Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
Autor(a) principal: | |
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Data de Publicação: | 2000 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFBA |
Texto Completo: | http://www.repositorio.ufba.br/ri/handle/ri/7857 |
Resumo: | Texto completo: acesso restrito. p. 1027–1033 |
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Teixeira, Leonardo Sena GomesRocha, Fábio Rodrigo PiovezaniKorn, MauroReis, Boaventura F.Ferreira, Sergio Luis CostaCosta, Antonio Celso SpinolaTeixeira, Leonardo Sena GomesRocha, Fábio Rodrigo PiovezaniKorn, MauroReis, Boaventura F.Ferreira, Sergio Luis CostaCosta, Antonio Celso Spinola2013-01-15T11:08:19Z20000039-9140http://www.repositorio.ufba.br/ri/handle/ri/7857v. 51, n. 5Texto completo: acesso restrito. p. 1027–1033Flow-injection solid-phase spectrophotometry is applied for sequential determination of nickel and zinc, exploiting their different sorption rates on 1-(2-thiazolylazo)-2-naphthol (TAN) immobilized on C18-bonded silica. The Zn(II) sorption rate on the solid support is constant for flow rates ranging from 0.70 to 2.2 ml min−1, but for Ni(II) the sorption rate decreases with increasing flow rate. A flow system was designed to perform sequential measurements at two different flow rates (0.85 and 1.9 ml min−1). The absorbance was measured at 595 nm, where both TAN-immobilized complexes showed maximum absorption. The coefficients of variation were estimated (n=10) as 1.1 and 1.7% (at 1.9 ml min−1) and 1.2 and 2.1% (at 0.85 ml min−1) for zinc and nickel, respectively. This strategy was applied to determine zinc and nickel in copper-based alloys and the results agreed with certified values at the 95% confidence level. The sample throughput was estimated as 36 h−1.Submitted by Suelen Reis (suelen_suzane@hotmail.com) on 2013-01-15T11:08:19Z No. of bitstreams: 1 Teixeira.pdf: 112406 bytes, checksum: cb7027d7ce3cd5c1dd0aaf14d4f55cd6 (MD5)Made available in DSpace on 2013-01-15T11:08:19Z (GMT). No. of bitstreams: 1 Teixeira.pdf: 112406 bytes, checksum: cb7027d7ce3cd5c1dd0aaf14d4f55cd6 (MD5) Previous issue date: 2000http://dx.doi.org/10.1016/S0039-9140(00)00288-5reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBASolid-phase spectrophotometrySorption ratesFlow-injection analysisNickelZincCopper-based alloysNickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption ratesTalantainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINALTeixeira.pdfTeixeira.pdfapplication/pdf112406https://repositorio.ufba.br/bitstream/ri/7857/1/Teixeira.pdfcb7027d7ce3cd5c1dd0aaf14d4f55cd6MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/7857/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXTTeixeira.pdf.txtTeixeira.pdf.txtExtracted texttext/plain18804https://repositorio.ufba.br/bitstream/ri/7857/3/Teixeira.pdf.txt745dde18978e0c82cbf498f22cebf05eMD53ri/78572022-07-05 14:02:50.81oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:02:50Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false |
dc.title.pt_BR.fl_str_mv |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
dc.title.alternative.pt_BR.fl_str_mv |
Talanta |
title |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
spellingShingle |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates Teixeira, Leonardo Sena Gomes Solid-phase spectrophotometry Sorption rates Flow-injection analysis Nickel Zinc Copper-based alloys |
title_short |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
title_full |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
title_fullStr |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
title_full_unstemmed |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
title_sort |
Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates |
author |
Teixeira, Leonardo Sena Gomes |
author_facet |
Teixeira, Leonardo Sena Gomes Rocha, Fábio Rodrigo Piovezani Korn, Mauro Reis, Boaventura F. Ferreira, Sergio Luis Costa Costa, Antonio Celso Spinola |
author_role |
author |
author2 |
Rocha, Fábio Rodrigo Piovezani Korn, Mauro Reis, Boaventura F. Ferreira, Sergio Luis Costa Costa, Antonio Celso Spinola |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Teixeira, Leonardo Sena Gomes Rocha, Fábio Rodrigo Piovezani Korn, Mauro Reis, Boaventura F. Ferreira, Sergio Luis Costa Costa, Antonio Celso Spinola Teixeira, Leonardo Sena Gomes Rocha, Fábio Rodrigo Piovezani Korn, Mauro Reis, Boaventura F. Ferreira, Sergio Luis Costa Costa, Antonio Celso Spinola |
dc.subject.por.fl_str_mv |
Solid-phase spectrophotometry Sorption rates Flow-injection analysis Nickel Zinc Copper-based alloys |
topic |
Solid-phase spectrophotometry Sorption rates Flow-injection analysis Nickel Zinc Copper-based alloys |
description |
Texto completo: acesso restrito. p. 1027–1033 |
publishDate |
2000 |
dc.date.issued.fl_str_mv |
2000 |
dc.date.accessioned.fl_str_mv |
2013-01-15T11:08:19Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://www.repositorio.ufba.br/ri/handle/ri/7857 |
dc.identifier.issn.none.fl_str_mv |
0039-9140 |
dc.identifier.number.pt_BR.fl_str_mv |
v. 51, n. 5 |
identifier_str_mv |
0039-9140 v. 51, n. 5 |
url |
http://www.repositorio.ufba.br/ri/handle/ri/7857 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.pt_BR.fl_str_mv |
http://dx.doi.org/10.1016/S0039-9140(00)00288-5 |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UFBA instname:Universidade Federal da Bahia (UFBA) instacron:UFBA |
instname_str |
Universidade Federal da Bahia (UFBA) |
instacron_str |
UFBA |
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UFBA |
reponame_str |
Repositório Institucional da UFBA |
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Repositório Institucional da UFBA |
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