A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH

Detalhes bibliográficos
Autor(a) principal: Franco, Luís Fernando Mercier
Data de Publicação: 2013
Outros Autores: Silva, Silvana Mattedi e, Pessôa Filho, Pedro de Alcântara
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/13280
Resumo: Texto completo. Acesso restrito. p. 38–46
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spelling Franco, Luís Fernando MercierSilva, Silvana Mattedi ePessôa Filho, Pedro de AlcântaraFranco, Luís Fernando MercierSilva, Silvana Mattedi ePessôa Filho, Pedro de Alcântara2013-10-16T15:08:27Z2013-10-16T15:08:27Z20130378-3812http://www.repositorio.ufba.br/ri/handle/ri/13280v. 354Texto completo. Acesso restrito. p. 38–46A new model to describe the solubility of amino acids and β-lactam compounds as a function of pH is proposed. The description of the solid–liquid equilibrium entails simultaneous calculation of phase and chemical equilibria. The liquid-phase non-ideality was accounted for through an extended Pitzer model for polyelectrolyte solutions. A statistical thermodynamic interpretation of Pitzer's binary interaction parameters is also presented. The model was successfully applied to different systems containing amino-acids, as well as glycine and its oligopeptides and β-lactam compounds such as ampicillin and 6-aminopenicillanic acid.Submitted by Santiago Fabio (fabio.ssantiago@hotmail.com) on 2013-10-08T19:48:17Z No. of bitstreams: 1 4444444.pdf: 834807 bytes, checksum: 2d56fb75e82db89ca6db8518a6a18789 (MD5)Approved for entry into archive by LIVIA FREITAS(livia.freitas@ufba.br) on 2013-10-16T15:08:27Z (GMT) No. of bitstreams: 1 4444444.pdf: 834807 bytes, checksum: 2d56fb75e82db89ca6db8518a6a18789 (MD5)Made available in DSpace on 2013-10-16T15:08:27Z (GMT). No. of bitstreams: 1 4444444.pdf: 834807 bytes, checksum: 2d56fb75e82db89ca6db8518a6a18789 (MD5) Previous issue date: 2013SalvadorFluid Phase Equilibriahttp://www-sciencedirect-com.ez10.periodicos.capes.gov.br/science/article/pii/S0378381213002847reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBASolid–liquid equilibriumModelyngAmino acidsβ-Lactam compoundsA new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pHFluid Phase Equilibriainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleenginfo:eu-repo/semantics/openAccessORIGINAL4444444.pdf4444444.pdfapplication/pdf834807https://repositorio.ufba.br/bitstream/ri/13280/1/4444444.pdf2d56fb75e82db89ca6db8518a6a18789MD51LICENSElicense.txtlicense.txttext/plain1365https://repositorio.ufba.br/bitstream/ri/13280/2/license.txt5371a150bdc863f78dcf39281543bd86MD52TEXT4444444.pdf.txt4444444.pdf.txtExtracted texttext/plain39898https://repositorio.ufba.br/bitstream/ri/13280/3/4444444.pdf.txt584b534bed3bea44ae72c5920d798999MD53ri/132802022-07-05 14:03:12.682oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:12Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
dc.title.alternative.pt_BR.fl_str_mv Fluid Phase Equilibria
title A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
spellingShingle A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
Franco, Luís Fernando Mercier
Solid–liquid equilibrium
Modelyng
Amino acids
β-Lactam compounds
title_short A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
title_full A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
title_fullStr A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
title_full_unstemmed A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
title_sort A new approach for the thermodynamic modeling of the solubility of amino acids and β-lactam compounds as a function of pH
author Franco, Luís Fernando Mercier
author_facet Franco, Luís Fernando Mercier
Silva, Silvana Mattedi e
Pessôa Filho, Pedro de Alcântara
author_role author
author2 Silva, Silvana Mattedi e
Pessôa Filho, Pedro de Alcântara
author2_role author
author
dc.contributor.author.fl_str_mv Franco, Luís Fernando Mercier
Silva, Silvana Mattedi e
Pessôa Filho, Pedro de Alcântara
Franco, Luís Fernando Mercier
Silva, Silvana Mattedi e
Pessôa Filho, Pedro de Alcântara
dc.subject.por.fl_str_mv Solid–liquid equilibrium
Modelyng
Amino acids
β-Lactam compounds
topic Solid–liquid equilibrium
Modelyng
Amino acids
β-Lactam compounds
description Texto completo. Acesso restrito. p. 38–46
publishDate 2013
dc.date.accessioned.fl_str_mv 2013-10-16T15:08:27Z
dc.date.available.fl_str_mv 2013-10-16T15:08:27Z
dc.date.issued.fl_str_mv 2013
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/13280
dc.identifier.issn.none.fl_str_mv 0378-3812
dc.identifier.number.pt_BR.fl_str_mv v. 354
identifier_str_mv 0378-3812
v. 354
url http://www.repositorio.ufba.br/ri/handle/ri/13280
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Fluid Phase Equilibria
publisher.none.fl_str_mv Fluid Phase Equilibria
dc.source.pt_BR.fl_str_mv http://www-sciencedirect-com.ez10.periodicos.capes.gov.br/science/article/pii/S0378381213002847
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
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instacron_str UFBA
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reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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