Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide

Detalhes bibliográficos
Autor(a) principal: Vidal, Robson da Silva
Data de Publicação: 2012
Outros Autores: Doro, Fabio Gorzoni, Ferreira, Kleber Queiroz, Rocha, Zênis Novais da, Castellano, Eduardo Ernesto, Nikolaou, Sofia, Tfouni, Elia
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://repositorio.ufba.br/ri/handle/ri/16494
Resumo: Texto completo: acesso restrito. p. 93–96
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spelling Vidal, Robson da SilvaDoro, Fabio GorzoniFerreira, Kleber QueirozRocha, Zênis Novais daCastellano, Eduardo ErnestoNikolaou, SofiaTfouni, EliaVidal, Robson da SilvaDoro, Fabio GorzoniFerreira, Kleber QueirozRocha, Zênis Novais daCastellano, Eduardo ErnestoNikolaou, SofiaTfouni, Elia2014-11-03T12:03:01Z2012http://repositorio.ufba.br/ri/handle/ri/16494v. 15Texto completo: acesso restrito. p. 93–96The cis to trans isomerizations during the syntheses of trans-[Ru(NO)(OH)(cyclam)](PF6)2, from cis-[RuCl2(cyclam)]Cl, and [Ru(NO)Cl(cyclam)] (PF6)2, from cis-[RuCl2(dmso)4], are reported. The novel trans-[Ru(NO)(OH)(cyclam)](PF6)2 complex was characterized by X-ray crystallography and vibrational infrared and nuclear magnetic resonance spectroscopies. The Ru–N–O bond angle (176.75º) and ν(NO) (1835 cm− 1) suggest a nitrosonium character for this hydroxo complex. The crystal and molecular structure of trans-[Ru(NO)Cl(cyclam)](ClO4)2·2 H2O is also reported. Results presented here support the cis–trans isomerization observed for the first time with ruthenium cyclam complexes.Submitted by Edileide Reis (leyde-landy@hotmail.com) on 2014-11-03T12:03:00Z No. of bitstreams: 1 Robson da Silva Vidal.pdf: 307221 bytes, checksum: f478f01847edeae648cc245e5af97a81 (MD5)Made available in DSpace on 2014-11-03T12:03:01Z (GMT). No. of bitstreams: 1 Robson da Silva Vidal.pdf: 307221 bytes, checksum: f478f01847edeae648cc245e5af97a81 (MD5) Previous issue date: 2012http://dx.doi.org/ 10.1016/j.inoche.2011.09.046reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBARutheniumCyclamNitrosylNitric oxideCis–trans isomerizationNitriteCis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxideInorganic Chemistry Communicationsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01info:eu-repo/semantics/openAccessengLICENSElicense.txtlicense.txttext/plain1345https://repositorio.ufba.br/bitstream/ri/16494/2/license.txt0d4b811ef71182510d2015daa7c8a900MD52ORIGINALRobson da Silva Vidal.pdfRobson da Silva Vidal.pdfapplication/pdf307221https://repositorio.ufba.br/bitstream/ri/16494/1/Robson%20da%20Silva%20Vidal.pdff478f01847edeae648cc245e5af97a81MD51TEXTRobson da Silva Vidal.pdf.txtRobson da Silva Vidal.pdf.txtExtracted texttext/plain20693https://repositorio.ufba.br/bitstream/ri/16494/3/Robson%20da%20Silva%20Vidal.pdf.txtf2e03887be20e3a91dae3417c3c521f3MD53ri/164942022-07-05 14:03:35.547oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:03:35Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
dc.title.alternative.pt_BR.fl_str_mv Inorganic Chemistry Communications
title Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
spellingShingle Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
Vidal, Robson da Silva
Ruthenium
Cyclam
Nitrosyl
Nitric oxide
Cis–trans isomerization
Nitrite
title_short Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
title_full Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
title_fullStr Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
title_full_unstemmed Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
title_sort Cis–trans isomerization in the syntheses of ruthenium cyclam complexes with nitric oxide
author Vidal, Robson da Silva
author_facet Vidal, Robson da Silva
Doro, Fabio Gorzoni
Ferreira, Kleber Queiroz
Rocha, Zênis Novais da
Castellano, Eduardo Ernesto
Nikolaou, Sofia
Tfouni, Elia
author_role author
author2 Doro, Fabio Gorzoni
Ferreira, Kleber Queiroz
Rocha, Zênis Novais da
Castellano, Eduardo Ernesto
Nikolaou, Sofia
Tfouni, Elia
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Vidal, Robson da Silva
Doro, Fabio Gorzoni
Ferreira, Kleber Queiroz
Rocha, Zênis Novais da
Castellano, Eduardo Ernesto
Nikolaou, Sofia
Tfouni, Elia
Vidal, Robson da Silva
Doro, Fabio Gorzoni
Ferreira, Kleber Queiroz
Rocha, Zênis Novais da
Castellano, Eduardo Ernesto
Nikolaou, Sofia
Tfouni, Elia
dc.subject.por.fl_str_mv Ruthenium
Cyclam
Nitrosyl
Nitric oxide
Cis–trans isomerization
Nitrite
topic Ruthenium
Cyclam
Nitrosyl
Nitric oxide
Cis–trans isomerization
Nitrite
description Texto completo: acesso restrito. p. 93–96
publishDate 2012
dc.date.issued.fl_str_mv 2012
dc.date.accessioned.fl_str_mv 2014-11-03T12:03:01Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://repositorio.ufba.br/ri/handle/ri/16494
dc.identifier.number.pt_BR.fl_str_mv v. 15
url http://repositorio.ufba.br/ri/handle/ri/16494
identifier_str_mv v. 15
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv http://dx.doi.org/ 10.1016/j.inoche.2011.09.046
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
instname:Universidade Federal da Bahia (UFBA)
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