Reações de Ortometalacão em Piridinas
| Autor(a) principal: | |
|---|---|
| Data de Publicação: | 2002 |
| Outros Autores: | |
| Tipo de documento: | Artigo |
| Idioma: | por |
| Título da fonte: | Repositório Institucional da UFJF |
| Texto Completo: | http://dx.doi.org/10.1590/S0100-40422002000100016 https://repositorio.ufjf.br/jspui/handle/ufjf/9155 |
Resumo: | - |
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2019-02-22T13:14:04Z2019-02-202019-02-22T13:14:04Z2002-022518998http://dx.doi.org/10.1590/S0100-40422002000100016https://repositorio.ufjf.br/jspui/handle/ufjf/9155-In this paper we describe a powerful methodology for the regiospecific construction of polysubstituted aromatic and heteroaromatic compounds. The DoM reaction (direct ortho-metalation) comprises the deprotonation in position ortho of a aromatic or heteroaromatic containing DMG (directed metalation group) by strong bases, normally an alkyllithium reagent, leading to an ortho-lithiated species. These species, upon treatment with electrophilic reagents, gives 1,2 disubstituted products.por--BrasilQuímica Nova-Ortho-metalationDirected metallation groupHeteroaromatic compoundsReações de Ortometalacão em Piridinasinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleSouza, Marcus .V. N. deAlmeida, Mauro Vieira deinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFJFinstname:Universidade Federal de Juiz de Fora (UFJF)instacron:UFJFTHUMBNAILReações de Ortometalacão em Piridinas.pdf.jpgReações de Ortometalacão em Piridinas.pdf.jpgGenerated Thumbnailimage/jpeg1573https://repositorio.ufjf.br/jspui/bitstream/ufjf/9155/4/Rea%c3%a7%c3%b5es%20de%20Ortometalac%c3%a3o%20em%20Piridinas.pdf.jpg2e1e01da587e8c1cc0c7f0833a6f063fMD54ORIGINALReações de Ortometalacão em Piridinas.pdfReações de Ortometalacão em Piridinas.pdfapplication/pdf1429746https://repositorio.ufjf.br/jspui/bitstream/ufjf/9155/1/Rea%c3%a7%c3%b5es%20de%20Ortometalac%c3%a3o%20em%20Piridinas.pdf553242967c8cbcdae4f2da1b1b1d4c81MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-82197https://repositorio.ufjf.br/jspui/bitstream/ufjf/9155/2/license.txt000e18a5aee6ca21bb5811ddf55fc37bMD52TEXTReações de Ortometalacão em Piridinas.pdf.txtReações de Ortometalacão em Piridinas.pdf.txtExtracted texttext/plain34467https://repositorio.ufjf.br/jspui/bitstream/ufjf/9155/3/Rea%c3%a7%c3%b5es%20de%20Ortometalac%c3%a3o%20em%20Piridinas.pdf.txt73797a5c8663db8a89d6b1d15180fb49MD53ufjf/91552019-06-16 12:25:31.431oai:hermes.cpd.ufjf.br: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Repositório InstitucionalPUBhttps://repositorio.ufjf.br/oai/requestopendoar:2019-06-16T15:25:31Repositório Institucional da UFJF - Universidade Federal de Juiz de Fora (UFJF)false |
| dc.title.pt_BR.fl_str_mv |
Reações de Ortometalacão em Piridinas |
| title |
Reações de Ortometalacão em Piridinas |
| spellingShingle |
Reações de Ortometalacão em Piridinas Souza, Marcus .V. N. de - Ortho-metalation Directed metallation group Heteroaromatic compounds |
| title_short |
Reações de Ortometalacão em Piridinas |
| title_full |
Reações de Ortometalacão em Piridinas |
| title_fullStr |
Reações de Ortometalacão em Piridinas |
| title_full_unstemmed |
Reações de Ortometalacão em Piridinas |
| title_sort |
Reações de Ortometalacão em Piridinas |
| author |
Souza, Marcus .V. N. de |
| author_facet |
Souza, Marcus .V. N. de Almeida, Mauro Vieira de |
| author_role |
author |
| author2 |
Almeida, Mauro Vieira de |
| author2_role |
author |
| dc.contributor.author.fl_str_mv |
Souza, Marcus .V. N. de Almeida, Mauro Vieira de |
| dc.subject.cnpq.fl_str_mv |
- |
| topic |
- Ortho-metalation Directed metallation group Heteroaromatic compounds |
| dc.subject.por.fl_str_mv |
Ortho-metalation Directed metallation group Heteroaromatic compounds |
| description |
- |
| publishDate |
2002 |
| dc.date.issued.fl_str_mv |
2002-02 |
| dc.date.accessioned.fl_str_mv |
2019-02-22T13:14:04Z |
| dc.date.available.fl_str_mv |
2019-02-20 2019-02-22T13:14:04Z |
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info:eu-repo/semantics/publishedVersion |
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info:eu-repo/semantics/article |
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article |
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https://repositorio.ufjf.br/jspui/handle/ufjf/9155 |
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http://dx.doi.org/10.1590/S0100-40422002000100016 |
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http://dx.doi.org/10.1590/S0100-40422002000100016 https://repositorio.ufjf.br/jspui/handle/ufjf/9155 |
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por |
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por |
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Química Nova |
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info:eu-repo/semantics/openAccess |
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openAccess |
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- |
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Brasil |
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