Biodegradable films of galactomannan: use in conservation fortress fruit.

Detalhes bibliográficos
Autor(a) principal: Ed Carlos Morais dos Santos
Data de Publicação: 2012
Tipo de documento: Tese
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFC
Texto Completo: http://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=8319
Resumo: The fruit growers are adapting to changes in consumption patterns and increased demand from consumers about the quality of fresh fruits available. The market need to meet the demand from consumption centers, which are increasingly distant from the centers of production, makes it necessary to prolong the shelf life of fruits without these attributes lose their health protection as a result of natural aging process. Research aimed at developing new technologies for reducing post harvest losses are fundamental to the national economy, and minimize losses, increase competitiveness and seek to meet the qualities of an increasingly demanding mark et. Biodegradable films and edible coatings have received attention in recent years, mainly due to its potential application for preserving fruit. The objective of this work was to study the biodegradable films prepared from galactomannan of Caesalpinia pu lcherrima and glycerol aiming its use in the creation of packaging to increase shelf life of fruits. Initially we analyzed the effect of preparation conditions of films on the properties of barriers and found that both temperature and drying time cause a p ositive effect on the permeability to water vapor of these films, being chosen, so the temperature of 50 Â C and 12 hours as standard methodology for preparing the films. Then , we studied the influence of concentrations of galactomannan and glycerol on phy sical - chemical properties and found that the variables were statistically significant in all properties, highlighting that the glycerol had a positive influence on all tests, increasing concentration of glycerol provides increased studied property , probabl y due to its hygroscopic character. The increase in the concentration of galactomannan causes a decrease in absorption, moisture content and oxygen permeability and carbon dioxide. It was observed that temperature and relative humidity have a major influen ce on the barrier properties of the films, since the increase of these variables causes an increase in permeability to water vapor and oxygen. To understand how films behave in the face of mechanical stress, we studied the influence of the galactomannan an d glycerol on the mechanical properties and found that the thickness of the films increases with these variables and that the polysaccharide is responsible for increasing the tensile strength , puncture and tear strength of the films and the plasticizer has a positive influence on elongation and tear strength. After the knowledge of all the physico - chemical, mechanical and barrier properties and having the formulations which afforded us the desired properties optimized, we chose the formulation of GalGl y (0 . 4:1 . 0) (%, m: m) to test the performance of films for packaging to maintain the shelf life of sliced apples. It was observed that the apples they received the protection of the films showed the lowest respiration rate, weight loss 10% lower and lower level s of browning, brightness and color variation when compared with those who were not covered under the tested conditions. Thus, the films studied in this work have great potential for application in the packaging sector and contribute to increase the shelf life of fruits
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spelling info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisBiodegradable films of galactomannan: use in conservation fortress fruit.Filmes biodegradÃveis de galactomanana: uso na conservaÃÃo de frutos fortaleza.2012-02-10Renato de Azevedo Moreira00114715300http://lattes.cnpq.br/4451208231291916Ana Cristina de Oliveira Monteiro Moreira42420199391http://lattes.cnpq.br/3183895586263436Maria Raquel AlcÃntara de Miranda46142371349http://buscatextual.cnpq.br/buscatextual/visualizacv.jsp?id=K4796542P9Maria Izabel GallÃo49633070997http://lattes.cnpq.br/3386021312697854Norma Maria Barros Benevides04505670368http://lattes.cnpq.br/383927208350882662278169300http://lattes.cnpq.br/8685772247777465Ed Carlos Morais dos SantosUniversidade Federal do CearÃPrograma de PÃs-GraduaÃÃo em BioquÃmicaUFCBRGalactomananas, filmes biodegradÃveis, glicerol, tempo de prateleiraBIOQUIMICAThe fruit growers are adapting to changes in consumption patterns and increased demand from consumers about the quality of fresh fruits available. The market need to meet the demand from consumption centers, which are increasingly distant from the centers of production, makes it necessary to prolong the shelf life of fruits without these attributes lose their health protection as a result of natural aging process. Research aimed at developing new technologies for reducing post harvest losses are fundamental to the national economy, and minimize losses, increase competitiveness and seek to meet the qualities of an increasingly demanding mark et. Biodegradable films and edible coatings have received attention in recent years, mainly due to its potential application for preserving fruit. The objective of this work was to study the biodegradable films prepared from galactomannan of Caesalpinia pu lcherrima and glycerol aiming its use in the creation of packaging to increase shelf life of fruits. Initially we analyzed the effect of preparation conditions of films on the properties of barriers and found that both temperature and drying time cause a p ositive effect on the permeability to water vapor of these films, being chosen, so the temperature of 50  C and 12 hours as standard methodology for preparing the films. Then , we studied the influence of concentrations of galactomannan and glycerol on phy sical - chemical properties and found that the variables were statistically significant in all properties, highlighting that the glycerol had a positive influence on all tests, increasing concentration of glycerol provides increased studied property , probabl y due to its hygroscopic character. The increase in the concentration of galactomannan causes a decrease in absorption, moisture content and oxygen permeability and carbon dioxide. It was observed that temperature and relative humidity have a major influen ce on the barrier properties of the films, since the increase of these variables causes an increase in permeability to water vapor and oxygen. To understand how films behave in the face of mechanical stress, we studied the influence of the galactomannan an d glycerol on the mechanical properties and found that the thickness of the films increases with these variables and that the polysaccharide is responsible for increasing the tensile strength , puncture and tear strength of the films and the plasticizer has a positive influence on elongation and tear strength. After the knowledge of all the physico - chemical, mechanical and barrier properties and having the formulations which afforded us the desired properties optimized, we chose the formulation of GalGl y (0 . 4:1 . 0) (%, m: m) to test the performance of films for packaging to maintain the shelf life of sliced apples. It was observed that the apples they received the protection of the films showed the lowest respiration rate, weight loss 10% lower and lower level s of browning, brightness and color variation when compared with those who were not covered under the tested conditions. Thus, the films studied in this work have great potential for application in the packaging sector and contribute to increase the shelf life of fruitsOs produtores de frutas estÃo se adaptando Ãs mudanÃas nos padrÃes de consumo e exigÃncia cada vez maior dos consumidores quanto à qualidade das frutas frescas disponÃveis no mercado. A necessidade do mercado de atender à demanda dos centros de consumo, que estÃo cada vez mais distantes dos centros de produÃÃo, faz com que seja necessÃrio, prolongar a vida Ãtil das frutas sem que estas percam seus atributos de proteÃÃo à saÃde, em consequÃncia do processo de senescÃncia natural. Pesquisas voltadas ao desenvolvimento de novas tecnologias para a reduÃÃo das perdas pÃs-colheita sÃo fundamentais para a economia nacional: alÃm de minimizar as perdas, elevam a competitividade e procuram atender Ãs qualidades de um mercado cada vez mais exigente. Filmes biodegradÃveis e revestimentos comestÃveis tÃm recebido atenÃÃo nos Ãltimos anos, principalmente em funÃÃo de seu potencial de aplicaÃÃo para conservaÃÃo de frutas. O objetivo deste trabalho foi estudar os filmes biodegradÃveis preparados a partir de galactomanana de Caesalpinia pulcherrima e glicerol visando o seu emprego na constituiÃÃo de embalagens para aumentar o tempo de prateleira de frutos. Inicialmente foi analisado o efeito das condiÃÃes de preparaÃÃo dos filmes nas propriedades de barreiras e foi observado que tanto temperatura quanto tempo de secagem causam um efeito positivo na permeabilidade ao vapor de Ãgua desses filmes, sendo escolhido, assim, a temperatura de 50 ÂC e 12 horas como metodologia padrÃo de preparaÃÃo dos filmes. Em seguida, foi avaliado a influÃncia das concentraÃÃes de galactomanana e glicerol nas propriedades fÃsico-quÃmicas, foi verificado que as variÃveis foram estatisticamente significativas, com destaque para o glicerol que apresentou influÃncia positiva em todos os testes, ou seja, o aumento da concentraÃÃo do glicerol proporciona um aumento na absorÃÃo de umidade, conteÃdo de umidade, permeabilidade ao vapor de Ãgua e na permeabilidade ao oxigÃnio e ao diÃxido de carbono, provavelmente devido ao seu carÃter higroscÃpico. O aumento na concentraÃÃo de galactomanana provoca uma diminuiÃÃo na absorÃÃo de umidade, conteÃdo de umidade e na permeabilidade ao oxigÃnio e diÃxido de carbono. Foi observado que a temperatura e a umidade relativa apresentam uma grande influÃncia nas propriedades de barreiras dos filmes, visto que o aumento dessas variÃveis provoca um aumento na permeabilidade ao vapor de Ãgua e ao oxigÃnio. Para entender como os filmes se comportariam frente a esforÃos mecÃnicos, foi avaliado a influÃncia das concentraÃÃes de galactomanana e de glicerol nas propriedades mecÃnicas e foi verificado que a espessura dos filmes aumenta com o aumento dessas variÃveis e que o polissacarÃdeo à responsÃvel por aumentar a elasticidade, a forÃa de perfuraÃÃo e ruptura dos filmes e que o plastificante tem influÃncia positiva no alongamento e na forÃa necessÃria para rasgar o filme. ApÃs o conhecimento de todas as propriedades fÃsico-quÃmicas, de barreira e mecÃnicas e tendo as formulaÃÃes necessÃrias para a finalidade proposta, a formulaÃÃo GalGli de (0,4:1,0) (%, m:m), foi escolhida para testar o desempenho dos filmes como embalagem na manutenÃÃo do tempo de prateleira de maÃÃs fatiadas. Foi observado que as maÃÃs que receberam a proteÃÃo dos filmes apresentaram a menor taxa de respiraÃÃo, perda de massa 10% menor e baixos Ãndices de escurecimento e variaÃÃo de cor quando comparadas com aquelas que nÃo foram recobertas nas condiÃÃes testadas. Dessa forma, os filmes estudados neste trabalho possuem grande potencial para aplicaÃÃo no setor de embalagens e contribuir para aumentar o perÃodo de conservaÃÃo de frutos.CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superiorhttp://www.teses.ufc.br/tde_busca/arquivo.php?codArquivo=8319application/pdfinfo:eu-repo/semantics/openAccessporreponame:Biblioteca Digital de Teses e Dissertações da UFCinstname:Universidade Federal do Cearáinstacron:UFC2019-01-21T11:21:22Zmail@mail.com -
dc.title.en.fl_str_mv Biodegradable films of galactomannan: use in conservation fortress fruit.
dc.title.alternative.pt.fl_str_mv Filmes biodegradÃveis de galactomanana: uso na conservaÃÃo de frutos fortaleza.
title Biodegradable films of galactomannan: use in conservation fortress fruit.
spellingShingle Biodegradable films of galactomannan: use in conservation fortress fruit.
Ed Carlos Morais dos Santos
Galactomananas, filmes biodegradÃveis, glicerol, tempo de prateleira
BIOQUIMICA
title_short Biodegradable films of galactomannan: use in conservation fortress fruit.
title_full Biodegradable films of galactomannan: use in conservation fortress fruit.
title_fullStr Biodegradable films of galactomannan: use in conservation fortress fruit.
title_full_unstemmed Biodegradable films of galactomannan: use in conservation fortress fruit.
title_sort Biodegradable films of galactomannan: use in conservation fortress fruit.
author Ed Carlos Morais dos Santos
author_facet Ed Carlos Morais dos Santos
author_role author
dc.contributor.advisor1.fl_str_mv Renato de Azevedo Moreira
dc.contributor.advisor1ID.fl_str_mv 00114715300
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/4451208231291916
dc.contributor.referee1.fl_str_mv Ana Cristina de Oliveira Monteiro Moreira
dc.contributor.referee1ID.fl_str_mv 42420199391
dc.contributor.referee1Lattes.fl_str_mv http://lattes.cnpq.br/3183895586263436
dc.contributor.referee2.fl_str_mv Maria Raquel AlcÃntara de Miranda
dc.contributor.referee2ID.fl_str_mv 46142371349
dc.contributor.referee2Lattes.fl_str_mv http://buscatextual.cnpq.br/buscatextual/visualizacv.jsp?id=K4796542P9
dc.contributor.referee3.fl_str_mv Maria Izabel GallÃo
dc.contributor.referee3ID.fl_str_mv 49633070997
dc.contributor.referee3Lattes.fl_str_mv http://lattes.cnpq.br/3386021312697854
dc.contributor.referee4.fl_str_mv Norma Maria Barros Benevides
dc.contributor.referee4ID.fl_str_mv 04505670368
dc.contributor.referee4Lattes.fl_str_mv http://lattes.cnpq.br/3839272083508826
dc.contributor.authorID.fl_str_mv 62278169300
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/8685772247777465
dc.contributor.author.fl_str_mv Ed Carlos Morais dos Santos
contributor_str_mv Renato de Azevedo Moreira
Ana Cristina de Oliveira Monteiro Moreira
Maria Raquel AlcÃntara de Miranda
Maria Izabel GallÃo
Norma Maria Barros Benevides
dc.subject.por.fl_str_mv Galactomananas, filmes biodegradÃveis, glicerol, tempo de prateleira
topic Galactomananas, filmes biodegradÃveis, glicerol, tempo de prateleira
BIOQUIMICA
dc.subject.cnpq.fl_str_mv BIOQUIMICA
dc.description.sponsorship.fl_txt_mv CoordenaÃÃo de AperfeiÃoamento de Pessoal de NÃvel Superior
dc.description.abstract.por.fl_txt_mv The fruit growers are adapting to changes in consumption patterns and increased demand from consumers about the quality of fresh fruits available. The market need to meet the demand from consumption centers, which are increasingly distant from the centers of production, makes it necessary to prolong the shelf life of fruits without these attributes lose their health protection as a result of natural aging process. Research aimed at developing new technologies for reducing post harvest losses are fundamental to the national economy, and minimize losses, increase competitiveness and seek to meet the qualities of an increasingly demanding mark et. Biodegradable films and edible coatings have received attention in recent years, mainly due to its potential application for preserving fruit. The objective of this work was to study the biodegradable films prepared from galactomannan of Caesalpinia pu lcherrima and glycerol aiming its use in the creation of packaging to increase shelf life of fruits. Initially we analyzed the effect of preparation conditions of films on the properties of barriers and found that both temperature and drying time cause a p ositive effect on the permeability to water vapor of these films, being chosen, so the temperature of 50 Â C and 12 hours as standard methodology for preparing the films. Then , we studied the influence of concentrations of galactomannan and glycerol on phy sical - chemical properties and found that the variables were statistically significant in all properties, highlighting that the glycerol had a positive influence on all tests, increasing concentration of glycerol provides increased studied property , probabl y due to its hygroscopic character. The increase in the concentration of galactomannan causes a decrease in absorption, moisture content and oxygen permeability and carbon dioxide. It was observed that temperature and relative humidity have a major influen ce on the barrier properties of the films, since the increase of these variables causes an increase in permeability to water vapor and oxygen. To understand how films behave in the face of mechanical stress, we studied the influence of the galactomannan an d glycerol on the mechanical properties and found that the thickness of the films increases with these variables and that the polysaccharide is responsible for increasing the tensile strength , puncture and tear strength of the films and the plasticizer has a positive influence on elongation and tear strength. After the knowledge of all the physico - chemical, mechanical and barrier properties and having the formulations which afforded us the desired properties optimized, we chose the formulation of GalGl y (0 . 4:1 . 0) (%, m: m) to test the performance of films for packaging to maintain the shelf life of sliced apples. It was observed that the apples they received the protection of the films showed the lowest respiration rate, weight loss 10% lower and lower level s of browning, brightness and color variation when compared with those who were not covered under the tested conditions. Thus, the films studied in this work have great potential for application in the packaging sector and contribute to increase the shelf life of fruits
Os produtores de frutas estÃo se adaptando Ãs mudanÃas nos padrÃes de consumo e exigÃncia cada vez maior dos consumidores quanto à qualidade das frutas frescas disponÃveis no mercado. A necessidade do mercado de atender à demanda dos centros de consumo, que estÃo cada vez mais distantes dos centros de produÃÃo, faz com que seja necessÃrio, prolongar a vida Ãtil das frutas sem que estas percam seus atributos de proteÃÃo à saÃde, em consequÃncia do processo de senescÃncia natural. Pesquisas voltadas ao desenvolvimento de novas tecnologias para a reduÃÃo das perdas pÃs-colheita sÃo fundamentais para a economia nacional: alÃm de minimizar as perdas, elevam a competitividade e procuram atender Ãs qualidades de um mercado cada vez mais exigente. Filmes biodegradÃveis e revestimentos comestÃveis tÃm recebido atenÃÃo nos Ãltimos anos, principalmente em funÃÃo de seu potencial de aplicaÃÃo para conservaÃÃo de frutas. O objetivo deste trabalho foi estudar os filmes biodegradÃveis preparados a partir de galactomanana de Caesalpinia pulcherrima e glicerol visando o seu emprego na constituiÃÃo de embalagens para aumentar o tempo de prateleira de frutos. Inicialmente foi analisado o efeito das condiÃÃes de preparaÃÃo dos filmes nas propriedades de barreiras e foi observado que tanto temperatura quanto tempo de secagem causam um efeito positivo na permeabilidade ao vapor de Ãgua desses filmes, sendo escolhido, assim, a temperatura de 50 ÂC e 12 horas como metodologia padrÃo de preparaÃÃo dos filmes. Em seguida, foi avaliado a influÃncia das concentraÃÃes de galactomanana e glicerol nas propriedades fÃsico-quÃmicas, foi verificado que as variÃveis foram estatisticamente significativas, com destaque para o glicerol que apresentou influÃncia positiva em todos os testes, ou seja, o aumento da concentraÃÃo do glicerol proporciona um aumento na absorÃÃo de umidade, conteÃdo de umidade, permeabilidade ao vapor de Ãgua e na permeabilidade ao oxigÃnio e ao diÃxido de carbono, provavelmente devido ao seu carÃter higroscÃpico. O aumento na concentraÃÃo de galactomanana provoca uma diminuiÃÃo na absorÃÃo de umidade, conteÃdo de umidade e na permeabilidade ao oxigÃnio e diÃxido de carbono. Foi observado que a temperatura e a umidade relativa apresentam uma grande influÃncia nas propriedades de barreiras dos filmes, visto que o aumento dessas variÃveis provoca um aumento na permeabilidade ao vapor de Ãgua e ao oxigÃnio. Para entender como os filmes se comportariam frente a esforÃos mecÃnicos, foi avaliado a influÃncia das concentraÃÃes de galactomanana e de glicerol nas propriedades mecÃnicas e foi verificado que a espessura dos filmes aumenta com o aumento dessas variÃveis e que o polissacarÃdeo à responsÃvel por aumentar a elasticidade, a forÃa de perfuraÃÃo e ruptura dos filmes e que o plastificante tem influÃncia positiva no alongamento e na forÃa necessÃria para rasgar o filme. ApÃs o conhecimento de todas as propriedades fÃsico-quÃmicas, de barreira e mecÃnicas e tendo as formulaÃÃes necessÃrias para a finalidade proposta, a formulaÃÃo GalGli de (0,4:1,0) (%, m:m), foi escolhida para testar o desempenho dos filmes como embalagem na manutenÃÃo do tempo de prateleira de maÃÃs fatiadas. Foi observado que as maÃÃs que receberam a proteÃÃo dos filmes apresentaram a menor taxa de respiraÃÃo, perda de massa 10% menor e baixos Ãndices de escurecimento e variaÃÃo de cor quando comparadas com aquelas que nÃo foram recobertas nas condiÃÃes testadas. Dessa forma, os filmes estudados neste trabalho possuem grande potencial para aplicaÃÃo no setor de embalagens e contribuir para aumentar o perÃodo de conservaÃÃo de frutos.
description The fruit growers are adapting to changes in consumption patterns and increased demand from consumers about the quality of fresh fruits available. The market need to meet the demand from consumption centers, which are increasingly distant from the centers of production, makes it necessary to prolong the shelf life of fruits without these attributes lose their health protection as a result of natural aging process. Research aimed at developing new technologies for reducing post harvest losses are fundamental to the national economy, and minimize losses, increase competitiveness and seek to meet the qualities of an increasingly demanding mark et. Biodegradable films and edible coatings have received attention in recent years, mainly due to its potential application for preserving fruit. The objective of this work was to study the biodegradable films prepared from galactomannan of Caesalpinia pu lcherrima and glycerol aiming its use in the creation of packaging to increase shelf life of fruits. Initially we analyzed the effect of preparation conditions of films on the properties of barriers and found that both temperature and drying time cause a p ositive effect on the permeability to water vapor of these films, being chosen, so the temperature of 50 Â C and 12 hours as standard methodology for preparing the films. Then , we studied the influence of concentrations of galactomannan and glycerol on phy sical - chemical properties and found that the variables were statistically significant in all properties, highlighting that the glycerol had a positive influence on all tests, increasing concentration of glycerol provides increased studied property , probabl y due to its hygroscopic character. The increase in the concentration of galactomannan causes a decrease in absorption, moisture content and oxygen permeability and carbon dioxide. It was observed that temperature and relative humidity have a major influen ce on the barrier properties of the films, since the increase of these variables causes an increase in permeability to water vapor and oxygen. To understand how films behave in the face of mechanical stress, we studied the influence of the galactomannan an d glycerol on the mechanical properties and found that the thickness of the films increases with these variables and that the polysaccharide is responsible for increasing the tensile strength , puncture and tear strength of the films and the plasticizer has a positive influence on elongation and tear strength. After the knowledge of all the physico - chemical, mechanical and barrier properties and having the formulations which afforded us the desired properties optimized, we chose the formulation of GalGl y (0 . 4:1 . 0) (%, m: m) to test the performance of films for packaging to maintain the shelf life of sliced apples. It was observed that the apples they received the protection of the films showed the lowest respiration rate, weight loss 10% lower and lower level s of browning, brightness and color variation when compared with those who were not covered under the tested conditions. Thus, the films studied in this work have great potential for application in the packaging sector and contribute to increase the shelf life of fruits
publishDate 2012
dc.date.issued.fl_str_mv 2012-02-10
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