Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen

Detalhes bibliográficos
Autor(a) principal: Rafael MagalhÃes Siqueira
Data de Publicação: 2015
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFC
Texto Completo: http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116
Resumo: Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions.
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spelling info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisFiltration combustion applied to biogas containing high concentration of Sulfide HydrogenCombustÃo de filtraÃÃo aplicada ao biogÃs com elevada concentraÃÃo de Sulfeto de HidrogÃnio2015-05-29William MagalhÃes Barcellos49442910787http://lattes.cnpq.br/3063061710566545Francisco Nivaldo Aguiar Freire39106705391http://lattes.cnpq.br/1550246266734380JoÃo Batista Furlan Duarte55844405072http://lattes.cnpq.br/2139814271237417 01247203310http://lattes.cnpq.br/6640848006487210Rafael MagalhÃes SiqueiraUniversidade Federal do CearÃPrograma de PÃs-GraduaÃÃo em Engenharia MecÃnicaUFCBR CombustÃo em meios porosos Sulfeto de hidrogÃnio Gases - EmissÃo Filtration combustion Biogas Hydrogen sulfide EmissionsENGENHARIA MECANICAUsing Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions.O uso do gÃs natural ou biogÃs in natura, contendo elevadas concentraÃÃes de sulfeto de hidrogÃnio (H2S), para aplicaÃÃo em processos de combustÃo convencionais, pode acarretar em diversos danos aos equipamentos, devido esse gÃs ser bastante corrosivo e, tambÃm, por formar Ãcido sulfÃrico ao reagir com a Ãgua resultante da combustÃo. AlÃm do que, a utilizaÃÃo dos citados combustÃveis sem um tratamento prÃvio pode ocasionar instabilidade da reaÃÃo, inclusive sob risco de apagamento da chama, o que implica na eficiÃncia e nos nÃveis de emissÃo de monÃxido de carbono (CO) e Ãxido de nitrogÃnio (NOx). Portanto, o presente trabalho refere-se ao estudo experimental da aplicaÃÃo de um processo de combustÃo nÃo-convencional, a combustÃo em meios porosos, tambÃm conhecida como combustÃo de filtraÃÃo (CF), para lidar com esses combustÃveis especiais, impossÃvel para os sistemas tÃrmicos conhecidos. O equipamento utilizado nos experimentos à um queimador, preenchido totalmente por esferas de alumina (Al2O3), em que esse meio poroso inerte envolve inclusive os trocadores de calor localizados nas extremidades do queimador. A influÃncia da razÃo de equivalÃncia, velocidade de escoamento e composiÃÃo do gÃs sob o processo à analisada experimentalmente. Os resultados sugerem que, mesmo utilizando uma mistura ar-combustÃvel ultra pobre, a reaÃÃo pode se manter estÃvel, apresentando boa conversÃo do H2S e baixas emissÃes de NOx.FundaÃÃo Cearense de Apoio ao Desenvolvimento Cientifico e TecnolÃgicohttp://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=15116application/pdfinfo:eu-repo/semantics/openAccessporreponame:Biblioteca Digital de Teses e Dissertações da UFCinstname:Universidade Federal do Cearáinstacron:UFC2019-01-21T11:28:11Zmail@mail.com -
dc.title.en.fl_str_mv Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
dc.title.alternative.pt.fl_str_mv CombustÃo de filtraÃÃo aplicada ao biogÃs com elevada concentraÃÃo de Sulfeto de HidrogÃnio
title Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
spellingShingle Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
Rafael MagalhÃes Siqueira
CombustÃo em meios porosos
Sulfeto de hidrogÃnio
Gases - EmissÃo
Filtration combustion
Biogas
Hydrogen sulfide
Emissions
ENGENHARIA MECANICA
title_short Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
title_full Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
title_fullStr Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
title_full_unstemmed Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
title_sort Filtration combustion applied to biogas containing high concentration of Sulfide Hydrogen
author Rafael MagalhÃes Siqueira
author_facet Rafael MagalhÃes Siqueira
author_role author
dc.contributor.advisor1.fl_str_mv William MagalhÃes Barcellos
dc.contributor.advisor1ID.fl_str_mv 49442910787
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/3063061710566545
dc.contributor.referee1.fl_str_mv Francisco Nivaldo Aguiar Freire
dc.contributor.referee1ID.fl_str_mv 39106705391
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/1550246266734380
dc.contributor.referee2.fl_str_mv JoÃo Batista Furlan Duarte
dc.contributor.referee2ID.fl_str_mv 55844405072
dc.contributor.referee2Lattes.fl_str_mv http://lattes.cnpq.br/2139814271237417
dc.contributor.authorID.fl_str_mv 01247203310
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/6640848006487210
dc.contributor.author.fl_str_mv Rafael MagalhÃes Siqueira
contributor_str_mv William MagalhÃes Barcellos
Francisco Nivaldo Aguiar Freire
JoÃo Batista Furlan Duarte
dc.subject.por.fl_str_mv CombustÃo em meios porosos
Sulfeto de hidrogÃnio
Gases - EmissÃo
topic CombustÃo em meios porosos
Sulfeto de hidrogÃnio
Gases - EmissÃo
Filtration combustion
Biogas
Hydrogen sulfide
Emissions
ENGENHARIA MECANICA
dc.subject.eng.fl_str_mv Filtration combustion
Biogas
Hydrogen sulfide
Emissions
dc.subject.cnpq.fl_str_mv ENGENHARIA MECANICA
dc.description.sponsorship.fl_txt_mv FundaÃÃo Cearense de Apoio ao Desenvolvimento Cientifico e TecnolÃgico
dc.description.abstract.por.fl_txt_mv Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions.
O uso do gÃs natural ou biogÃs in natura, contendo elevadas concentraÃÃes de sulfeto de hidrogÃnio (H2S), para aplicaÃÃo em processos de combustÃo convencionais, pode acarretar em diversos danos aos equipamentos, devido esse gÃs ser bastante corrosivo e, tambÃm, por formar Ãcido sulfÃrico ao reagir com a Ãgua resultante da combustÃo. AlÃm do que, a utilizaÃÃo dos citados combustÃveis sem um tratamento prÃvio pode ocasionar instabilidade da reaÃÃo, inclusive sob risco de apagamento da chama, o que implica na eficiÃncia e nos nÃveis de emissÃo de monÃxido de carbono (CO) e Ãxido de nitrogÃnio (NOx). Portanto, o presente trabalho refere-se ao estudo experimental da aplicaÃÃo de um processo de combustÃo nÃo-convencional, a combustÃo em meios porosos, tambÃm conhecida como combustÃo de filtraÃÃo (CF), para lidar com esses combustÃveis especiais, impossÃvel para os sistemas tÃrmicos conhecidos. O equipamento utilizado nos experimentos à um queimador, preenchido totalmente por esferas de alumina (Al2O3), em que esse meio poroso inerte envolve inclusive os trocadores de calor localizados nas extremidades do queimador. A influÃncia da razÃo de equivalÃncia, velocidade de escoamento e composiÃÃo do gÃs sob o processo à analisada experimentalmente. Os resultados sugerem que, mesmo utilizando uma mistura ar-combustÃvel ultra pobre, a reaÃÃo pode se manter estÃvel, apresentando boa conversÃo do H2S e baixas emissÃes de NOx.
description Using Natural Gas or Biogas in natura, containing high hydrogen (H2S) sulfide concentrations, to apply in conventional combustion processes, can cause several damages to equipment. This is due to the fact that it is a very corrosive gas that can form a sulfur acid reaction with water from combustion. In addition, using these fuels without pretreatment can cause instability on reaction, even under flame risk deletion, which implies in efficiency and oxide carbon (CO) and nitrogen oxide (NOx) emission levels. Therefore, this study refers to the experimental method of non-conventional combustion process application, the porous media combustion, also known as filtration combustion, to deal with these special fuels, impossible to use in known thermal systems. A burner all filled with alumina spheres (Al2O3) was the equipment used for these experiments. This inert porous media fills even the heat exchangers located on the ends of the burner. The equivalent ratio, flow velocity and gas composition influence in the process, are experimental analyzed. Preliminary results have suggested that when using an ultra-lean air-fuel mixture, the reaction can remain steady with a good H2S conversion and low CO and NOx emissions.
publishDate 2015
dc.date.issued.fl_str_mv 2015-05-29
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
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status_str publishedVersion
format masterThesis
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dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.publisher.program.fl_str_mv Programa de PÃs-GraduaÃÃo em Engenharia MecÃnica
dc.publisher.initials.fl_str_mv UFC
dc.publisher.country.fl_str_mv BR
publisher.none.fl_str_mv Universidade Federal do CearÃ
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações da UFC
instname:Universidade Federal do Ceará
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