Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates

Detalhes bibliográficos
Autor(a) principal: Teixeira, Leonardo Sena Gomes
Data de Publicação: 2000
Outros Autores: Rocha, Fábio Rodrigo Piovezani, Korn, Mauro, Reis, Boaventura F., Ferreira, Sergio Luis Costa, Costa, Antonio Celso Spinola
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFBA
Texto Completo: http://www.repositorio.ufba.br/ri/handle/ri/7857
Resumo: Texto completo: acesso restrito. p. 1027–1033
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spelling Teixeira, Leonardo Sena GomesRocha, Fábio Rodrigo PiovezaniKorn, MauroReis, Boaventura F.Ferreira, Sergio Luis CostaCosta, Antonio Celso SpinolaTeixeira, Leonardo Sena GomesRocha, Fábio Rodrigo PiovezaniKorn, MauroReis, Boaventura F.Ferreira, Sergio Luis CostaCosta, Antonio Celso Spinola2013-01-15T11:08:19Z20000039-9140http://www.repositorio.ufba.br/ri/handle/ri/7857v. 51, n. 5Texto completo: acesso restrito. p. 1027–1033Flow-injection solid-phase spectrophotometry is applied for sequential determination of nickel and zinc, exploiting their different sorption rates on 1-(2-thiazolylazo)-2-naphthol (TAN) immobilized on C18-bonded silica. The Zn(II) sorption rate on the solid support is constant for flow rates ranging from 0.70 to 2.2 ml min−1, but for Ni(II) the sorption rate decreases with increasing flow rate. A flow system was designed to perform sequential measurements at two different flow rates (0.85 and 1.9 ml min−1). The absorbance was measured at 595 nm, where both TAN-immobilized complexes showed maximum absorption. The coefficients of variation were estimated (n=10) as 1.1 and 1.7% (at 1.9 ml min−1) and 1.2 and 2.1% (at 0.85 ml min−1) for zinc and nickel, respectively. This strategy was applied to determine zinc and nickel in copper-based alloys and the results agreed with certified values at the 95% confidence level. The sample throughput was estimated as 36 h−1.Submitted by Suelen Reis (suelen_suzane@hotmail.com) on 2013-01-15T11:08:19Z No. of bitstreams: 1 Teixeira.pdf: 112406 bytes, checksum: cb7027d7ce3cd5c1dd0aaf14d4f55cd6 (MD5)Made available in DSpace on 2013-01-15T11:08:19Z (GMT). No. of bitstreams: 1 Teixeira.pdf: 112406 bytes, checksum: cb7027d7ce3cd5c1dd0aaf14d4f55cd6 (MD5) Previous issue date: 2000http://dx.doi.org/10.1016/S0039-9140(00)00288-5reponame:Repositório Institucional da UFBAinstname:Universidade Federal da Bahia (UFBA)instacron:UFBASolid-phase spectrophotometrySorption ratesFlow-injection analysisNickelZincCopper-based alloysNickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption ratesTalantainfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article10000-01-01enginfo:eu-repo/semantics/openAccessORIGINALTeixeira.pdfTeixeira.pdfapplication/pdf112406https://repositorio.ufba.br/bitstream/ri/7857/1/Teixeira.pdfcb7027d7ce3cd5c1dd0aaf14d4f55cd6MD51LICENSElicense.txtlicense.txttext/plain1762https://repositorio.ufba.br/bitstream/ri/7857/2/license.txt1b89a9a0548218172d7c829f87a0eab9MD52TEXTTeixeira.pdf.txtTeixeira.pdf.txtExtracted texttext/plain18804https://repositorio.ufba.br/bitstream/ri/7857/3/Teixeira.pdf.txt745dde18978e0c82cbf498f22cebf05eMD53ri/78572022-07-05 14:02:50.81oai:repositorio.ufba.br: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Repositório InstitucionalPUBhttp://192.188.11.11:8080/oai/requestopendoar:19322022-07-05T17:02:50Repositório Institucional da UFBA - Universidade Federal da Bahia (UFBA)false
dc.title.pt_BR.fl_str_mv Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
dc.title.alternative.pt_BR.fl_str_mv Talanta
title Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
spellingShingle Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
Teixeira, Leonardo Sena Gomes
Solid-phase spectrophotometry
Sorption rates
Flow-injection analysis
Nickel
Zinc
Copper-based alloys
title_short Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
title_full Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
title_fullStr Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
title_full_unstemmed Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
title_sort Nickel and zinc determination by flow-injection solid-phase spectrophotometry exploiting different sorption rates
author Teixeira, Leonardo Sena Gomes
author_facet Teixeira, Leonardo Sena Gomes
Rocha, Fábio Rodrigo Piovezani
Korn, Mauro
Reis, Boaventura F.
Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
author_role author
author2 Rocha, Fábio Rodrigo Piovezani
Korn, Mauro
Reis, Boaventura F.
Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Teixeira, Leonardo Sena Gomes
Rocha, Fábio Rodrigo Piovezani
Korn, Mauro
Reis, Boaventura F.
Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
Teixeira, Leonardo Sena Gomes
Rocha, Fábio Rodrigo Piovezani
Korn, Mauro
Reis, Boaventura F.
Ferreira, Sergio Luis Costa
Costa, Antonio Celso Spinola
dc.subject.por.fl_str_mv Solid-phase spectrophotometry
Sorption rates
Flow-injection analysis
Nickel
Zinc
Copper-based alloys
topic Solid-phase spectrophotometry
Sorption rates
Flow-injection analysis
Nickel
Zinc
Copper-based alloys
description Texto completo: acesso restrito. p. 1027–1033
publishDate 2000
dc.date.issued.fl_str_mv 2000
dc.date.accessioned.fl_str_mv 2013-01-15T11:08:19Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://www.repositorio.ufba.br/ri/handle/ri/7857
dc.identifier.issn.none.fl_str_mv 0039-9140
dc.identifier.number.pt_BR.fl_str_mv v. 51, n. 5
identifier_str_mv 0039-9140
v. 51, n. 5
url http://www.repositorio.ufba.br/ri/handle/ri/7857
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.pt_BR.fl_str_mv http://dx.doi.org/10.1016/S0039-9140(00)00288-5
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFBA
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reponame_str Repositório Institucional da UFBA
collection Repositório Institucional da UFBA
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