A FAMÍLIA DAS BAMBUS[N]URILAS

Detalhes bibliográficos
Autor(a) principal: Cicolani,Renato Salviato
Data de Publicação: 2018
Outros Autores: Demets,Grégoire Jean-François
Tipo de documento: Artigo
Idioma: por
Título da fonte: Química Nova (Online)
Texto Completo: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000800912
Resumo: This review describes the properties of the bambus[n]urils and some of their applications. These macrocycles are synthesized by the condensation of glycoluril derivatives and paraformaldehyde in acid medium. The alternate conformation of the monomers creates low electron density regions at the center of the macrocycle cavity and this is the main cause of bambus[n]urils high affinity and selectivity towards anions. Due to these properties, bambus[n]urils have been used for the detection of anions in mixtures, but also in complex supramolecular systems where they act as donors in photoinduced electron-transfer processes, and synthetic ion-channels for example. These compounds are relatively recent and deserve attention for their potential in many branches of chemistry, especially in supramolecular and inclusion chemistry.
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spelling A FAMÍLIA DAS BAMBUS[N]URILAScavitandsbambus[n]urilsanion bindinginclusion chemistryThis review describes the properties of the bambus[n]urils and some of their applications. These macrocycles are synthesized by the condensation of glycoluril derivatives and paraformaldehyde in acid medium. The alternate conformation of the monomers creates low electron density regions at the center of the macrocycle cavity and this is the main cause of bambus[n]urils high affinity and selectivity towards anions. Due to these properties, bambus[n]urils have been used for the detection of anions in mixtures, but also in complex supramolecular systems where they act as donors in photoinduced electron-transfer processes, and synthetic ion-channels for example. These compounds are relatively recent and deserve attention for their potential in many branches of chemistry, especially in supramolecular and inclusion chemistry.Sociedade Brasileira de Química2018-08-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000800912Química Nova v.41 n.8 2018reponame:Química Nova (Online)instname:Sociedade Brasileira de Química (SBQ)instacron:SBQ10.21577/0100-4042.20170250info:eu-repo/semantics/openAccessCicolani,Renato SalviatoDemets,Grégoire Jean-Françoispor2018-10-16T00:00:00Zoai:scielo:S0100-40422018000800912Revistahttps://www.scielo.br/j/qn/ONGhttps://old.scielo.br/oai/scielo-oai.phpquimicanova@sbq.org.br1678-70640100-4042opendoar:2018-10-16T00:00Química Nova (Online) - Sociedade Brasileira de Química (SBQ)false
dc.title.none.fl_str_mv A FAMÍLIA DAS BAMBUS[N]URILAS
title A FAMÍLIA DAS BAMBUS[N]URILAS
spellingShingle A FAMÍLIA DAS BAMBUS[N]URILAS
Cicolani,Renato Salviato
cavitands
bambus[n]urils
anion binding
inclusion chemistry
title_short A FAMÍLIA DAS BAMBUS[N]URILAS
title_full A FAMÍLIA DAS BAMBUS[N]URILAS
title_fullStr A FAMÍLIA DAS BAMBUS[N]URILAS
title_full_unstemmed A FAMÍLIA DAS BAMBUS[N]URILAS
title_sort A FAMÍLIA DAS BAMBUS[N]URILAS
author Cicolani,Renato Salviato
author_facet Cicolani,Renato Salviato
Demets,Grégoire Jean-François
author_role author
author2 Demets,Grégoire Jean-François
author2_role author
dc.contributor.author.fl_str_mv Cicolani,Renato Salviato
Demets,Grégoire Jean-François
dc.subject.por.fl_str_mv cavitands
bambus[n]urils
anion binding
inclusion chemistry
topic cavitands
bambus[n]urils
anion binding
inclusion chemistry
description This review describes the properties of the bambus[n]urils and some of their applications. These macrocycles are synthesized by the condensation of glycoluril derivatives and paraformaldehyde in acid medium. The alternate conformation of the monomers creates low electron density regions at the center of the macrocycle cavity and this is the main cause of bambus[n]urils high affinity and selectivity towards anions. Due to these properties, bambus[n]urils have been used for the detection of anions in mixtures, but also in complex supramolecular systems where they act as donors in photoinduced electron-transfer processes, and synthetic ion-channels for example. These compounds are relatively recent and deserve attention for their potential in many branches of chemistry, especially in supramolecular and inclusion chemistry.
publishDate 2018
dc.date.none.fl_str_mv 2018-08-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000800912
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422018000800912
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv 10.21577/0100-4042.20170250
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Sociedade Brasileira de Química
publisher.none.fl_str_mv Sociedade Brasileira de Química
dc.source.none.fl_str_mv Química Nova v.41 n.8 2018
reponame:Química Nova (Online)
instname:Sociedade Brasileira de Química (SBQ)
instacron:SBQ
instname_str Sociedade Brasileira de Química (SBQ)
instacron_str SBQ
institution SBQ
reponame_str Química Nova (Online)
collection Química Nova (Online)
repository.name.fl_str_mv Química Nova (Online) - Sociedade Brasileira de Química (SBQ)
repository.mail.fl_str_mv quimicanova@sbq.org.br
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