Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Biblioteca Digital de Teses e Dissertações da UFC |
Texto Completo: | http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116 |
Resumo: | Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions. |
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Biblioteca Digital de Teses e Dissertações da UFC |
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info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisFiltration combustion applied to biogas containing high concentration of Sulfide HydrogenCombustÃo de filtraÃÃo aplicada ao biogÃs com elevada concentraÃÃo de Sulfeto de HidrogÃnio2015-05-29William MagalhÃes Barcellos49442910787http://lattes.cnpq.br/3063061710566545Francisco Nivaldo Aguiar Freire39106705391http://lattes.cnpq.br/1550246266734380JoÃo Batista Furlan Duarte55844405072http://lattes.cnpq.br/2139814271237417 01247203310http://lattes.cnpq.br/6640848006487210Rafael MagalhÃes SiqueiraUniversidade Federal do CearÃPrograma de PÃs-GraduaÃÃo em Engenharia MecÃnicaUFCBR CombustÃo em meios porosos Sulfeto de hidrogÃnio Gases - EmissÃo Filtration combustion Biogas Hydrogen sulfide EmissionsENGENHARIA MECANICAUsing Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions.O uso do gÃs natural ou biogÃs in natura, contendo elevadas concentraÃÃes de sulfeto de hidrogÃnio (H2S), para aplicaÃÃo em processos de combustÃo convencionais, pode acarretar em diversos danos aos equipamentos, devido esse gÃs ser bastante corrosivo e, tambÃm, por formar Ãcido sulfÃrico ao reagir com a Ãgua resultante da combustÃo. AlÃm do que, a utilizaÃÃo dos citados combustÃveis sem um tratamento prÃvio pode ocasionar instabilidade da reaÃÃo, inclusive sob risco de apagamento da chama, o que implica na eficiÃncia e nos nÃveis de emissÃo de monÃxido de carbono (CO) e Ãxido de nitrogÃnio (NOx). Portanto, o presente trabalho refere-se ao estudo experimental da aplicaÃÃo de um processo de combustÃo nÃo-convencional, a combustÃo em meios porosos, tambÃm conhecida como combustÃo de filtraÃÃo (CF), para lidar com esses combustÃveis especiais, impossÃvel para os sistemas tÃrmicos conhecidos. O equipamento utilizado nos experimentos à um queimador, preenchido totalmente por esferas de alumina (Al2O3), em que esse meio poroso inerte envolve inclusive os trocadores de calor localizados nas extremidades do queimador. A influÃncia da razÃo de equivalÃncia, velocidade de escoamento e composiÃÃo do gÃs sob o processo à analisada experimentalmente. Os resultados sugerem que, mesmo utilizando uma mistura ar-combustÃvel ultra pobre, a reaÃÃo pode se manter estÃvel, apresentando boa conversÃo do H2S e baixas emissÃes de NOx.FundaÃÃo Cearense de Apoio ao Desenvolvimento Cientifico e TecnolÃgicohttp://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116application/pdfinfo:eu-repo/semantics/openAccessporreponame:Biblioteca Digital de Teses e Dissertações da UFCinstname:Universidade Federal do Cearáinstacron:UFC2019-01-21T11:28:11Zmail@mail.com - |
dc.title.en.fl_str_mv |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
dc.title.alternative.pt.fl_str_mv |
CombustÃo de filtraÃÃo aplicada ao biogÃs com elevada concentraÃÃo de Sulfeto de HidrogÃnio |
title |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
spellingShingle |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen Rafael MagalhÃes Siqueira CombustÃo em meios porosos Sulfeto de hidrogÃnio Gases - EmissÃo Filtration combustion Biogas Hydrogen sulfide Emissions ENGENHARIA MECANICA |
title_short |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
title_full |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
title_fullStr |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
title_full_unstemmed |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
title_sort |
Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen |
author |
Rafael MagalhÃes Siqueira |
author_facet |
Rafael MagalhÃes Siqueira |
author_role |
author |
dc.contributor.advisor1.fl_str_mv |
William MagalhÃes Barcellos |
dc.contributor.advisor1ID.fl_str_mv |
49442910787 |
dc.contributor.advisor1Lattes.fl_str_mv |
http://lattes.cnpq.br/3063061710566545 |
dc.contributor.referee1.fl_str_mv |
Francisco Nivaldo Aguiar Freire |
dc.contributor.referee1ID.fl_str_mv |
39106705391 |
dc.contributor.referee1Lattes.fl_str_mv |
http://lattes.cnpq.br/1550246266734380 |
dc.contributor.referee2.fl_str_mv |
JoÃo Batista Furlan Duarte |
dc.contributor.referee2ID.fl_str_mv |
55844405072 |
dc.contributor.referee2Lattes.fl_str_mv |
http://lattes.cnpq.br/2139814271237417 |
dc.contributor.authorID.fl_str_mv |
01247203310 |
dc.contributor.authorLattes.fl_str_mv |
http://lattes.cnpq.br/6640848006487210 |
dc.contributor.author.fl_str_mv |
Rafael MagalhÃes Siqueira |
contributor_str_mv |
William MagalhÃes Barcellos Francisco Nivaldo Aguiar Freire JoÃo Batista Furlan Duarte |
dc.subject.por.fl_str_mv |
CombustÃo em meios porosos Sulfeto de hidrogÃnio Gases - EmissÃo |
topic |
CombustÃo em meios porosos Sulfeto de hidrogÃnio Gases - EmissÃo Filtration combustion Biogas Hydrogen sulfide Emissions ENGENHARIA MECANICA |
dc.subject.eng.fl_str_mv |
Filtration combustion Biogas Hydrogen sulfide Emissions |
dc.subject.cnpq.fl_str_mv |
ENGENHARIA MECANICA |
dc.description.sponsorship.fl_txt_mv |
FundaÃÃo Cearense de Apoio ao Desenvolvimento Cientifico e TecnolÃgico |
dc.description.abstract.por.fl_txt_mv |
Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions. O uso do gÃs natural ou biogÃs in natura, contendo elevadas concentraÃÃes de sulfeto de hidrogÃnio (H2S), para aplicaÃÃo em processos de combustÃo convencionais, pode acarretar em diversos danos aos equipamentos, devido esse gÃs ser bastante corrosivo e, tambÃm, por formar Ãcido sulfÃrico ao reagir com a Ãgua resultante da combustÃo. AlÃm do que, a utilizaÃÃo dos citados combustÃveis sem um tratamento prÃvio pode ocasionar instabilidade da reaÃÃo, inclusive sob risco de apagamento da chama, o que implica na eficiÃncia e nos nÃveis de emissÃo de monÃxido de carbono (CO) e Ãxido de nitrogÃnio (NOx). Portanto, o presente trabalho refere-se ao estudo experimental da aplicaÃÃo de um processo de combustÃo nÃo-convencional, a combustÃo em meios porosos, tambÃm conhecida como combustÃo de filtraÃÃo (CF), para lidar com esses combustÃveis especiais, impossÃvel para os sistemas tÃrmicos conhecidos. O equipamento utilizado nos experimentos à um queimador, preenchido totalmente por esferas de alumina (Al2O3), em que esse meio poroso inerte envolve inclusive os trocadores de calor localizados nas extremidades do queimador. A influÃncia da razÃo de equivalÃncia, velocidade de escoamento e composiÃÃo do gÃs sob o processo à analisada experimentalmente. Os resultados sugerem que, mesmo utilizando uma mistura ar-combustÃvel ultra pobre, a reaÃÃo pode se manter estÃvel, apresentando boa conversÃo do H2S e baixas emissÃes de NOx. |
description |
Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions. |
publishDate |
2015 |
dc.date.issued.fl_str_mv |
2015-05-29 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
status_str |
publishedVersion |
format |
masterThesis |
dc.identifier.uri.fl_str_mv |
http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116 |
url |
http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal do Cearà |
dc.publisher.program.fl_str_mv |
Programa de PÃs-GraduaÃÃo em Engenharia MecÃnica |
dc.publisher.initials.fl_str_mv |
UFC |
dc.publisher.country.fl_str_mv |
BR |
publisher.none.fl_str_mv |
Universidade Federal do Cearà |
dc.source.none.fl_str_mv |
reponame:Biblioteca Digital de Teses e Dissertações da UFC instname:Universidade Federal do Ceará instacron:UFC |
reponame_str |
Biblioteca Digital de Teses e Dissertações da UFC |
collection |
Biblioteca Digital de Teses e Dissertações da UFC |
instname_str |
Universidade Federal do Ceará |
instacron_str |
UFC |
institution |
UFC |
repository.name.fl_str_mv |
-
|
repository.mail.fl_str_mv |
mail@mail.com |
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1643295207976861696 |