John F.
dc.subject.por.fl_str_mv chemical education
undergraduate Organic Chemistry
misconceptions
hybrid orbitals
topic chemical education
undergraduate Organic Chemistry
misconceptions
hybrid orbitals
description The importance of hybrid atomic orbitals, both historically and mathematically, is reviewed. Our new analysis of the original derivation of the sp3, sp2, sp model reveals serious errors. Based on a critical survey of the literature, we submit six formal criteria that deprecate the use of hybrid orbitals in a pedagogical context. A sound mathematical basis of sp3 and sp2 formulae does not exist; hybrid atomic orbitals have hence no legitimate role in the teaching of organic chemistry.
publishDate 2019
dc.date.none.fl_str_mv 2019-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019004700812
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019004700812
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.21577/0100-4042.20170376
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.42 n.7 2019
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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