Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)

Detalhes bibliográficos
Autor(a) principal: Silva, Murillo Romero da
Data de Publicação: 2017
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Repositório Institucional da UFSCAR
Texto Completo: https://repositorio.ufscar.br/handle/ufscar/9081
Resumo: Shape memory alloys (SMA) are alloys that undergo martensitic transformation due to an external solicitation (temperature, stress, strain or magnetic field) and are capable of recovering permanent deformation when heated above a critical temperature. The most used shape memory alloys are Ti-Ni- and Cu-based. Cu-based SMA have some advantages due to better thermal and electrical conductivity, lower production cost and are easier to process. The main disadvantage of Cu-based SMA is its low ductility. This property is improved by decreasing the grain size and by a reduction of microstructural heterogeneities. This can be achieved at the surface of structural components after LASER remelting, through which the surface of the material is remelted by a LASER beam and solidifies under extremely high cooling rates. In this context, the aim of the present work is to investigate the influence of LASER surface remelting in the microstructure, thermal stability and mechanical properties of Cu-11.8Al-3.2Ni-3Mn (wt. %) SMA plates obtained by suction casting. The samples were characterized by optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, electron backscatter diffraction, X-ray computed tomography, X-ray diffraction, differential scanning calorimetry as well as by tensile and microhardness tests. The results show that small shifts in the transformation temperatures occur due to the LASER treatment. It was observed that only the monoclinic β’1 martensitic phase formed in the as cast and LASER treated samples. The LASER treatment provided an improvement in mechanical properties with an increase of up to 162 MPa in fracture stress, up to 2.2% in fracture strain and up to 21 HV in microhardness when compared with the as-cast sample. This makes the surface remelting treatment a promising method for improving the mechanical properties of Cu-based SMA.
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spelling Silva, Murillo Romero daBolfarini, Claudemirohttp://lattes.cnpq.br/9231627080617037Gargarella, Piterhttp://lattes.cnpq.br/4641435644243916http://lattes.cnpq.br/77413157913685059235b5ad-e4b4-43ce-a2a6-be4b121ee4c32017-09-06T18:34:27Z2017-09-06T18:34:27Z2017-02-10SILVA, Murillo Romero da. Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso). 2017. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2017. Disponível em: https://repositorio.ufscar.br/handle/ufscar/9081.https://repositorio.ufscar.br/handle/ufscar/9081Shape memory alloys (SMA) are alloys that undergo martensitic transformation due to an external solicitation (temperature, stress, strain or magnetic field) and are capable of recovering permanent deformation when heated above a critical temperature. The most used shape memory alloys are Ti-Ni- and Cu-based. Cu-based SMA have some advantages due to better thermal and electrical conductivity, lower production cost and are easier to process. The main disadvantage of Cu-based SMA is its low ductility. This property is improved by decreasing the grain size and by a reduction of microstructural heterogeneities. This can be achieved at the surface of structural components after LASER remelting, through which the surface of the material is remelted by a LASER beam and solidifies under extremely high cooling rates. In this context, the aim of the present work is to investigate the influence of LASER surface remelting in the microstructure, thermal stability and mechanical properties of Cu-11.8Al-3.2Ni-3Mn (wt. %) SMA plates obtained by suction casting. The samples were characterized by optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, electron backscatter diffraction, X-ray computed tomography, X-ray diffraction, differential scanning calorimetry as well as by tensile and microhardness tests. The results show that small shifts in the transformation temperatures occur due to the LASER treatment. It was observed that only the monoclinic β’1 martensitic phase formed in the as cast and LASER treated samples. The LASER treatment provided an improvement in mechanical properties with an increase of up to 162 MPa in fracture stress, up to 2.2% in fracture strain and up to 21 HV in microhardness when compared with the as-cast sample. This makes the surface remelting treatment a promising method for improving the mechanical properties of Cu-based SMA.Ligas com memória de forma (LMF) sofrem transformação martensítica devido a uma solicitação externa (temperatura, tensão, deformação ou campo magnético) e são capazes de recuperar deformações permanentes quando aquecidas acima de uma temperatura crítica. Dentre as LMF mais utilizadas se destacam aquelas à base de Ti e Ni e aquelas à base de Cu. As à base de Cu apresentam vantagens devido a melhor condutividade térmica e elétrica, menor custo de produção e maior facilidade de processamento. A principal desvantagem das LMF à base de cobre é a baixa ductilidade. Uma forma de melhorar essa propriedade é promovendo uma diminuição no tamanho de grão e uma redução das heterogeneidades microestruturais. Isso pode ser obtido no tratamento de refusão superficial a LASER, no qual a superfície do material é refundida por um feixe de LASER e solidificada sob altas taxas de resfriamento. Nesse contexto, o objetivo da presente dissertação de mestrado é analisar a influência do tratamento de refusão superficial a LASER na microestrutura, na estabilidade térmica e nas propriedades mecânicas de placas da LMF Cu-11,8Al-3,2Ni-3Mn (% peso) obtidas através de fundição por sucção. As amostras foram caracterizadas por microscopia óptica e eletrônica de varredura, espectometria de energia dispersiva de raios X, difração de elétrons retroespalhados, tomografia computacional por raios X, calorimetria diferencial de varredura, difração de raios X, ensaio de tração e microdureza. A análise dos resultados mostrou que as temperaturas de transformação sofreram pequenas variações e nenhuma nova fase foi observada após o tratamento de refusão a LASER, sendo observada apenas a presença da fase monoclínica martensítica β’1. O tratamento propiciou uma melhoria nas propriedades mecânicas das placas obtidas por fundição por sucção, com um aumento em até 162 MPa na tensão de fratura, em até 2,2 % na deformação de fratua e em até 21 HV na microdureza, fazendo deste tratamento um método promissor para melhorar as propriedades mecânicas das LMF à base de Cu.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)CNPq: 132132/2015-0FAPESP: 2015/04134-7porUniversidade Federal de São CarlosCâmpus São CarlosPrograma de Pós-Graduação em Ciência e Engenharia de Materiais - PPGCEMUFSCarLigas com memória de formaRefusão superficial a laserTransformação martensíticaResfriamento rápidoShape memory alloysLaser surface remeltingMartensitic transformationRapid coolingENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICARefusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)Laser surface remelting of a Cu-11.8Al-3.2Ni-3Mn (wt. %) shape memory alloyinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisOnline600600ea2697dd-8d22-4c7a-8bdd-487c739e04c7info:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFSCARinstname:Universidade Federal de São Carlos (UFSCAR)instacron:UFSCARORIGINALDissMRS.pdfDissMRS.pdfapplication/pdf7292710https://repositorio.ufscar.br/bitstream/ufscar/9081/1/DissMRS.pdfb518987951bcfa31933df3cece2f16cfMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81957https://repositorio.ufscar.br/bitstream/ufscar/9081/2/license.txtae0398b6f8b235e40ad82cba6c50031dMD52TEXTDissMRS.pdf.txtDissMRS.pdf.txtExtracted texttext/plain147582https://repositorio.ufscar.br/bitstream/ufscar/9081/3/DissMRS.pdf.txta8b102e3f71b039cea6f5daf43770300MD53THUMBNAILDissMRS.pdf.jpgDissMRS.pdf.jpgIM Thumbnailimage/jpeg5813https://repositorio.ufscar.br/bitstream/ufscar/9081/4/DissMRS.pdf.jpg51de8b979a0b91b78453bb1a0e4d79ceMD54ufscar/90812023-09-18 18:31:26.228oai:repositorio.ufscar.br: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Repositório InstitucionalPUBhttps://repositorio.ufscar.br/oai/requestopendoar:43222023-09-18T18:31:26Repositório Institucional da UFSCAR - Universidade Federal de São Carlos (UFSCAR)false
dc.title.por.fl_str_mv Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
dc.title.alternative.eng.fl_str_mv Laser surface remelting of a Cu-11.8Al-3.2Ni-3Mn (wt. %) shape memory alloy
title Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
spellingShingle Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
Silva, Murillo Romero da
Ligas com memória de forma
Refusão superficial a laser
Transformação martensítica
Resfriamento rápido
Shape memory alloys
Laser surface remelting
Martensitic transformation
Rapid cooling
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
title_short Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
title_full Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
title_fullStr Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
title_full_unstemmed Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
title_sort Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso)
author Silva, Murillo Romero da
author_facet Silva, Murillo Romero da
author_role author
dc.contributor.authorlattes.por.fl_str_mv http://lattes.cnpq.br/7741315791368505
dc.contributor.author.fl_str_mv Silva, Murillo Romero da
dc.contributor.advisor1.fl_str_mv Bolfarini, Claudemiro
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/9231627080617037
dc.contributor.advisor-co1.fl_str_mv Gargarella, Piter
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/4641435644243916
dc.contributor.authorID.fl_str_mv 9235b5ad-e4b4-43ce-a2a6-be4b121ee4c3
contributor_str_mv Bolfarini, Claudemiro
Gargarella, Piter
dc.subject.por.fl_str_mv Ligas com memória de forma
Refusão superficial a laser
Transformação martensítica
Resfriamento rápido
topic Ligas com memória de forma
Refusão superficial a laser
Transformação martensítica
Resfriamento rápido
Shape memory alloys
Laser surface remelting
Martensitic transformation
Rapid cooling
ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
dc.subject.eng.fl_str_mv Shape memory alloys
Laser surface remelting
Martensitic transformation
Rapid cooling
dc.subject.cnpq.fl_str_mv ENGENHARIAS::ENGENHARIA DE MATERIAIS E METALURGICA
description Shape memory alloys (SMA) are alloys that undergo martensitic transformation due to an external solicitation (temperature, stress, strain or magnetic field) and are capable of recovering permanent deformation when heated above a critical temperature. The most used shape memory alloys are Ti-Ni- and Cu-based. Cu-based SMA have some advantages due to better thermal and electrical conductivity, lower production cost and are easier to process. The main disadvantage of Cu-based SMA is its low ductility. This property is improved by decreasing the grain size and by a reduction of microstructural heterogeneities. This can be achieved at the surface of structural components after LASER remelting, through which the surface of the material is remelted by a LASER beam and solidifies under extremely high cooling rates. In this context, the aim of the present work is to investigate the influence of LASER surface remelting in the microstructure, thermal stability and mechanical properties of Cu-11.8Al-3.2Ni-3Mn (wt. %) SMA plates obtained by suction casting. The samples were characterized by optical and scanning electron microscopy, energy dispersive X-ray spectroscopy, electron backscatter diffraction, X-ray computed tomography, X-ray diffraction, differential scanning calorimetry as well as by tensile and microhardness tests. The results show that small shifts in the transformation temperatures occur due to the LASER treatment. It was observed that only the monoclinic β’1 martensitic phase formed in the as cast and LASER treated samples. The LASER treatment provided an improvement in mechanical properties with an increase of up to 162 MPa in fracture stress, up to 2.2% in fracture strain and up to 21 HV in microhardness when compared with the as-cast sample. This makes the surface remelting treatment a promising method for improving the mechanical properties of Cu-based SMA.
publishDate 2017
dc.date.accessioned.fl_str_mv 2017-09-06T18:34:27Z
dc.date.available.fl_str_mv 2017-09-06T18:34:27Z
dc.date.issued.fl_str_mv 2017-02-10
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
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dc.identifier.citation.fl_str_mv SILVA, Murillo Romero da. Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso). 2017. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2017. Disponível em: https://repositorio.ufscar.br/handle/ufscar/9081.
dc.identifier.uri.fl_str_mv https://repositorio.ufscar.br/handle/ufscar/9081
identifier_str_mv SILVA, Murillo Romero da. Refusão superficial a laser da liga com memória de forma Cu-11,8Al-3,2Ni-3Mn (% Peso). 2017. Dissertação (Mestrado em Ciência e Engenharia de Materiais) – Universidade Federal de São Carlos, São Carlos, 2017. Disponível em: https://repositorio.ufscar.br/handle/ufscar/9081.
url https://repositorio.ufscar.br/handle/ufscar/9081
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dc.publisher.none.fl_str_mv Universidade Federal de São Carlos
Câmpus São Carlos
dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Ciência e Engenharia de Materiais - PPGCEM
dc.publisher.initials.fl_str_mv UFSCar
publisher.none.fl_str_mv Universidade Federal de São Carlos
Câmpus São Carlos
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