Aproveitamento integral dos resíduos da jabuticaba

Detalhes bibliográficos
Autor(a) principal: Miranda, Bruna Melo
Data de Publicação: 2023
Tipo de documento: Tese
Idioma: por
Título da fonte: Repositório Institucional da UFG
dARK ID: ark:/38995/0013000003h2q
Texto Completo: http://repositorio.bc.ufg.br/tede/handle/tede/12697
Resumo: The food industry has been looking for alternatives to produce healthier foods with functional properties, without losing the physical-chemical and sensory qualities demanded by consumers. The extraction of polysaccharides and bioactive compounds from plant matrices, mainly from waste/by-products generated by the industry, is an excellent economic and sustainable alternative for this purpose. For the recovery and use of such compounds, it is essential to understand the mechanisms related to their extraction, composition, structure and interactions that can occur in real food environments. In this sense, the objective of this work was to extract compounds from jaboticaba residues, such as anthocyanins and pectic polysaccharide from the peels and starch from the seed, in addition to carrying out the chemical and technological characterization of these compounds. During the anthocyanin extraction process, the best parameters for the process (pH, time, temperature and application of enzymes) were evaluated and their application in a halachromic film was proposed. During the extraction of the pectic polysaccharide, also extracted from jaboticaba peel, the parameters of time, temperature and pH were evaluated and the material characterized as to its composition of monosaccharides by nuclear magnetic resonance and gas chromatography, the degree of esterification was also determined, color, antioxidant activity, emulsifying capacity and rheological properties. The starch extracted from the seed was studied in relation to its composition (amylose, amylopectin, phenolic compounds, proteins) and structure (X-ray, differential scanning calorimetry, size exclusion chromatography and high-performance anion exchange chromatography). The results obtained demonstrated that anthocyanin was successfully included in a polymeric matrix for the formulation of a pH-sensitive film, which responds with color variation according to the pH of the medium. It was observed that the pectic polysaccharide has a high galactose content in its composition and excellent antioxidant activity and emulsification. As for the seed residue, it was possible to obtain a pure starch, classified as the Cc type, with a high amylose content and intermediate chains of amylopectin. Thus, the jaboticaba residues are presented as excellent materials for obtaining compounds of high industrial interest, with several possibilities for applications.
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spelling Silva, Flávio Alves dahttp://lattes.cnpq.br/1713250447051507Fernandes, Kátia Fláviahttp://lattes.cnpq.br/9737543228759171Silva, Flávio Alves daSilva, Nara Rúbia Rodrigues do NascimentoCardoso, Cláudio FernandesMorgado, Cristiane Maria AscariSousa, Gardênia Martins dehttp://lattes.cnpq.br/2400626216411326Miranda, Bruna Melo2023-04-03T11:03:34Z2023-04-03T11:03:34Z2023-02-15MIRANDA, B. M. Aproveitamento integral dos resíduos da jabuticaba. 2023. 64 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal de Goiás, Goiânia, 2023http://repositorio.bc.ufg.br/tede/handle/tede/12697ark:/38995/0013000003h2qThe food industry has been looking for alternatives to produce healthier foods with functional properties, without losing the physical-chemical and sensory qualities demanded by consumers. The extraction of polysaccharides and bioactive compounds from plant matrices, mainly from waste/by-products generated by the industry, is an excellent economic and sustainable alternative for this purpose. For the recovery and use of such compounds, it is essential to understand the mechanisms related to their extraction, composition, structure and interactions that can occur in real food environments. In this sense, the objective of this work was to extract compounds from jaboticaba residues, such as anthocyanins and pectic polysaccharide from the peels and starch from the seed, in addition to carrying out the chemical and technological characterization of these compounds. During the anthocyanin extraction process, the best parameters for the process (pH, time, temperature and application of enzymes) were evaluated and their application in a halachromic film was proposed. During the extraction of the pectic polysaccharide, also extracted from jaboticaba peel, the parameters of time, temperature and pH were evaluated and the material characterized as to its composition of monosaccharides by nuclear magnetic resonance and gas chromatography, the degree of esterification was also determined, color, antioxidant activity, emulsifying capacity and rheological properties. The starch extracted from the seed was studied in relation to its composition (amylose, amylopectin, phenolic compounds, proteins) and structure (X-ray, differential scanning calorimetry, size exclusion chromatography and high-performance anion exchange chromatography). The results obtained demonstrated that anthocyanin was successfully included in a polymeric matrix for the formulation of a pH-sensitive film, which responds with color variation according to the pH of the medium. It was observed that the pectic polysaccharide has a high galactose content in its composition and excellent antioxidant activity and emulsification. As for the seed residue, it was possible to obtain a pure starch, classified as the Cc type, with a high amylose content and intermediate chains of amylopectin. Thus, the jaboticaba residues are presented as excellent materials for obtaining compounds of high industrial interest, with several possibilities for applications.A indústria de alimentos tem buscado alternativas para produzir alimentos mais saudáveis e com propriedades funcionais, sem perder as qualidades físico-químicas e sensoriais, exigidas pelos consumidores. A extração de polissacarídeos e compostos bioativos de matrizes vegetais, principalmente de resíduos/subprodutos gerados pela indústria é uma excelente alternativa econômica e sustentável para tal finalidade. Para a recuperação e utilização de tais compostos, é fundamental compreender os mecanismos relacionados à sua extração, composição, estrutura e interações que podem acontecer em meios alimentícios reais. Neste sentido, o objetivo deste trabalho foi extrair compostos dos resíduos de jaboticaba, como antocianinas e polissacarídeo péctico da casca e amido da semente, além disso, realizar a caracterização química e tecnológica destes compostos. Durante o processo de extração da antocianina foram avaliados os melhores parâmetros para o processo (pH, tempo, temperatura e aplicação de enzimas) e proposto sua aplicação em um filme halacromico. Durante a extração do polissacarídeo péctico, também extraído da casca de jaboticaba, os parâmetros de tempo, temperatura e pH foram avaliados e o material caracterizado quanto a sua composição de monossacarídeos por ressonância magnética nuclear e cromatografia gasosa, também foi determinado o grau de esterificação, cor, atividade antioxidante, capacidade emulsificante e propriedades reológicas. O amido extraído da semente foi estudado com relação a sua composição (teor de amilose, amilopectina, compostos fenólicos, proteínas) e estrutura (raio X, calorimetria de varredura diferencial, cromatografia de exclusão por tamanho e cromatografia de troca aniônica de alto desempenho) Os resultados obtidos demonstraram que a antocianina foi incluída com sucesso em uma matriz polimérica para formulação de um filme sensível ao pH, que responde com variação de cor de acordo com o pH do meio. Foi observado que o polissacarídeo péctico possui alto teor de galactose na sua composição e excelente atividade antioxidante e emulsificação. Já o resíduo de sementes, foi possível obter um amido puro, classificado como do tipo Cc , com alto teor de amilose e cadeias intermediárias de amilopectina. Deste modo, os resíduos de jaboticaba se apresentaram como excelentes materiais para obtenção de compostos de alto interesse industrial, com diversas possibilidades para aplicações.Submitted by Marlene Santos (marlene.bc.ufg@gmail.com) on 2023-03-27T19:34:32Z No. of bitstreams: 2 Tese - Bruna Melo Miranda - 2023.pdf: 1164792 bytes, checksum: 48faec5cac983fd12913cd519ebd2c0b (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5)Approved for entry into archive by Luciana Ferreira (lucgeral@gmail.com) on 2023-04-03T11:03:34Z (GMT) No. of bitstreams: 2 Tese - Bruna Melo Miranda - 2023.pdf: 1164792 bytes, checksum: 48faec5cac983fd12913cd519ebd2c0b (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5)Made available in DSpace on 2023-04-03T11:03:34Z (GMT). No. of bitstreams: 2 Tese - Bruna Melo Miranda - 2023.pdf: 1164792 bytes, checksum: 48faec5cac983fd12913cd519ebd2c0b (MD5) license_rdf: 805 bytes, checksum: 4460e5956bc1d1639be9ae6146a50347 (MD5) Previous issue date: 2023-02-15Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESporUniversidade Federal de GoiásPrograma de Pós-graduação em Ciência e Tecnologia de Alimentos (EA)UFGBrasilEscola de Agronomia - EA (RMG)Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessSubproduto agroindustrialPolissacarídeo pécticoAntocianinaAmidoCaracterização químicaAgroindustrial by-productPectic polysaccharideAnthocyaninStarchChemical characterizationCIENCIAS AGRARIAS::AGRONOMIAAproveitamento integral dos resíduos da jabuticabaFull use of jabuticaba residuesinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesis1850050050050021511reponame:Repositório Institucional da UFGinstname:Universidade Federal de Goiás (UFG)instacron:UFGORIGINALTese - Bruna Melo Miranda - 2023.pdfTese - Bruna Melo Miranda - 2023.pdfapplication/pdf1164792http://repositorio.bc.ufg.br/tede/bitstreams/49084cdb-f326-475e-9f07-2f3867d30559/download48faec5cac983fd12913cd519ebd2c0bMD53LICENSElicense.txtlicense.txttext/plain; charset=utf-81748http://repositorio.bc.ufg.br/tede/bitstreams/9f2f6caf-92bf-4cf7-84b7-12105bebcdd5/download8a4605be74aa9ea9d79846c1fba20a33MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8805http://repositorio.bc.ufg.br/tede/bitstreams/39ab5776-c97e-46f6-9296-b6c20cf6d193/download4460e5956bc1d1639be9ae6146a50347MD52tede/126972023-04-03 08:03:35.095http://creativecommons.org/licenses/by-nc-nd/4.0/Attribution-NonCommercial-NoDerivatives 4.0 Internationalopen.accessoai:repositorio.bc.ufg.br:tede/12697http://repositorio.bc.ufg.br/tedeRepositório InstitucionalPUBhttp://repositorio.bc.ufg.br/oai/requesttasesdissertacoes.bc@ufg.bropendoar:2023-04-03T11:03:35Repositório Institucional da UFG - Universidade Federal de Goiás (UFG)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
dc.title.pt_BR.fl_str_mv Aproveitamento integral dos resíduos da jabuticaba
dc.title.alternative.eng.fl_str_mv Full use of jabuticaba residues
title Aproveitamento integral dos resíduos da jabuticaba
spellingShingle Aproveitamento integral dos resíduos da jabuticaba
Miranda, Bruna Melo
Subproduto agroindustrial
Polissacarídeo péctico
Antocianina
Amido
Caracterização química
Agroindustrial by-product
Pectic polysaccharide
Anthocyanin
Starch
Chemical characterization
CIENCIAS AGRARIAS::AGRONOMIA
title_short Aproveitamento integral dos resíduos da jabuticaba
title_full Aproveitamento integral dos resíduos da jabuticaba
title_fullStr Aproveitamento integral dos resíduos da jabuticaba
title_full_unstemmed Aproveitamento integral dos resíduos da jabuticaba
title_sort Aproveitamento integral dos resíduos da jabuticaba
author Miranda, Bruna Melo
author_facet Miranda, Bruna Melo
author_role author
dc.contributor.advisor1.fl_str_mv Silva, Flávio Alves da
dc.contributor.advisor1Lattes.fl_str_mv http://lattes.cnpq.br/1713250447051507
dc.contributor.advisor-co1.fl_str_mv Fernandes, Kátia Flávia
dc.contributor.advisor-co1Lattes.fl_str_mv http://lattes.cnpq.br/9737543228759171
dc.contributor.referee1.fl_str_mv Silva, Flávio Alves da
dc.contributor.referee2.fl_str_mv Silva, Nara Rúbia Rodrigues do Nascimento
dc.contributor.referee3.fl_str_mv Cardoso, Cláudio Fernandes
dc.contributor.referee4.fl_str_mv Morgado, Cristiane Maria Ascari
dc.contributor.referee5.fl_str_mv Sousa, Gardênia Martins de
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/2400626216411326
dc.contributor.author.fl_str_mv Miranda, Bruna Melo
contributor_str_mv Silva, Flávio Alves da
Fernandes, Kátia Flávia
Silva, Flávio Alves da
Silva, Nara Rúbia Rodrigues do Nascimento
Cardoso, Cláudio Fernandes
Morgado, Cristiane Maria Ascari
Sousa, Gardênia Martins de
dc.subject.por.fl_str_mv Subproduto agroindustrial
Polissacarídeo péctico
Antocianina
Amido
Caracterização química
topic Subproduto agroindustrial
Polissacarídeo péctico
Antocianina
Amido
Caracterização química
Agroindustrial by-product
Pectic polysaccharide
Anthocyanin
Starch
Chemical characterization
CIENCIAS AGRARIAS::AGRONOMIA
dc.subject.eng.fl_str_mv Agroindustrial by-product
Pectic polysaccharide
Anthocyanin
Starch
Chemical characterization
dc.subject.cnpq.fl_str_mv CIENCIAS AGRARIAS::AGRONOMIA
description The food industry has been looking for alternatives to produce healthier foods with functional properties, without losing the physical-chemical and sensory qualities demanded by consumers. The extraction of polysaccharides and bioactive compounds from plant matrices, mainly from waste/by-products generated by the industry, is an excellent economic and sustainable alternative for this purpose. For the recovery and use of such compounds, it is essential to understand the mechanisms related to their extraction, composition, structure and interactions that can occur in real food environments. In this sense, the objective of this work was to extract compounds from jaboticaba residues, such as anthocyanins and pectic polysaccharide from the peels and starch from the seed, in addition to carrying out the chemical and technological characterization of these compounds. During the anthocyanin extraction process, the best parameters for the process (pH, time, temperature and application of enzymes) were evaluated and their application in a halachromic film was proposed. During the extraction of the pectic polysaccharide, also extracted from jaboticaba peel, the parameters of time, temperature and pH were evaluated and the material characterized as to its composition of monosaccharides by nuclear magnetic resonance and gas chromatography, the degree of esterification was also determined, color, antioxidant activity, emulsifying capacity and rheological properties. The starch extracted from the seed was studied in relation to its composition (amylose, amylopectin, phenolic compounds, proteins) and structure (X-ray, differential scanning calorimetry, size exclusion chromatography and high-performance anion exchange chromatography). The results obtained demonstrated that anthocyanin was successfully included in a polymeric matrix for the formulation of a pH-sensitive film, which responds with color variation according to the pH of the medium. It was observed that the pectic polysaccharide has a high galactose content in its composition and excellent antioxidant activity and emulsification. As for the seed residue, it was possible to obtain a pure starch, classified as the Cc type, with a high amylose content and intermediate chains of amylopectin. Thus, the jaboticaba residues are presented as excellent materials for obtaining compounds of high industrial interest, with several possibilities for applications.
publishDate 2023
dc.date.accessioned.fl_str_mv 2023-04-03T11:03:34Z
dc.date.available.fl_str_mv 2023-04-03T11:03:34Z
dc.date.issued.fl_str_mv 2023-02-15
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
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dc.identifier.citation.fl_str_mv MIRANDA, B. M. Aproveitamento integral dos resíduos da jabuticaba. 2023. 64 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal de Goiás, Goiânia, 2023
dc.identifier.uri.fl_str_mv http://repositorio.bc.ufg.br/tede/handle/tede/12697
dc.identifier.dark.fl_str_mv ark:/38995/0013000003h2q
identifier_str_mv MIRANDA, B. M. Aproveitamento integral dos resíduos da jabuticaba. 2023. 64 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal de Goiás, Goiânia, 2023
ark:/38995/0013000003h2q
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dc.relation.cnpq.fl_str_mv 151
dc.relation.sponsorship.fl_str_mv 1
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
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info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Universidade Federal de Goiás
dc.publisher.program.fl_str_mv Programa de Pós-graduação em Ciência e Tecnologia de Alimentos (EA)
dc.publisher.initials.fl_str_mv UFG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Escola de Agronomia - EA (RMG)
publisher.none.fl_str_mv Universidade Federal de Goiás
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFG
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