Sorção de cromo em solos do cerrado goiano, Brasil
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UFLA |
Texto Completo: | http://repositorio.ufla.br/jspui/handle/1/42062 |
Resumo: | Land application of tannery sludge, which usually contain high levels of chromium, and considerable amounts of organic matter, macronutrients and micronutrients may contribute to the improvement of soil fertility and plant nutrition, and constitutes a form of disposal residue in the environment. The objective of this work was to determine the sorption isotherms of metal chromium (Cr+3) in a Ultisol, Oxisol Typic Acrustox, Quartzipsamment and Kandic Oxisol, identify soil classes that are prone to chromium mobility, and characterize the potential of agricultural soils of Goiás that are subject to groundwater contamination by the potentially toxic metal. For the establishment of sorption isotherms, solutions were prepared at 1:10 in volume. Air dried samples of 5.0 cm3 of each class of soil were placed in triplicates in beakers of 250.0 cm3. A solution containing 50.0 cm3 of the potentially toxic metal was added to solution. The solutions were prepared in CaCl2.(2H2O) (0.01 mol.L-1) as electrolyte support and employing the basic chromium sulphate as a source of metal. Adjustments were made to the polynomial regression between the concentrations of potentially toxic levels of metal contaminants in the solution depending on the concentration of metal in the filtered solution after equilibrium. The Quartzipsamment showed lower retention compared to other classes of soils. Therefore it is more vulnerable to groundwater contamination if industrial wastes containing trivalent chromium are used as fertilizer. |
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Sorção de cromo em solos do cerrado goiano, BrasilSorption of chromium in soils of the Cerrado Goias, BrazilMetais pesados - Contaminação do soloCurtumeLatossoloNeossolo QuartzarênicoHeavy metals - Soil contaminationTanningOxisol Typic AcrustoxQuartzipsammentLand application of tannery sludge, which usually contain high levels of chromium, and considerable amounts of organic matter, macronutrients and micronutrients may contribute to the improvement of soil fertility and plant nutrition, and constitutes a form of disposal residue in the environment. The objective of this work was to determine the sorption isotherms of metal chromium (Cr+3) in a Ultisol, Oxisol Typic Acrustox, Quartzipsamment and Kandic Oxisol, identify soil classes that are prone to chromium mobility, and characterize the potential of agricultural soils of Goiás that are subject to groundwater contamination by the potentially toxic metal. For the establishment of sorption isotherms, solutions were prepared at 1:10 in volume. Air dried samples of 5.0 cm3 of each class of soil were placed in triplicates in beakers of 250.0 cm3. A solution containing 50.0 cm3 of the potentially toxic metal was added to solution. The solutions were prepared in CaCl2.(2H2O) (0.01 mol.L-1) as electrolyte support and employing the basic chromium sulphate as a source of metal. Adjustments were made to the polynomial regression between the concentrations of potentially toxic levels of metal contaminants in the solution depending on the concentration of metal in the filtered solution after equilibrium. The Quartzipsamment showed lower retention compared to other classes of soils. Therefore it is more vulnerable to groundwater contamination if industrial wastes containing trivalent chromium are used as fertilizer.O uso agrícola de lodos de curtume, que contêm, normalmente, elevados teores de cromo, e consideráveis teores de matéria orgânica, macronutrientes e micronutrientes, pode contribuir para a melhoria da fertilidade dos solos e nutrição das plantas, além de representar uma forma de descarte do resíduo no ambiente. Objetivou-se, com esta pesquisa, determinar as isotermas de sorção do metal cromo trivalente (Cr+3) em Argissolo Vermelho Eutrófico (PVef), Latossolo Vermelho Acriférrico (LVwf), Neossolo Quartzarênico (RQ) e Nitossolo Vermelho Eutroférrico (NVef); verificar, dentre essas classes de solos, qual proporciona maior mobilidade ao cromo, e caracterizar o potencial dos solos agricultáveis do Estado de Goiás quanto ao risco de contaminação de águas subterrâneas por esse metal potencialmente tóxico. Para o estabelecimento de isotermas de sorção foram colocados 5,0 cm3 de amostras de terra fina seca ao ar (TFSA) de cada classe de solo, em triplicata, em béqueres de 250,0 cm3. Foram adicionados, com o auxílio de uma proveta, 50,0 cm3 da solução contendo o metal potencialmente tóxico. As soluções foram preparadas em CaCl2.(2H2O) (0,01 mol.L-1) como eletrólito-suporte e empregando o sulfato básico de cromo como fonte do metal. Foram efetuados ajustes de regressão polinomial entre as concentrações dos teores do metal potencialmente tóxico na solução contaminante em função da concentração do metal na solução filtrada após o equilíbrio. O Neossolo Quartzarênico apresentou uma menor retenção em comparação com as demais classes de solos sendo, portanto, mais vulnerável à contaminação das águas subterrâneas, caso resíduos industriais contendo Cr+3 sejam aplicados como fertilizantes nessa classe de solo.Instituto de Pesquisas Ambientais em Bacias Hidrográficas (IPABHi)2020-07-21T12:43:00Z2020-07-21T12:43:00Z2010info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfLEMKE-DE-CASTRO, M. L. et al. Sorção de cromo em solos do cerrado goiano, Brasil. Revista Ambiente & Água, Taubaté, v. 5, n. 2, p. 133-143, 2010.http://repositorio.ufla.br/jspui/handle/1/42062Revista Ambiente & Águareponame:Repositório Institucional da UFLAinstname:Universidade Federal de Lavras (UFLA)instacron:UFLAhttp://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessLemke-de-Castro, Mara LuciaBorges, Jácomo DivinoOliveira, Luiz Fernando Coutinho deRodrigues, CristianeFigueiredo, Cícero CélioCastro, Welershon José depor2023-05-02T17:54:46Zoai:localhost:1/42062Repositório InstitucionalPUBhttp://repositorio.ufla.br/oai/requestnivaldo@ufla.br || repositorio.biblioteca@ufla.bropendoar:2023-05-02T17:54:46Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA)false |
dc.title.none.fl_str_mv |
Sorção de cromo em solos do cerrado goiano, Brasil Sorption of chromium in soils of the Cerrado Goias, Brazil |
title |
Sorção de cromo em solos do cerrado goiano, Brasil |
spellingShingle |
Sorção de cromo em solos do cerrado goiano, Brasil Lemke-de-Castro, Mara Lucia Metais pesados - Contaminação do solo Curtume Latossolo Neossolo Quartzarênico Heavy metals - Soil contamination Tanning Oxisol Typic Acrustox Quartzipsamment |
title_short |
Sorção de cromo em solos do cerrado goiano, Brasil |
title_full |
Sorção de cromo em solos do cerrado goiano, Brasil |
title_fullStr |
Sorção de cromo em solos do cerrado goiano, Brasil |
title_full_unstemmed |
Sorção de cromo em solos do cerrado goiano, Brasil |
title_sort |
Sorção de cromo em solos do cerrado goiano, Brasil |
author |
Lemke-de-Castro, Mara Lucia |
author_facet |
Lemke-de-Castro, Mara Lucia Borges, Jácomo Divino Oliveira, Luiz Fernando Coutinho de Rodrigues, Cristiane Figueiredo, Cícero Célio Castro, Welershon José de |
author_role |
author |
author2 |
Borges, Jácomo Divino Oliveira, Luiz Fernando Coutinho de Rodrigues, Cristiane Figueiredo, Cícero Célio Castro, Welershon José de |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Lemke-de-Castro, Mara Lucia Borges, Jácomo Divino Oliveira, Luiz Fernando Coutinho de Rodrigues, Cristiane Figueiredo, Cícero Célio Castro, Welershon José de |
dc.subject.por.fl_str_mv |
Metais pesados - Contaminação do solo Curtume Latossolo Neossolo Quartzarênico Heavy metals - Soil contamination Tanning Oxisol Typic Acrustox Quartzipsamment |
topic |
Metais pesados - Contaminação do solo Curtume Latossolo Neossolo Quartzarênico Heavy metals - Soil contamination Tanning Oxisol Typic Acrustox Quartzipsamment |
description |
Land application of tannery sludge, which usually contain high levels of chromium, and considerable amounts of organic matter, macronutrients and micronutrients may contribute to the improvement of soil fertility and plant nutrition, and constitutes a form of disposal residue in the environment. The objective of this work was to determine the sorption isotherms of metal chromium (Cr+3) in a Ultisol, Oxisol Typic Acrustox, Quartzipsamment and Kandic Oxisol, identify soil classes that are prone to chromium mobility, and characterize the potential of agricultural soils of Goiás that are subject to groundwater contamination by the potentially toxic metal. For the establishment of sorption isotherms, solutions were prepared at 1:10 in volume. Air dried samples of 5.0 cm3 of each class of soil were placed in triplicates in beakers of 250.0 cm3. A solution containing 50.0 cm3 of the potentially toxic metal was added to solution. The solutions were prepared in CaCl2.(2H2O) (0.01 mol.L-1) as electrolyte support and employing the basic chromium sulphate as a source of metal. Adjustments were made to the polynomial regression between the concentrations of potentially toxic levels of metal contaminants in the solution depending on the concentration of metal in the filtered solution after equilibrium. The Quartzipsamment showed lower retention compared to other classes of soils. Therefore it is more vulnerable to groundwater contamination if industrial wastes containing trivalent chromium are used as fertilizer. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010 2020-07-21T12:43:00Z 2020-07-21T12:43:00Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
LEMKE-DE-CASTRO, M. L. et al. Sorção de cromo em solos do cerrado goiano, Brasil. Revista Ambiente & Água, Taubaté, v. 5, n. 2, p. 133-143, 2010. http://repositorio.ufla.br/jspui/handle/1/42062 |
identifier_str_mv |
LEMKE-DE-CASTRO, M. L. et al. Sorção de cromo em solos do cerrado goiano, Brasil. Revista Ambiente & Água, Taubaté, v. 5, n. 2, p. 133-143, 2010. |
url |
http://repositorio.ufla.br/jspui/handle/1/42062 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
http://creativecommons.org/licenses/by/4.0/ info:eu-repo/semantics/openAccess |
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http://creativecommons.org/licenses/by/4.0/ |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Instituto de Pesquisas Ambientais em Bacias Hidrográficas (IPABHi) |
publisher.none.fl_str_mv |
Instituto de Pesquisas Ambientais em Bacias Hidrográficas (IPABHi) |
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Revista Ambiente & Água reponame:Repositório Institucional da UFLA instname:Universidade Federal de Lavras (UFLA) instacron:UFLA |
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Universidade Federal de Lavras (UFLA) |
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UFLA |
institution |
UFLA |
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Repositório Institucional da UFLA |
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Repositório Institucional da UFLA |
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Repositório Institucional da UFLA - Universidade Federal de Lavras (UFLA) |
repository.mail.fl_str_mv |
nivaldo@ufla.br || repositorio.biblioteca@ufla.br |
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1815439186055921664 |