Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand

Detalhes bibliográficos
Autor(a) principal: Ferreira, Kleber Queiroz
Data de Publicação: 2004
Outros Autores: Santos, Flavia Gouveia, Rocha, Zênis Novais da, Guaratini, Thais, Silva, Roberto Santana da, Tfouni, Elia
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/8315
Resumo: Texto completo: acesso restrito. p. 204-208
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spelling Ferreira, Kleber QueirozSantos, Flavia GouveiaRocha, Zênis Novais daGuaratini, ThaisSilva, Roberto Santana daTfouni, EliaFerreira, Kleber QueirozSantos, Flavia GouveiaRocha, Zênis Novais daGuaratini, ThaisSilva, Roberto Santana daTfouni, Elia2013-01-31T17:45:14Z20041387-7003http://www.repositorio.ufba.br/ri/handle/ri/8315v. 7, n. 2Texto completo: acesso restrito. p. 204-208The reaction of cis-dichloro(1,4,7,10-tetraazacyclododecane)ruthenium(III), cis-[RuIIICl2(cyclen)]þ, in acidic aqueous solution,in the presence of nitric oxide, results in cis-[RuIICl(imcyclen)(NOþ)]2þ. The cis nitrosyl complex is precipitated as a mixture of two conformational isomers, which are separated by high performance liquid chromatography. Electrochemical, infrared spectroeletrochemistry, and infrared, UV–Vis, 1H NMR, and EPR spectra results indicate the presence of coordinated nitric oxide in the form of nitrosonium (NOþ), and that the macrocyclic ligand (cyclen) is in the oxidized form in the complexes.Submitted by JURANDI DE SOUZA SILVA (jssufba@hotmail.com) on 2013-01-31T17:45:14Z No. of bitstreams: 1 1-s2.0-S1387700303003678-main.pdf: 204836 bytes, checksum: 28530aaa4e145b85255afbc86da3674f (MD5)Made available in DSpace on 2013-01-31T17:45:14Z (GMT). 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Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligandInorganic Chemistry Communicationsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINAL1-s2.0-S1387700303003678-main.pdf1-s2.0-S1387700303003678-main.pdfapplication/pdf204836https://repositorio.ufba.br/bitstream/ri/8315/1/1-s2.0-S1387700303003678-main.pdf28530aaa4e145b85255afbc86da3674fMD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/8315/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXT1-s2.0-S1387700303003678-main.pdf.txt1-s2.0-S1387700303003678-main.pdf.txtExtracted texttext/plain18601https://repositorio.ufba.br/bitstream/ri/8315/3/1-s2.0-S1387700303003678-main.pdf.txt8cb8546449585da5c8df6c6f4568a576MD53ri/83152022-07-05 14:03:03.14oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:03Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
dc.title.alternative.pt_BR.fl_str_mv Inorganic Chemistry Communications
title Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
spellingShingle Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
Ferreira, Kleber Queiroz
Nitrosyl ruthenium cyclen conformational isomers
Nitric oxide
Nitrosyl ruthenium imcyclen conformational isomers
title_short Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
title_full Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
title_fullStr Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
title_full_unstemmed Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
title_sort Conformational isomers of cis-chloro(nitrosyl)(1,4,7,10-tetraazacyclododecene)ruthenium(II), cis-[RuIICl(imcyclen)(NOþ)]2þ. Oxidation of the coordinated 1,4,7,10-tetraazacyclododecane (cyclen) ligand
author Ferreira, Kleber Queiroz
author_facet Ferreira, Kleber Queiroz
Santos, Flavia Gouveia
Rocha, Zênis Novais da
Guaratini, Thais
Silva, Roberto Santana da
Tfouni, Elia
author_role author
author2 Santos, Flavia Gouveia
Rocha, Zênis Novais da
Guaratini, Thais
Silva, Roberto Santana da
Tfouni, Elia
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Ferreira, Kleber Queiroz
Santos, Flavia Gouveia
Rocha, Zênis Novais da
Guaratini, Thais
Silva, Roberto Santana da
Tfouni, Elia
Ferreira, Kleber Queiroz
Santos, Flavia Gouveia
Rocha, Zênis Novais da
Guaratini, Thais
Silva, Roberto Santana da
Tfouni, Elia
dc.subject.por.fl_str_mv Nitrosyl ruthenium cyclen conformational isomers
Nitric oxide
Nitrosyl ruthenium imcyclen conformational isomers
topic Nitrosyl ruthenium cyclen conformational isomers
Nitric oxide
Nitrosyl ruthenium imcyclen conformational isomers
description Texto completo: acesso restrito. p. 204-208
publishDate 2004
dc.date.issued.fl_str_mv 2004
dc.date.accessioned.fl_str_mv 2013-01-31T17:45:14Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/8315
dc.identifier.issn.none.fl_str_mv 1387-7003
dc.identifier.number.pt_BR.fl_str_mv v. 7, n. 2
identifier_str_mv 1387-7003
v. 7, n. 2
url http://www.repositorio.ufba.br/ri/handle/ri/8315
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1016/j.inoche.2003.10.017
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
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reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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