Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium

Detalhes bibliográficos
Autor(a) principal: Maria Eduarda Santos de Jesus
Data de Publicação: 2020
Outros Autores: André de Mendonça Santos, Miriam Sanae Tokumoto, Fernando Cotting, Isabella Pacifico Aquino, Vera Rosa Capelossi
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMG
Texto Completo: https://doi.org/10.34117/bjdv6n10-227
http://hdl.handle.net/1843/57234
https://orcid.org/0000-0002-1544-0864
https://orcid.org/0000-0002-3887-0189
https://orcid.org/0000-0002-2692-6667
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-0212-8388
Resumo: Having in mind that the synthetic inhibitors, currently used to prevent corrosion are aggressive to the environment, natural inhibitors, might be a valid alternative and an innovative solution to this problem, due to its low cost, sustainability and its eco-friendly profile. In this work, a study was carried out on the evaluation of efficiency of avocado seed powder (Persea Americana) as inhibitor on the corrosion of SAE 1008 carbon steel in acidic medium (HCl 0.5 mol.L-1). The avocado seed powder was obtained from milling and sieving at 170 mesh. Different concentrations (0.44 g L-1;0.77 g L-1; 1.11 g L-1; 1.44 g L-1; 1.77 g L-1) of avocado seed powder were added in HCl solution. The efficiency of the inhibitor was measured by electrochemical techniques, such as electrochemical impedance spectroscopy (EIS) and poteciodynimic polarization curves, as well as gravimetric tests. The chemical characterization of the inhibitor was performed by Fourier transform infrared spectroscopy (FTIR), while the morphological characterization was obtained by optical microscopy. The FTIR characterization reveals the presence of compounds formed by heteroatoms such as nitrogen and oxygen in functional groups know to prevent the corrosion process. The results provided by these tests showed that the tendency of this inhibitor is to increase the corrosion resistance as the concentration of the inhibitor also increases, revealing that the inhibitor is a promising alternative when it comes to avoiding corrosive processes on the surface of the SAE 1008 carbon steel.
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spelling 2023-07-31T16:40:13Z2023-07-31T16:40:13Z2020-10-096107719777215https://doi.org/10.34117/bjdv6n10-2272525-8761http://hdl.handle.net/1843/57234https://orcid.org/0000-0002-1544-0864https://orcid.org/0000-0002-3887-0189https://orcid.org/0000-0002-2692-6667https://orcid.org/0000-0001-5980-0078https://orcid.org/0000-0002-0212-8388Having in mind that the synthetic inhibitors, currently used to prevent corrosion are aggressive to the environment, natural inhibitors, might be a valid alternative and an innovative solution to this problem, due to its low cost, sustainability and its eco-friendly profile. In this work, a study was carried out on the evaluation of efficiency of avocado seed powder (Persea Americana) as inhibitor on the corrosion of SAE 1008 carbon steel in acidic medium (HCl 0.5 mol.L-1). The avocado seed powder was obtained from milling and sieving at 170 mesh. Different concentrations (0.44 g L-1;0.77 g L-1; 1.11 g L-1; 1.44 g L-1; 1.77 g L-1) of avocado seed powder were added in HCl solution. The efficiency of the inhibitor was measured by electrochemical techniques, such as electrochemical impedance spectroscopy (EIS) and poteciodynimic polarization curves, as well as gravimetric tests. The chemical characterization of the inhibitor was performed by Fourier transform infrared spectroscopy (FTIR), while the morphological characterization was obtained by optical microscopy. The FTIR characterization reveals the presence of compounds formed by heteroatoms such as nitrogen and oxygen in functional groups know to prevent the corrosion process. The results provided by these tests showed that the tendency of this inhibitor is to increase the corrosion resistance as the concentration of the inhibitor also increases, revealing that the inhibitor is a promising alternative when it comes to avoiding corrosive processes on the surface of the SAE 1008 carbon steel.Tendo em vista que os inibidores sintéticos, atualmente utilizados para prevenir a corrosão são agressivos ao meio ambiente, os inibidores naturais podem ser uma alternativa válida e uma solução inovadora para este problema, devido ao seu baixo custo, sustentabilidade e perfil ecologicamente correto. Neste trabalho foi realizado um estudo sobre a avaliação da eficiência do pó do caroço de abacate (Persea Americana) como inibidor da corrosão do aço carbono SAE 1008 em meio ácido (HCl 0,5 mol.L-1). O pó da semente de abacate foi obtido por moagem e peneiramento em malha 170. Diferentes concentrações (0,44 g L-1; 0,77 g L-1; 1,11 g L-1; 1,44 g L-1; 1,77 g L-1) de pó de semente de abacate foram adicionadas à solução de HCl. A eficiência do inibidor foi medida por técnicas eletroquímicas, como espectroscopia de impedância eletroquímica (EIS) e curvas de polarização potenciodinâmica, além de testes gravimétricos. A caracterização química do inibidor foi realizada por espectroscopia de infravermelho com transformada de Fourier (FTIR), enquanto a caracterização morfológica foi obtida por microscopia óptica. A caracterização por FTIR revela a presença de compostos formados por heteroátomos como nitrogênio e oxigênio em grupos funcionais conhecidos por impedir o processo de corrosão. Os resultados fornecidos por esses testes mostraram que a tendência desse inibidor é aumentar a resistência à corrosão à medida que a concentração do inibidor também aumenta, revelando que o inibidor é uma alternativa promissora para evitar processos corrosivos na superfície do aço carbono SAE 1008.Outra AgênciaengUniversidade Federal de Minas GeraisUFMGBrasilENG - DEPARTAMENTO DE ENGENHARIA QUÍMICABrazilian Journal of DevelopmentEngenharia químicaAço-carbono - CorrosãoAbacateGreen inhibitorsCarbon steelAcidic mediumAvocado seedEISEvaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic mediumAvaliação da eficiência da semente de abacate em pó (Persea Americana) como inibidor de corrosão em aço carbono SAE 1008 em meio ácidoinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttps://ojs.brazilianjournals.com.br/ojs/index.php/BRJD/article/view/18077Maria Eduarda Santos de JesusAndré de Mendonça SantosMiriam Sanae TokumotoFernando CottingIsabella Pacifico AquinoVera Rosa Capelossiapplication/pdfinfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFMGinstname:Universidade Federal de Minas Gerais (UFMG)instacron:UFMGLICENSELicense.txtLicense.txttext/plain; charset=utf-82042https://repositorio.ufmg.br/bitstream/1843/57234/1/License.txtfa505098d172de0bc8864fc1287ffe22MD51ORIGINALEvaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium.pdfEvaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium.pdfapplication/pdf831776https://repositorio.ufmg.br/bitstream/1843/57234/2/Evaluation%20of%20efficiency%20of%20avocado%20seed%20powder%20%28Persea%20Americana%29%20as%20a%20corrosion%20inhibitor%20in%20SAE%201008%20carbon%20steel%20in%20acidic%20medium.pdfb3eb6cd8c6096449a1e45ee0255264d1MD521843/572342023-07-31 13:40:13.899oai:repositorio.ufmg.br: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Repositório de PublicaçõesPUBhttps://repositorio.ufmg.br/oaiopendoar:2023-07-31T16:40:13Repositório Institucional da UFMG - Universidade Federal de Minas Gerais (UFMG)false
dc.title.pt_BR.fl_str_mv Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
dc.title.alternative.pt_BR.fl_str_mv Avaliação da eficiência da semente de abacate em pó (Persea Americana) como inibidor de corrosão em aço carbono SAE 1008 em meio ácido
title Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
spellingShingle Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
Maria Eduarda Santos de Jesus
Green inhibitors
Carbon steel
Acidic medium
Avocado seed
EIS
Engenharia química
Aço-carbono - Corrosão
Abacate
title_short Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
title_full Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
title_fullStr Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
title_full_unstemmed Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
title_sort Evaluation of efficiency of avocado seed powder (Persea Americana) as a corrosion inhibitor in SAE 1008 carbon steel in acidic medium
author Maria Eduarda Santos de Jesus
author_facet Maria Eduarda Santos de Jesus
André de Mendonça Santos
Miriam Sanae Tokumoto
Fernando Cotting
Isabella Pacifico Aquino
Vera Rosa Capelossi
author_role author
author2 André de Mendonça Santos
Miriam Sanae Tokumoto
Fernando Cotting
Isabella Pacifico Aquino
Vera Rosa Capelossi
author2_role author
author
author
author
author
dc.contributor.author.fl_str_mv Maria Eduarda Santos de Jesus
André de Mendonça Santos
Miriam Sanae Tokumoto
Fernando Cotting
Isabella Pacifico Aquino
Vera Rosa Capelossi
dc.subject.por.fl_str_mv Green inhibitors
Carbon steel
Acidic medium
Avocado seed
EIS
topic Green inhibitors
Carbon steel
Acidic medium
Avocado seed
EIS
Engenharia química
Aço-carbono - Corrosão
Abacate
dc.subject.other.pt_BR.fl_str_mv Engenharia química
Aço-carbono - Corrosão
Abacate
description Having in mind that the synthetic inhibitors, currently used to prevent corrosion are aggressive to the environment, natural inhibitors, might be a valid alternative and an innovative solution to this problem, due to its low cost, sustainability and its eco-friendly profile. In this work, a study was carried out on the evaluation of efficiency of avocado seed powder (Persea Americana) as inhibitor on the corrosion of SAE 1008 carbon steel in acidic medium (HCl 0.5 mol.L-1). The avocado seed powder was obtained from milling and sieving at 170 mesh. Different concentrations (0.44 g L-1;0.77 g L-1; 1.11 g L-1; 1.44 g L-1; 1.77 g L-1) of avocado seed powder were added in HCl solution. The efficiency of the inhibitor was measured by electrochemical techniques, such as electrochemical impedance spectroscopy (EIS) and poteciodynimic polarization curves, as well as gravimetric tests. The chemical characterization of the inhibitor was performed by Fourier transform infrared spectroscopy (FTIR), while the morphological characterization was obtained by optical microscopy. The FTIR characterization reveals the presence of compounds formed by heteroatoms such as nitrogen and oxygen in functional groups know to prevent the corrosion process. The results provided by these tests showed that the tendency of this inhibitor is to increase the corrosion resistance as the concentration of the inhibitor also increases, revealing that the inhibitor is a promising alternative when it comes to avoiding corrosive processes on the surface of the SAE 1008 carbon steel.
publishDate 2020
dc.date.issued.fl_str_mv 2020-10-09
dc.date.accessioned.fl_str_mv 2023-07-31T16:40:13Z
dc.date.available.fl_str_mv 2023-07-31T16:40:13Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://hdl.handle.net/1843/57234
dc.identifier.doi.pt_BR.fl_str_mv https://doi.org/10.34117/bjdv6n10-227
dc.identifier.issn.pt_BR.fl_str_mv 2525-8761
dc.identifier.orcid.pt_BR.fl_str_mv https://orcid.org/0000-0002-1544-0864
https://orcid.org/0000-0002-3887-0189
https://orcid.org/0000-0002-2692-6667
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-0212-8388
url https://doi.org/10.34117/bjdv6n10-227
http://hdl.handle.net/1843/57234
https://orcid.org/0000-0002-1544-0864
https://orcid.org/0000-0002-3887-0189
https://orcid.org/0000-0002-2692-6667
https://orcid.org/0000-0001-5980-0078
https://orcid.org/0000-0002-0212-8388
identifier_str_mv 2525-8761
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Brazilian Journal of Development
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
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dc.publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.publisher.initials.fl_str_mv UFMG
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv ENG - DEPARTAMENTO DE ENGENHARIA QUÍMICA
publisher.none.fl_str_mv Universidade Federal de Minas Gerais
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMG
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