SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE

Detalhes bibliográficos
Autor(a) principal: Cárdenas-Riojas,Andy Alfredo
Data de Publicação: 2019
Outros Autores: Wong,Ademar, Sotomayor,Maria Del Pilar T., Rosa-Toro,Adolfo La, Baena-Moncada,Angélica María
Tipo de documento: Artigo
Idioma: spa
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000300255
Resumo: Two sensors were synthesized for the detection of free cyanide (CN-), based on silver sulfide nanoparticles (Np-Ag2S) supported on Multiwall Carbon Nanotubes (MWCNT) and hierarchical porous carbon (HPC). The Ag2S/HPC400 and Ag2S/MWCNT were characterized by physicochemical techniques such as Raman spectroscopy, X-Ray diffraction (XRD) and Scanning electron microscopy (SEM). These sensors were evaluated against the detection of free cyanide by potentiometry; the stability, reproducibility and linearity of each sensor were determined. A limit of detection of 3.34 µg L-1 and a limit of quantification of 11.05 µg L-1 for Ag2S/HPC400 sensor was obtained; while for the Ag2S/MWCNT sensor a limit of detection and limit of quantification value of 23.17 µg L-1 and 76.46 µg L-1 were obtained, respectively. The results show that the presence of carbonaceous materials with a hierarchical structure improves the limits of quantification and detection of the Ag2S/HPC400 sensor.
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spelling SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBREhierarchical porous carbonsensorsfree cyanidesilver sulfidemultiwall carbon nanotubesTwo sensors were synthesized for the detection of free cyanide (CN-), based on silver sulfide nanoparticles (Np-Ag2S) supported on Multiwall Carbon Nanotubes (MWCNT) and hierarchical porous carbon (HPC). The Ag2S/HPC400 and Ag2S/MWCNT were characterized by physicochemical techniques such as Raman spectroscopy, X-Ray diffraction (XRD) and Scanning electron microscopy (SEM). These sensors were evaluated against the detection of free cyanide by potentiometry; the stability, reproducibility and linearity of each sensor were determined. A limit of detection of 3.34 µg L-1 and a limit of quantification of 11.05 µg L-1 for Ag2S/HPC400 sensor was obtained; while for the Ag2S/MWCNT sensor a limit of detection and limit of quantification value of 23.17 µg L-1 and 76.46 µg L-1 were obtained, respectively. The results show that the presence of carbonaceous materials with a hierarchical structure improves the limits of quantification and detection of the Ag2S/HPC400 sensor.Sociedade Brasileira de Química2019-03-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000300255Química Nova v.42 n.3 2019reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170338info:eu-repo/semantics/openAccessCárdenas-Riojas,Andy AlfredoWong,AdemarSotomayor,Maria Del Pilar T.Rosa-Toro,Adolfo LaBaena-Moncada,Angélica Maríaspa2019-04-30T00:00:00Zoai:scielo:S0100-40422019000300255Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2019-04-30T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
title SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
spellingShingle SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
Cárdenas-Riojas,Andy Alfredo
hierarchical porous carbon
sensors
free cyanide
silver sulfide
multiwall carbon nanotubes
title_short SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
title_full SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
title_fullStr SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
title_full_unstemmed SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
title_sort SENSOR POTENCIOMÉTRICO BASADO EN NANOPARTÍCULAS DE SULFURO DE PLATA SOPORTADAS EN MATERIALES CARBONOSOS PARA LA DETECCIÓN DE CIANURO LIBRE
author Cárdenas-Riojas,Andy Alfredo
author_facet Cárdenas-Riojas,Andy Alfredo
Wong,Ademar
Sotomayor,Maria Del Pilar T.
Rosa-Toro,Adolfo La
Baena-Moncada,Angélica María
author_role author
author2 Wong,Ademar
Sotomayor,Maria Del Pilar T.
Rosa-Toro,Adolfo La
Baena-Moncada,Angélica María
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Cárdenas-Riojas,Andy Alfredo
Wong,Ademar
Sotomayor,Maria Del Pilar T.
Rosa-Toro,Adolfo La
Baena-Moncada,Angélica María
dc.subject.por.fl_str_mv hierarchical porous carbon
sensors
free cyanide
silver sulfide
multiwall carbon nanotubes
topic hierarchical porous carbon
sensors
free cyanide
silver sulfide
multiwall carbon nanotubes
description Two sensors were synthesized for the detection of free cyanide (CN-), based on silver sulfide nanoparticles (Np-Ag2S) supported on Multiwall Carbon Nanotubes (MWCNT) and hierarchical porous carbon (HPC). The Ag2S/HPC400 and Ag2S/MWCNT were characterized by physicochemical techniques such as Raman spectroscopy, X-Ray diffraction (XRD) and Scanning electron microscopy (SEM). These sensors were evaluated against the detection of free cyanide by potentiometry; the stability, reproducibility and linearity of each sensor were determined. A limit of detection of 3.34 µg L-1 and a limit of quantification of 11.05 µg L-1 for Ag2S/HPC400 sensor was obtained; while for the Ag2S/MWCNT sensor a limit of detection and limit of quantification value of 23.17 µg L-1 and 76.46 µg L-1 were obtained, respectively. The results show that the presence of carbonaceous materials with a hierarchical structure improves the limits of quantification and detection of the Ag2S/HPC400 sensor.
publishDate 2019
dc.date.none.fl_str_mv 2019-03-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000300255
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422019000300255
dc.language.iso.fl_str_mv spa
language spa
dc.relation.none.fl_str_mv 10.21577/0100-4042.20170338
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.42 n.3 2019
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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