Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation
Autor(a) principal: | |
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Data de Publicação: | 2008 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Acta scientiarum. Technology (Online) |
Texto Completo: | http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2499 |
Resumo: | This research aims to work with photocatalysis as an alternative in the treatment of textile wastewater, because of the unsatisfactory degradation of some dyes by the conventional biological methods. Photocatalytic degradation tests were done in three natural textile effluents, under visible irradiation. The photocatalysts used were: TiO2 and Nb2O5, pure and combined with mechanical mixture (1:1) and impregnation (5% Nb2O5/TiO2). The characterization analysis (TPR, DRS, acidity, FTIR and textural analysis) indicated a synergic effect and differentiated interaction between the oxides and the formation of a new phase in the catalystic Nb2O5-TiO2. Decolorization and mineralization results showed that the color reduction is not directly related to the COD reduction and that the efficiency of the photocatalytic process depends on both, the effluent to be treated and the photocatalyst worked, showing that the use of Nb2O5 and visible irradiation on the photo degradation of the textile effluents is promising. |
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Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiationDegradação fotocatalítica de efluentes de indústria têxtil empregando TiO2 e Nb2O5, sob irradiação visívelfotodegradaçãoirradiação visívelTiO2Nb2O53.06.00.00-6 Engenharia QuímicaThis research aims to work with photocatalysis as an alternative in the treatment of textile wastewater, because of the unsatisfactory degradation of some dyes by the conventional biological methods. Photocatalytic degradation tests were done in three natural textile effluents, under visible irradiation. The photocatalysts used were: TiO2 and Nb2O5, pure and combined with mechanical mixture (1:1) and impregnation (5% Nb2O5/TiO2). The characterization analysis (TPR, DRS, acidity, FTIR and textural analysis) indicated a synergic effect and differentiated interaction between the oxides and the formation of a new phase in the catalystic Nb2O5-TiO2. Decolorization and mineralization results showed that the color reduction is not directly related to the COD reduction and that the efficiency of the photocatalytic process depends on both, the effluent to be treated and the photocatalyst worked, showing that the use of Nb2O5 and visible irradiation on the photo degradation of the textile effluents is promising.A aplicação de métodos biológicos convencionais de tratamento de efluentes têxteis está limitada pela degradação insatisfatória de alguns corantes. Assim, a fotocatálise heterogênea é uma alternativa no tratamento desse tipo de efluente. Foram realizados testes de degradação fotocatalítica em três efluentes naturais de indústria têxtil, sob irradiação visível, empregando os fotocatalisadores: TiO2, Nb2O5 puros e em combinação, através da mistura mecânica (1:1) e impregnação (5%Nb2O5/TiO2). As análises de caracterização realizadas (RTP, DRS, acidez, FTIR e análise textural) indicaram um efeito sinérgico e interação diferenciada entre os óxidos e a formação de uma nova fase no catalisador Nb2O5-TiO2. Os resultados de descoloração e mineralização mostraram que a redução de cor não está diretamente relacionada com a redução de DQO, e que a eficiência do processo fotocatalítico depende tanto do efluente a ser tratado quanto do fotocatalisador empregado, tornando-se promissor o uso do Nb2O5 e irradiação visível na fotodegradação de efluentes têxteis.Universidade Estadual De Maringá2008-04-22info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/249910.4025/actascitechnol.v24i0.2499Acta Scientiarum. Technology; Vol 24 (2002); 1681-1686Acta Scientiarum. Technology; v. 24 (2002); 1681-16861806-25631807-8664reponame:Acta scientiarum. Technology (Online)instname:Universidade Estadual de Maringá (UEM)instacron:UEMporhttp://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2499/1565Santana, Veronice SlusarskiMachado, Nádia Regina Camargo Fernandesinfo:eu-repo/semantics/openAccess2024-05-17T13:02:45Zoai:periodicos.uem.br/ojs:article/2499Revistahttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/indexPUBhttps://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/oai||actatech@uem.br1807-86641806-2563opendoar:2024-05-17T13:02:45Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM)false |
dc.title.none.fl_str_mv |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation Degradação fotocatalítica de efluentes de indústria têxtil empregando TiO2 e Nb2O5, sob irradiação visível |
title |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
spellingShingle |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation Santana, Veronice Slusarski fotodegradação irradiação visível TiO2 Nb2O5 3.06.00.00-6 Engenharia Química |
title_short |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
title_full |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
title_fullStr |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
title_full_unstemmed |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
title_sort |
Photocatalytic degradation of textile effluents using TiO2 and Nb2O5, under visible irradiation |
author |
Santana, Veronice Slusarski |
author_facet |
Santana, Veronice Slusarski Machado, Nádia Regina Camargo Fernandes |
author_role |
author |
author2 |
Machado, Nádia Regina Camargo Fernandes |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Santana, Veronice Slusarski Machado, Nádia Regina Camargo Fernandes |
dc.subject.por.fl_str_mv |
fotodegradação irradiação visível TiO2 Nb2O5 3.06.00.00-6 Engenharia Química |
topic |
fotodegradação irradiação visível TiO2 Nb2O5 3.06.00.00-6 Engenharia Química |
description |
This research aims to work with photocatalysis as an alternative in the treatment of textile wastewater, because of the unsatisfactory degradation of some dyes by the conventional biological methods. Photocatalytic degradation tests were done in three natural textile effluents, under visible irradiation. The photocatalysts used were: TiO2 and Nb2O5, pure and combined with mechanical mixture (1:1) and impregnation (5% Nb2O5/TiO2). The characterization analysis (TPR, DRS, acidity, FTIR and textural analysis) indicated a synergic effect and differentiated interaction between the oxides and the formation of a new phase in the catalystic Nb2O5-TiO2. Decolorization and mineralization results showed that the color reduction is not directly related to the COD reduction and that the efficiency of the photocatalytic process depends on both, the effluent to be treated and the photocatalyst worked, showing that the use of Nb2O5 and visible irradiation on the photo degradation of the textile effluents is promising. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-04-22 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2499 10.4025/actascitechnol.v24i0.2499 |
url |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2499 |
identifier_str_mv |
10.4025/actascitechnol.v24i0.2499 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
http://www.periodicos.uem.br/ojs/index.php/ActaSciTechnol/article/view/2499/1565 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
publisher.none.fl_str_mv |
Universidade Estadual De Maringá |
dc.source.none.fl_str_mv |
Acta Scientiarum. Technology; Vol 24 (2002); 1681-1686 Acta Scientiarum. Technology; v. 24 (2002); 1681-1686 1806-2563 1807-8664 reponame:Acta scientiarum. Technology (Online) instname:Universidade Estadual de Maringá (UEM) instacron:UEM |
instname_str |
Universidade Estadual de Maringá (UEM) |
instacron_str |
UEM |
institution |
UEM |
reponame_str |
Acta scientiarum. Technology (Online) |
collection |
Acta scientiarum. Technology (Online) |
repository.name.fl_str_mv |
Acta scientiarum. Technology (Online) - Universidade Estadual de Maringá (UEM) |
repository.mail.fl_str_mv |
||actatech@uem.br |
_version_ |
1799315332125425664 |